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Efficient phase field simulation of a binary dendritic growth in a forced flow

C.W. Lan、Chih‐Jen Shih2004-03-11Physical Review E

Efficient quantitative phase field simulation using an adaptive finite volume method with an antisolutal trapping scheme is presented for a binary dendritic growth in a forced flow. For the case of no convection, the calculated results with different interface thickness are examined. It is found that with a proper ant…

Aluminum Alloy Microstructure PropertiesSolidification and crystal growth phenomenananoparticles nucleation surface interactions

Metal−Polyimide Nanocomposite Films: Single-Stage Synthesis of Silvered Polyimide Films Prepared from Silver(I) Complexes and BPDA/4,4‘-ODA

Robin E. Southward、David W. Thompson2004-03-11Chemistry of Materials

Highly reflective and surface conductive flexible polyimide films have been prepared by the incorporation of silver(I) acetate and 1,1,1-trifluoro-2,4-pentanedione or 1,1,1,5,5,5-hexafluoro-2,4-pentanedione into a dimethylacetamide solution of the poly(amic acid) formed from 3,3‘,4,4‘-biphenyltetracarboxylic dianhydri…

Synthetic Organic Chemistry MethodsSynthesis and properties of polymersSilicone and Siloxane Chemistry

Influence of acrylonitrile–butadiene–styrene (ABS) morphology and poly(styrene‐co‐acrylonitrile) (SAN) content on fracture behavior of ABS/SAN blends

Roberto S. Yamakawa、Carlos A. Correa、Elias Hage2004-03-11Journal of Applied Polymer Science

Abstract This study attempted to correlate morphological changes and physical properties for a high rubber content acrylonitrile–butadiene–styrene (ABS) and its diluted blends with a poly(styrene‐ co ‐acrylonitrile) (SAN) copolymer. The results showed a close relationship between rubber content and fracture toughness…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesNatural Fiber Reinforced Composites

Dependency of thermal and mechanical properties on the composition of mixed‐substituent poly(fluoroalkoxyphosphazenes)

Andrew E. Maher、Catherine M. Ambler、Eric S. Powell 等 4 位作者2004-03-11Journal of Applied Polymer Science

Abstract A series of poly(fluoroalkoxyphosphazenes) containing a mixture of 2,2,3,3,4,4,5,5‐octafluoropentoxy and 2,2,2‐trifluoroethoxy substituents was synthesized. The series included polymers with 25–94% incorporation of the trifluoroethoxy substituent, as well as single‐substituent polymers with 100% octafluoropen…

Synthesis and characterization of novel inorganic/organometallic compoundsFlame retardant materials and propertiesSynthesis and properties of polymers

( 5Z )‐4‐bromo‐5‐(bromomethylene)‐3‐butyl‐2( 5H )‐furanone reduces corrosion from Desulfotomaculum orientis

Dacheng Ren、Thomas K. Wood2004-03-11Environmental Microbiology

(5Z)-4-bromo-5-(bromomethylene)-3-butyl-2(5H)-furanone (furanone) from the red marine alga Delisea pulchra was found previously to inhibit the growth, swarming and biofilm formation of Gram-positive bacteria (Ren et al., 2002, Lett Appl Microbiol 34: 293-299). In the present study, the Gram-positive sulphate-reducing…

Corrosion Behavior and InhibitionOdor and Emission Control TechnologiesConcrete Corrosion and Durability

Effect of chitin addition on injection‐molded thermoplastic corn starch

Roberto Rosa、Cristina T. Andrade2004-03-11Journal of Applied Polymer Science

Abstract A new type of biodegradable starch‐based composites was prepared by injection‐molding using glycerol and water as plasticizers. Chitin flakes, obtained from shells of Penaeus schmitti , were used as reinforcing phase. The effect of chitin content on the structural and tensile properties of the composite sampl…

Food composition and propertiesNanocomposite Films for Food Packagingbiodegradable polymer synthesis and properties

Direct fluorination of the polyimide Matrimid® 5218: The formation kinetics and physicochemical properties of the fluorinated layers

A.P. Kharitonov、Yu. L. Moskvin、D. A. Syrtsova 等 5 位作者2004-03-11Journal of Applied Polymer Science

The corresponding author's email address was printed incorrectly at the bottom of p. 6 when this article was published. Dr. A. P. Kharitonov's correct email address is: khariton@binep.ac.ru We regret the error.

