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Preferable Filament Diameter Ratios of Hybrid Yarn Components for Optimized Longfiber Reinforced Thermoplastics

R. Beyreuther、Harald Brünig、Roland Vogel2002-05-01International Polymer Processing

Abstract The mechanical properties of hybrid (commingled) yarn based reinforced thermoplastics depend on many parameters of the fiber components as well as of the different technological conditions during the commingling and the hot press molding. Among the fiber parameters the diameter ratio of the matrix and the rei…

Textile materials and evaluationsFiber-reinforced polymer compositesStructural Analysis and Optimization

Hydrogen Isotope Separation Factors on Palladium Alloy Membranes

Deli Luo、Chunlei Shen、Deying Meng2002-05-01Fusion Science & Technology

The influence of temperature and gas composition on hydrogen isotope separation factors of membrane cascade with reflux ratio of 0.9998 and different palladium alloy membranes were studied. Separation factors for H-D mixture with different palladium alloy membranes varies from 1.31 to 1.42 at different temperatures, a…

Fusion materials and technologiesNuclear Materials and PropertiesChemical Synthesis and Characterization

Design of Metal Hydride Vessels for Processing Tritium

L. K. Heung2002-05-01Fusion Science & Technology

Metal hydrides offer safe, compact and efficient ways to process tritium in areas including storage, pumping, compression, transportation and purification. Westinghouse at Savannah River Site in USA has developed and implemented metal hydride based technology for various tritium applications over the past 20 years. Th…

Fusion materials and technologiesHydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen Reduction

Tritium and Deuterium Retention in Graphite Limiters in TEXTOR

T. Tanabe、K. Miyasaka、M. Rubel 等 4 位作者2002-05-01Fusion Science & Technology

In order to investigate tritium behavior in tokamak, we have measured surface distributions of deuterium and tritium on graphite limiter tiles used in TEXTOR under D-D operation by means of an ion beam analysis and tritium imaging plate technique, respectively.It was found that both distributions were quite different,…

Magnetic confinement fusion researchFusion materials and technologiesPlasma Diagnostics and Applications

Physical mechanisms responsible for the relaxation time distribution in disordered dielectrics

V. A. Stephanovich、M. D. Glinchuk、B. Hilczer 等 4 位作者2002-05-01Physics of the Solid State

The relaxation time distribution function F (τ) is calculated in the framework of the random-field theory. The function F (τ) is expressed through the distribution function f ( E ) of a random electric field E with due regard for the derived dependence of the relaxation time τ on the electric field. The distribution f…

Ferroelectric and Piezoelectric MaterialsMaterial Dynamics and PropertiesGlass properties and applications

Preparation and study of carbidized porous silicon

O. M. Sreseli、D. N. Goryachev、V. Yu. Osipov 等 8 位作者2002-05-01Semiconductors

Porous silicon layers with introduced carbon-containing substances (fullerenes, ultradisperse diamond, carbohydrates) have been studied. It was found that high-temperature annealing of such layers in a hydrogen atmosphere leads to substantial transformation of the photoluminescence spectra. It is assumed that this res…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

P‐69: Polymer Stabilized Cholesteric Dichroic Dye Displays

F. Zhang、Deng‐Ke Yang2002-05-01SID Symposium Digest of Technical Papers

Abstract We have developed two types of polymer stabilized cholesteric dichroic dye displays. In the first type, an anisotropic polymer network perpendicular to the cell surface was formed by photo‐polymerization in the homeotropic texture in the presence of an electric field. The polymer network enhanced the hysteres…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsElectrowetting and Microfluidic Technologies

The Behaviour of Zirconium-Cobalt as a Material for Tritium Storage

U. Besserer、R.‐D. Penzhorn、R. Brandt2002-05-01Fusion Science & Technology

The Tritium Storage facility of the Tritium Laboratory Karlsruhe (TLK), was recently upgraded by four additional uranium beds and one containing ZrCo. Now it is possible to compare under very similar conditions the sorption/desorption properties of uranium and those of ZrCo. To test the adequacy of ZrCo for routine, t…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Materials and Properties

Innovative Pipe Coating Material and Process for High Temperature Fields

V. Sauvant-Moynot、Sébastien Duval、Jacky Grenier2002-05-01Oil & Gas Science and Technology – Revue d’IFP Energies nouvelles

To date, the high temperatures (above 140°C) met in some fields in, e. g. , the North Sea, impose the development of innovative corrosion protecting coatings. Thermostable products have been developed from combining a high-Tg thermoplastic and epoxyamine monomers (the latter reducing the viscosity of the former to all…

Corrosion Behavior and InhibitionConcrete Corrosion and DurabilityStructural Integrity and Reliability Analysis

Lifetime RC time delay of on-chip copper interconnect

Meiling Sun、Michael Pecht、D. F. Barbe2002-05-01IEEE Transactions on Semiconductor Manufacturing

Increasing resistance and RC time delay induced by an oxidation in a copper line during its lifetime may limit copper-based metallization for technologies with critical dimension. Based on the mechanisms of resistance, constriction resistance and material diffusion, two dynamic models to access lifetime behavior of re…

Electronic Packaging and Soldering TechnologiesSemiconductor materials and devicesCopper Interconnects and Reliability

In situ Raman studies on the interaction of oxygen and methanol with an iodine‐modified electrolytic silver catalyst

Wei‐Lin Dai、Yi Dong、Yong Cao 等 7 位作者2002-05-01Journal of Raman Spectroscopy

Abstract In situ Raman spectroscopy was used to study the interaction of iodine‐modified electrolytic silver with oxygen and methanol at atmospheric pressure at temperatures between 25 and 500°C. It is shown that the presence of iodine inhibits the formation of surface oxygen species corresponding to deep oxidation an…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

