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Optical and thermal studies on pure and doped L-arginine phosphate crystals

P. Sumithraj Premkumar2010-03-20Indian Journal of Science and Technology

In the present study the single crystal growth of the pure and doped organic nonlinear optical crystal, L-arginine phosphate is reported. The dopants used were urea and thiourea. The crystals were grown by slow evaporation technique. The presence of various functional groups in the grown crystal was confirmed by Fouri…

Crystal structures of chemical compoundsNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Synthesis, properties, functionalisation and applications of carbon nanotube: a state of the art review

G. Broza2010-03-20Chemistry & Chemical Technology

Abstr act. The investigation of fullerenes and especially of carbon nanotubes (CNTs) has opened a new window for the development of polymer matrix composites with novel properties and applications. CNTs, which have a number of unexpected properties, both mechanical and electrical, seem to have a large potential as a f…

Carbon Nanotubes in CompositesFullerene Chemistry and ApplicationsNanotechnology research and applications

Syntheses, crystal structures, and some properties of heavier lanthanide(III) complexes with optically active N,N ′-bis(2-hydroxybenzyl)-N,N ′-bis(2-pyridylmethyl)-R-1,2-propanediamine

Yasunori Yamada、S. Takenouchi、Yusuke Miyoshi 等 4 位作者2010-03-20Journal of Coordination Chemistry

The reaction of N,N′-bis(2-hydroxybenzyl)-N,N′-bis(2-pyridylmethyl)-R-1,2-propanediamine (R-bbppnH2) with Ln(NO3)3 · nH2O (Ln = Tb, Dy, Ho, Er, Tm, Yb, or Lu) stereoselectively gave an optically active complex, [Ln(R-bbppn)(NO3)]. All the complexes crystallize in the same acentric orthorhombic space group of C2221 . T…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

In situ cross‐linking of the shell of self‐assembled peptide nanotubes

R. Gokhale、Julien Couet、Markus Biesalski2010-03-20physica status solidi (a)

Abstract Peptide polymer nanotubes (PPNTs) were prepared by in situ surface‐initiated atom transfer radical polymerization (ATRP) from self‐assembled cyclic peptide nanotubes. PPNT dimensions, i.e. , height ( i.e. diameter) and length, as derived from AFM measurements of surface‐adsorbed, dry PPNT are a function of th…

Chemical Synthesis and AnalysisSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Microstructural Effects on the Creep Deformation of Alumina/Single‐Wall Carbon Nanotubes Composites

Eugenio Zapata‐Solvas、Diego Gómez-Garcı́a、R. Poyato 等 8 位作者2010-03-20Journal of the American Ceramic Society

The enhanced high‐temperature creep resistance in alumina/single‐wall carbon nanotubes (SWNTs) composites has been attributed to the unprecedented grain‐boundary structure of these composites, where the SWNTs bundles segregated at the alumina grain boundaries partially impede grain‐boundary sliding. In this study, the…

Carbon Nanotubes in CompositesAdvanced ceramic materials synthesisAluminum Alloys Composites Properties

Electron transport enhanced molecular dynamics for metals and semi‐metals

Reese E. Jones、Jeremy Alan Templeton、Gregory J. Wagner 等 5 位作者2010-03-20International Journal for Numerical Methods in Engineering

Abstract In this work we extend classical molecular dynamics by coupling it with an electron transport model known as the two temperature model. This energy balance between free electrons and phonons was first proposed in 1956 by Kaganov et al . but has recently been utilized as a framework for coupling molecular dyna…

Quantum and electron transport phenomenaThermal properties of materialsThermal Radiation and Cooling Technologies

Nanopartikelcluster: SERS im Rampenlicht

Rongchao Jin2010-03-20Angewandte Chemie

Im Doppel besser: Nanopartikelcluster (wie Dimere, Trimere usw.) sind begehrte Systeme für Anwendungen in der oberflächenverstärkten Raman-Spektroskopie. Eine jüngste Studie bietet einen eleganten Ansatz für die Herstellung von Dimeren von Silber-Nanokugeln aus Nanowürfeln durch kontrolliertes chemisches Ätzen. Die Na…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and Applications

Compatibilization of PP/PAE blends by means of the addition of an ionomer

Ainhoa Granado、J. I. Eguiazábal、J. Nazábal2010-03-20Polymer Engineering and Science

Abstract Minor amounts of poly(ethylene‐ co ‐methacrylic acid) ionomer neutralized with Zn (PEMA‐Zn) were added in the melt state to blends of polypropylene (PP) with up to 40% of poly(amino ether) (PAE) resin. Given the good barrier characteristics of PAE, it is a good candidate to improve the poor barrier properties…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and Irradiation