Synthesis and properties of polymersSilicone and Siloxane ChemistryMaterial Properties and Applications

Misorientation dependence of the energy of symmetrical tilt boundaries in hcp metals: prediction by the disclination-structural unit model

Mao S. Wu、А. А. Назаров、Kun Zhou2004-03-11The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

The misorientation dependence of the energy of grain boundaries in hcp metals is predicted by application of the disclination-structural unit model and continuum solutions for interfacial disclination dipoles in elastically anisotropic and inhomogeneous bicrystals. For symmetrical tilt boundaries in cobalt and titaniu…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsMagnesium Alloys: Properties and Applications

Scattering operators forE1−E2x-ray resonant diffraction

Ivan Marri、Paolo Carra2004-03-11Physical Review B

Resonant x-ray diffraction in noncentrosymmetric crystals is studied by considering E1-E2 processes in the fast-collision approximation. The scattering amplitude is expressed in terms of polar and magnetoelectric operators of the valence states, which are involved in the resonance. Near-edge Bragg peaks from ferroelec…

Multiferroics and related materialsCrystal Structures and PropertiesAdvanced Condensed Matter Physics

The Effects of Network Structure on the Resistance of Silane Coupling Agent Layers to Water-Assisted Crack Growth

Jason J. Benkoski、Edward J. Krämer、Hyungshin Yim 等 5 位作者2004-03-11Langmuir

Silane adhesion promoters are commonly used to improve the adhesion, durability, and corrosion resistance of polymer-oxide interfaces. The current study investigates a model interface consisting of the natural oxide of(100) Si and an epoxy cured from diglycidyl ether ofbisphenol A (DGEBA) and triethylenetetraamine (TE…

Corrosion Behavior and InhibitionHigh voltage insulation and dielectric phenomenaConcrete Corrosion and Durability

Calcium–lead fluoro-vanadinite apatites. II. Equilibrium structures

Zhili Dong、Timothy J. White2004-03-11Acta Crystallographica Section B Structural Science

The synthetic vanadinites (Pb(x)Ca(10-x))(VO4)6(F(1-2y)O(y) (y))2, 0.57 < x < 9 and 0.10 < y < 0.47, adopt the P6(3)/m apatite structure with 9.7835 (3) < or = a < or = 10.0531 (1) A and 7.0318 (2) < or = c < or = 7.3033 (1) A. The calcium endmember is monoclinic, space group P2(1)/m, with a = 9.7370 (3), b = 9.7358 (…

Crystal Structures and PropertiesNuclear materials and radiation effectsX-ray Diffraction in Crystallography

Relaxation dynamics of a polymer in a 2D confinement

Gustavo A. Schwartz、R.G. Bergman、Jan Swenson2004-03-11The Journal of Chemical Physics

The molecular dynamics of oligomeric poly(propylene glycol) (PPG) liquids (MW=1000, 2000, and 4000 g/mol) confined in a two-dimensional layer-structured Na-vermiculite clay has been studied by broadband dielectric spectroscopy. The alpha-relaxation and the normal mode relaxation processes were studied for all samples…

Carbon Nanotubes in CompositesMaterial Dynamics and PropertiesForce Microscopy Techniques and Applications

Proportional relation between magnetoresistance and entropy suppression due to magnetic field in metallic ferromagnets

Norihiko Sakamoto、Tôru Kyômen、Shingo Tsubouchi 等 4 位作者2004-03-11Physical Review B

A temperature-independent proportional relation was discovered between magnetoresistance and magnetoentropy in metallic ferromagnets, ${\mathrm{La}}_{0.6}{\mathrm{Sr}}_{0.4}{\mathrm{CoO}}_{3},$ ${\mathrm{SrRuO}}_{3},$ and ${\mathrm{CoPt}}_{3}$ up to 90 kOe above, at, and just below Curie temperature. This concludes th…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsAdvanced Condensed Matter Physics

