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Soft modes and superconductivity in the layered hexagonal carbidesV2CAs,Nb2CAs,andNb2CS

S. V. Halilov、David J. Singh、D. A. Papaconstantopoulos2002-04-29Physical review. B, Condensed matter

The electronic structure, selected phonon frequencies, and electron phonon coupling of the hexagonal layered compounds ${\mathrm{Nb}}_{2}\mathrm{CS},$ ${\mathrm{Nb}}_{2}\mathrm{CAs},$ and ${\mathrm{V}}_{2}\mathrm{CAs}$ are elucidated using density functional calculations. All materials are good three-dimensional metal…

Metal and Thin Film MechanicsIron-based superconductors researchMXene and MAX Phase Materials

Polarized Raman scattering of epitaxial PbTiO3 thin film with coexisting c and a domains

Sun-Hwa Lee、Hyun M. Jang、Seong M. Cho 等 4 位作者2002-04-29Applied Physics Letters

Effects of the orientation of ferroelectric domains on the characteristics of polarized Raman spectra were studied using an epitaxially grown PbTiO3 thin film in which the c-axis oriented domains coexist with the a-axis oriented domains on MgO (001). To obtain polarized spectra for both two distinctive c and a domains…

Ferroelectric and Piezoelectric MaterialsPhotorefractive and Nonlinear OpticsAcoustic Wave Resonator Technologies

Charge-density wave as an electro-optical switch and memory

N. Ogawa、Kenjiro Miyano2002-04-29Applied Physics Letters

Switching and memory effects based on the deformation of the charge-density wave (CDW) in K0.3MoO3 are demonstrated. The deformations, which greatly affect the CDW dynamic phase transition from creep phase to slide phase, can be set by an external electric field and be removed by photoexcitation. This property can be…

Perovskite Materials and ApplicationsOrganic and Molecular Conductors ResearchSolid-state spectroscopy and crystallography

Blackbody Spectra for Sonoluminescing Hydrogen Bubbles

George Vazquez、Carlos G. Camara、Seth Putterman 等 4 位作者2002-04-29Physical Review Letters

The dynamical motion of sonoluminescing bubbles formed from a mixture of water and hydrogen gas indicates that these bubbles contain hydrogen. Their spectrum is well matched by an ideal 6000 K blackbody radiating from a surface with a radius less than 1/4 microm. According to this model, the state of matter inside the…

Ultrasound and Hyperthermia ApplicationsUltrasound and Cavitation PhenomenaPhotoacoustic and Ultrasonic Imaging

Dislocation jumping over the sound barrier in tungsten

Qikai Li、San‐Qiang Shi2002-04-29Applied Physics Letters

It is commonly believed that dislocations cannot surmount the sound barrier at the shear wave velocity. This letter presents results of molecular dynamics simulation showing the contrary, namely that a stationary dislocation can be accelerated above the sound barrier provided that the theoretical shear strength is rea…

High-pressure geophysics and materialsFusion materials and technologiesNuclear Materials and Properties

Mechanical Analysis of Ultrasonic Bonding for Rapid Prototyping

Yuan Gao、Charalabos C. Doumanidis2002-04-29Journal of Manufacturing Science and Engineering

Ultrasonic bonding of thin foils has been recently introduced to rapid prototyping of complex-shaped and/or internally structured layered parts. This article provides the mechanical analysis of an elementary ultrasonic spot welding process of a metal foil on a previously deposited substrate. A 2-D, quasi-static/dynami…

Mechanical Behavior of CompositesAdvanced Welding Techniques AnalysisHigh-Velocity Impact and Material Behavior

Field emission from nonaligned carbon nanotubes embedded in a polystyrene matrix

C.H.P. Poa、S. Ravi P. Silva、Paul Watts 等 6 位作者2002-04-29Applied Physics Letters

Low threshold fields of 1.6 V/μm and 2.6 V/μm were obtained for field emission from multiwalled carbon nanotubes and boron-doped multiwalled carbon nanotubes embedded in polystyrene, respectively. A Fowler–Nordheim analysis of the results together with sheet resistivity data illustrate that the higher carbon nanotube…