State of Magnesia in Magnesia (10.4 mol%)‐Doped Zirconia Powder Prepared from Coprecipitation

Tian Jun Rong、Xiao Huang、Shi Wei Wang 等 5 位作者2002-05-01Journal of the American Ceramic Society

MgO (10.4 mol%)‐doped ZrO 2 powder, which was prepared by coprecipitation and calcination at 750°C, was leached and milled, respectively. The powders were characterized by Auger electron scanning microprobe and XRD technologies. Only the 2.3 mol% MgO was soluble in ZrO 2 ; it stabilized ZrO 2 as the metastable tetrago…

Advanced ceramic materials synthesisAdvanced materials and compositesNuclear materials and radiation effects

Growth, Structural and Microtopographical Studies of Calcium Iodate, Monohydrate Crystals Grown in Silica Gel

S. J. Shitole、K. B. Saraf2002-05-01Crystal Research and Technology

Single crystals of calcium iodate, monohydrate [Ca(IO3)2, H2O] have been grown by gel technique. Prismatic, prismatic pyramidal, needle shaped and hopper crystals were obtained. These crystals were also grown by doping impurities such as copper and iron. Kinetics of growth parameters was investigated. Structural analy…

Crystallization and Solubility Studies

EPR of Er3+, Nd3+, and Ce3+ ions in YAlO3 single crystals

Georgi Asatryan、J. Rosa2002-05-01Physics of the Solid State

EPR spectra of the Er 3+ , Nd 3+ , and Ce 3+ ions substituting for the Y 3+ ion in the YAlO 3 yttrium orthoaluminate lattice are studied. The EPR spectra of these rare-earth ions are described by a spin Hamiltonian of rhombic symmetry with an effective spin S =1/2. The principal values of the g tensors were determined…

Luminescence Properties of Advanced MaterialsAdvanced Condensed Matter PhysicsSolid-state spectroscopy and crystallography

Development of a Passively Cooled, Electrically Heated Hydride (PACE) Bed

J. E. Klein、James R. Brenner、Edward Dyer2002-05-01Fusion Science & Technology

A nominal 1500 STP-L PAssively Cooled, Electrically heated hydride (PACE) Bed has been developed and tested. The bed contained 12.6 kg of a La-Ni-Al alloy and used aluminum foam to improve heat transfer within the bed. Steady-state temperature measurements made at constant power showed a nonuniform bed temperature pro…

Advancements in Solid Oxide Fuel CellsHydrogen Storage and MaterialsNuclear Materials and Properties

Templated tetramerization of dicyanobenzenes to form mixed porphyrinato and phthalocyaninato rare earth(III) triple-decker complexes

Na Pan、Jianzhuang Jiang、Xuegui Cui 等 4 位作者2002-05-01Journal of Porphyrins and Phthalocyanines

Heteroleptic porphyrinato/phthalocyaninato rare earth(III) triple-decker compounds M 2 ( Por ) 2 ( Pc ') (1a-4a) and M 2 ( Por )( Pc ') 2 (1c-4c) ( M = Eu , Tb ; Por = TDOPP , Pc ' = OOPc or Por = TpClPP , Pc ' = Pc where H 2 (TDOPP) = 5,10,15,20-tetrakis(4-n-dodecyloxyphenyl)porphyrin, H 2 [OOPc] = 2,3,9,10,16,17,23,…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Structural restoration of inactive recombinant fish growth hormones by chemical chaperonin and solvent restraint approaches

Chia‐Ching Chang、Chi-Tung Tsai、Chi-Yao Chang2002-05-01Protein Engineering Design and Selection

Recombinant proteins may undergo conformational distortion, leading to aggregation and loss of function, when they are expressed in heterologous systems. The structural and functional restoration of such inactive proteins is highly desirable. We have over-expressed recombinant growth hormones from the fish ayu (Plecog…

Protein Structure and DynamicsEnzyme Structure and FunctionViral Infectious Diseases and Gene Expression in Insects

Domain-Driven Binding of Fibrin(Ogen) onto Silk Fibroin Biomaterials

Matteo Santin、S.P. Denyer、Andrew W. Lloyd 等 4 位作者2002-05-01Journal of Bioactive and Compatible Polymers

Studies have demonstrated that serum protein adsorption onto silk fibroin-based biomaterials dramatically changes when the conformation of this natural polymer is rearranged by engineering procedures. In the present study, attention was paid to the binding of fibrin(ogen) to fibroin fibers and regenerated films. The f…

Electrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction StudiesSilk-based biomaterials and applications

Microstructural characterization of radio frequency magnetron sputter-deposited Ga2O3:Mn phosphor thin films

Joo Han Kim、Paul H. Holloway2002-05-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Ga 2 O 3 : Mn phosphor thin films have been prepared by radio frequency (rf) magnetron sputtering of a 2 mol % Mn-doped Ga2O3 target in an oxygen–argon mixture atmosphere. The deposition rate of the films decreased from 14 to 12 Å/min when the working gas pressure decreased from 30 to 2 mTorr, while the O/Ga ratio of…

Advanced Photocatalysis TechniquesZnO doping and propertiesGa2O3 and related materials

Reduction of Residual Monomer in Latex Products by Enhanced Polymerization and Extraction in Supercritical Carbon Dioxide

Maartje F. Kemmere、Marcus van Schilt、Mascha Cleven 等 5 位作者2002-05-01Industrial & Engineering Chemistry Research

One of the most important environmental incentives for the polymer industry is to reduce the residual monomer content in polymer products. In addition to the conventional techniques for the reduction of residual monomer, a process based on supercritical carbon dioxide (scCO 2 ) can be a viable alternative as both furt…

Phase Equilibria and ThermodynamicsCarbon dioxide utilization in catalysisPolymer Foaming and Composites