Structure for perovskites with layered ordering of A-site cations

Christopher J. Howard、Zhaoming Zhang2004-03-11Acta Crystallographica Section B Structural Science

The structure of La(1/3)NbO3 is that of a perovskite with La3+ cations ordered into alternate layers of perovskite A-sites. This is the description of a tetragonal structure and yet the room-temperature structure shows an orthorhombic distortion. The structure of La(2/3)TiO3 shows similar features. It has been recogni…

Magnetic and transport properties of perovskites and related materialsMicrowave Dielectric Ceramics SynthesisThermal Expansion and Ionic Conductivity

Structure of liquidGeO2from a computer simulation model

Gonzalo Gutiérrez、José Rogan2004-03-11Physical Review E

The structural properties of liquid GeO2 are investigated by means of molecular dynamics simulation using a pairwise potential. The simulations were performed in the microcanonical ensemble on systems with up to 576 particles prepared at 21 different densities, corresponding to pressures from -2 to 30 GPa, and tempera…

Material Dynamics and PropertiesGlass properties and applicationsTheoretical and Computational Physics

Simplified model of underwater electrical discharge

V. Ts. Gurovich、A. Grinenko、Ya. E. Krasik 等 4 位作者2004-03-11Physical Review E

A model of the underwater discharge with initiating wire is presented. The model reveals the nature of similarity parameters which have been phenomenologically introduced in earlier experimental research in order to predict behavior of different discharges. It is shown that these parameters naturally appear as a resul…

High voltage insulation and dielectric phenomenaPlasma Diagnostics and ApplicationsElectrohydrodynamics and Fluid Dynamics

Local Melting and Drag for a Particle Driven through a Colloidal Crystal

C. J. O. Reichhardt、C. J. Olson Reichhardt2004-03-11Physical Review Letters

We numerically investigate a colloidal particle driven through a colloidal crystal as a function of temperature. When the charge of the driven particle is larger or comparable to that of the colloids comprising the crystal, a local melting can occur, characterized by defect generation in the lattice surrounding the dr…

Material Dynamics and PropertiesTheoretical and Computational PhysicsCharacterization and Applications of Magnetic Nanoparticles

Synthesis, Structure, and Magnetism of a Ferric 24-Azametallacrown-8 Complex

Shen Lin、Shi‐Xiong Liu、Zhong Chen 等 5 位作者2004-03-11Inorganic Chemistry

A new pentadentate N-isobutyrylsalicylhydrazidate ligand (H(3)ibushz, C(11)H(14)N(2)O(3)) and a self-assembly synthesis of the first 24-azametallacrown-8, [Fe(8)(C(11)H(11)N(2)O(3))(8)(CH(3)OH)(8)].0.5CH(2)Cl(2).7.5CH(3)OH.3.5H(2)O, have been reported. Eight Fe(III) ions and eight deprotonated ibushz(3)(-) ligands con…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Formation of stacking-fault tetrahedra in aluminum irradiated with high-energy particles at low-temperatures

Y. Satoh、T. Yoshiie、H. Mori 等 4 位作者2004-03-11Physical Review B

Stacking-fault tetrahedra (SFT) are typical vacancy clusters in fcc metals. SFT have been, however, considered to be unstable in aluminum because of its high stacking-fault energy, until the recent finding of SFT in thin aluminum foils subjected to a tensile fracture. This study confirmed that SFT form in aluminum fol…

Microstructure and mechanical propertiesFusion materials and technologiesIon-surface interactions and analysis

The Influence of Doping Levels and Surface Termination on the Electrochemistry of Polycrystalline Diamond

Matthew N. Latto、Gustavo Pastor‐Moreno、D. Jason Riley2004-03-11Electroanalysis

Abstract The influence of surface chemistry and boron doping density on the redox chemistry of Fe(CN) $\rm{ {_{6}^{3-/4-}}}$ at CVD polycrystalline diamond electrodes is considered. It is demonstrated that for this couple both the doping density and the surface chemistry are important in determining the rate of charge…

Diamond and Carbon-based Materials ResearchMolecular Junctions and NanostructuresForce Microscopy Techniques and Applications