Carbon Nanotubes in CompositesGraphene research and applicationsIon-surface interactions and analysis

Simultaneous production of polyhydroxyalkanoates and rhamnolipids by Pseudomonas aeruginosa

Katsutoshi Hori、Sidik Marsudi、Hajime Unno2002-04-29Biotechnology and Bioengineering

The feasibility of the simultaneous production of polyhydroxyalkanoates (PHAs) and rhamnolipids, as a novel approach to reduce their production costs, was demonstrated by the cultivation of Pseudomonas aeruginosa IFO3924. Fairly large amounts of PHAs and rhamnolipids were obtained from the bacterial cells and the cult…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionGraphene and Nanomaterials Applications

Dissolution of rare-earth clusters inSiO2by Al codoping: A microscopic model

Jesper Lægsgaard2002-04-29Physical review. B, Condensed matter

A microscopic model for the incorporation of ${\mathrm{Er}}_{2}{\mathrm{O}}_{3}$ units in silica codoped with ${\mathrm{Al}}_{2}{\mathrm{O}}_{3}$ is presented. The model assumes that Er clustering is counteracted by the formation of Er-Al complexes in which each Er ion provides valence compensation for three substitut…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsCrystal Structures and Properties

Piezoelectric properties and phase transitions of 〈001〉-oriented Pb(Zn1/3Nb2/3)O3–PbTiO3 single crystals

W. Ren、S. F. Liu、Bhaskar Mukherjee2002-04-29Applied Physics Letters

Electric-field-induced phase transitions and piezoelectric properties of 〈001〉-oriented Pb(Zn1/3Nb2/3)O3–xPbTiO3 single crystals for x=4.5% and 8% (PZN–4.5%PT and PZN–8%PT) have been investigated as a function of temperature. It was found that the piezoelectric properties and phase transitions for both crystals are st…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Cerium dioxide buffer layers at low temperature by atomic layer deposition

Jani Päiväsaari、Matti Putkonen、Lauri Niinistö2002-04-29Journal of Materials Chemistry

Thin films of cerium dioxide were deposited by atomic layer deposition (ALD). Temperature ranges studied in detail were 175–375 °C and 225–350 °C for the Ce(thd)4 and Ce(thd)3phen (thd = 2,2,6,6-tetramethyl-3,5-heptanedionate, phen = 1,10-phenanthroline) precursors, respectively. Ozone was used in both cases as oxygen…

Catalytic Processes in Materials ScienceSemiconductor materials and devicesElectronic and Structural Properties of Oxides

NO reduction with CO in the presence of O2 over Al2O3-supported and Cu-based catalysts

Takashi Yamamoto、Tsunehiro Tanaka、Ryoji Kuma 等 9 位作者2002-04-29Physical Chemistry Chemical Physics

NO reduction with CO in the presence of O2 was examined over various kinds of Al2O3-supported and Cu-based catalysts. The effects of loaded elements, supports and calcination temperatures on catalysis for the NO–CO–O2 reaction system were investigated. We found that the most effective catalyst was 0.5 wt.% Cu/γ-Al2O3…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

Manufacture of specific structure of aluminum-doped zinc oxide films by patterning the substrate surface

Xin Jiang、Chun‐Lin Jia、Bernd Szyszka2002-04-29Applied Physics Letters

(0001)-oriented aluminum-doped zinc oxide films were prepared using a magnetron sputtering technique. High-resolution transmission-electron-microscopic images show that the oriented grains nucleate directly on the substrate surface and grow with equal lateral dimensions through the film thickness. A surface-energy-dri…

ZnO doping and propertiesCopper-based nanomaterials and applicationsFluid Dynamics and Thin Films

Spin-coherent transport in ferromagnetically contacted carbon nanotubes

Bo Zhao、Ingolf Mönch、H. Vinzelberg 等 5 位作者2002-04-29Applied Physics Letters

The spin-coherent quantum transport through multiwall carbon nanotubes contacted by ferromagnetic Co pads is investigated experimentally. At 4.2 K, the devices show a remarkable increase of the magnetoresistance (MR) ratio with decreasing junction bias, reaching a maximum MR ratio of 30% at a junction bias current of…

Carbon Nanotubes in CompositesGraphene research and applicationsQuantum and electron transport phenomena

Effect of surface treatment of NiTi alloy on its corrosion behavior in Hanks’ solution

O. Cissé、O. Savadogo、Meiping Wu 等 4 位作者2002-04-29Journal of Biomedical Materials Research

The effect of surface modification of NiTi shape memory alloy on its corrosion behavior in Hanks' solution was determined. The near-equi-atomic super elastic NiTi (Ni 55.8 wt %) alloy used for this study was provided by Memry USA. The surfaces of heat-treated samples were modified by mechanical polishing (MP), electro…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsShape Memory Alloy Transformations

Formation and catalytic characterization of various rare earth phosphates

Hiroaki Onoda、Hiroyuki Nariai、Ai Moriwaki 等 5 位作者2002-04-29Journal of Materials Chemistry

Various rare earth phosphates [rare earth elements: R = La, Ce, Pr, Nd, Sm, Yb, and Y; phosphates: Monazite-type, Xenotime-type, Rhabdophane-type, and Weinshenkite-type orthophosphates RPO4, polyphosphate R(PO3)3, and ultraphosphate RP5O14] were synthesized by heating the mixtures of each rare earth oxide and diammoni…

Polyoxometalates: Synthesis and ApplicationsCatalysis and Oxidation ReactionsChemical Synthesis and Characterization

Ferroelectric ordering in the relaxorPb(Mg1/3Nb2/3)O3as evidenced by low-temperature phonon anomalies

S. Wakimoto、Christian Stock、R. J. Birgeneau 等 8 位作者2002-04-29Physical review. B, Condensed matter

Neutron scattering measurements of the lowest-energy TO phonons in the relaxor $\mathrm{Pb}({\mathrm{Mg}}_{1/3}{\mathrm{Nb}}_{2/3}){\mathrm{O}}_{3}$ (PMN) are reported for $10<~T<~750 \mathrm{K}.$ The soft mode, which is overdamped by the polar nanoregions below the Burns temperature ${T}_{d}=620 \mathrm{K},$ su…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Size effect in mesoscopic epitaxial ferroelectric structures: Increase of piezoelectric response with decreasing feature size

Simon Bühlmann、B. Dwir、J. Baborowski 等 4 位作者2002-04-29Applied Physics Letters

An epitaxial 200 nm thick film of Pb(Zr0.40Ti0.60)O3 (PZT) has been deposited by reactive rf magnetron sputtering on conductive Nb-doped SrTiO3 (100) (STO). The patterning process involved electron-beam lithography of polymethylmethacrylate, fabrication of a 75 nm thick Cr hard mask layer by means of a lift-off proces…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesAdhesion, Friction, and Surface Interactions

Crystal Structure of the Core Domain of RhoE/Rnd3: A Constitutively Activated Small G Protein,

Halina Garavini、Kirsi Riento、John P. Phelan 等 6 位作者2002-04-27Biochemistry

We report the 2.1 A crystal structure of the core G protein domain of the unusual Rho family member RhoE/Rnd3 in complex with endogenous GTP and magnesium. Unlike other small G proteins, RhoE, along with two other proteins Rnd1/Rho6 and Rnd2/RhoN, does not hydrolyze GTP. The main reason for this is the presence of ser…

Protein Kinase Regulation and GTPase SignalingMicrotubule and mitosis dynamicsEnzyme Structure and Function