Temperature Dependences of Leakage Currents of ZnO Varistors Doped with Rare‐Earth Oxides

Jun Hu、Jinliang He、Wangcheng Long 等 4 位作者2010-03-20Journal of the American Ceramic Society

Rare‐earth oxides are doped into ZnO varistors as grain growth inhibitors for increasing the varistors' voltage gradients. However, their leakage currents become large and their nonlinear coefficients decrease at the same time. The reasonable explanation for such a phenomenon has not yet been available. In this paper,…

ZnO doping and propertiesThin-Film Transistor TechnologiesSemiconductor materials and interfaces

The High‐Temperature Oxidation Behavior of Reaction‐Bonded Porous Silicon Carbide Ceramics in Dry Oxygen

Chuanwei Zheng、Zhenming Yang、Jinsong Zhang2010-03-20Journal of the American Ceramic Society

The oxidation behavior of reaction‐bonded porous silicon carbide (RPSC) ceramics in dry oxygen between 1100° and 1500°C was investigated based on four specimens with different porosities. RPSC ceramics exhibited a rapid mass increase in the initial stage of oxidation but a slow mass increase in the following oxidation…

Advanced ceramic materials synthesisHigh-Temperature Coating BehaviorsAdvanced materials and composites

Surface chemistry and topographical changes of an electropolished NiTi shape memory alloy

Lakshman Neelakantan、Markus Valtiner、Gunther Eggeler 等 4 位作者2010-03-20physica status solidi (a)

Abstract Electropolishing and its mechanism for NiTi shape memory alloy in methanolic sulfuric acid have been investigated recently. In the current study, X‐ray photoelectron spectroscopy was carried out to characterize the chemical nature of the electropolished surface. The electropolished surface is covered by a thi…

Corrosion Behavior and InhibitionAdvanced Memory and Neural ComputingShape Memory Alloy Transformations

Establishing the effect of loop length on dimensional stability of single jersey knitted fabric made from cotton/lycra core spun yarn

C. Prakash2010-03-20Indian Journal of Science and Technology

Munden and earlier workers established that in plain knitted fabrics the fabric dimensional parameters namely Kc, Kw and Ks are constant at dry and wet relaxed state for wool, cotton, orlon and nylon yarns. But in the present study of cotton/lycra core spun yarn single jersey derivative knitted fabrics the values for…

Textile materials and evaluations

Asymmetric Dumbbells from Selective Deposition of Metals on Seeded Semiconductor Nanorods

Sabyasachi Chakrabortty、Jie Yang、Yee Min Tan 等 5 位作者2010-03-20Angewandte Chemie

Das Wachstum von Au- und Ag2S-Nanopartikeln an bestimmten Stellen von CdS-Nanostäben mit CdSe-Keimen lässt sich über die Konzentration der Au- bzw. Ag-Vorstufe steuern. Auf diese Weise sind „Janus“-Nanostabstrukturen zugänglich, in denen Au am reaktiveren Ende und Ag2S am anderen Ende zu finden ist (siehe Bild; CdSe d…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Influence of molecular parameters on thermal, mechanical, and dynamic mechanical properties of hydrogenated nitrile rubber and its nanocomposites

Anusuya Choudhury、Anil K. Bhowmick、Christopher Ong 等 4 位作者2010-03-20Polymer Engineering and Science

Abstract The present work derives a relationship between structure and properties of hydrogenated nitrile rubber (HNBR) in the presence as well as absence of nanofillers. Four different grades of HNBR were selected to examine the influence of polarity, unsaturation, and molecular weight on thermal, mechanical, and dyn…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesHigh voltage insulation and dielectric phenomena

Novel Fabrication of Ca‐Doped LaNbO 4 Thin‐Film Proton‐Conducting Fuel Cells by Pulsed Laser Deposition

Anna Magrasó、E. Xuriguera、M. Várela 等 7 位作者2010-03-20Journal of the American Ceramic Society

Thin films of 0.5% Ca‐doped La 0.995 Ca 0.005 NbO 4−δ (LCNO) proton‐conducting electrolytes of ∼2 μm thickness were obtained by pulsed laser deposition on NiO–LaNbO 4 composite substrates. The morphology of the films was granular after annealing at T ≤1000°C and evolved to spherical‐like grains at 1100°C and above. Th…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Rate‐Dependent Indentation Response of Structural Ceramics

Michael A. Klecka、Ghatu Subhash2010-03-20Journal of the American Ceramic Society

Static and dynamic (high‐rate) indentation hardness values are determined for ZrO 2 , SiC, and Si 3 N 4 ceramics. While the static hardness is determined using a conventional Vickers tester, the dynamic hardness is determined using a custom‐designed tester that can produce a single indent within a 100‐μs duration. The…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsAdvanced materials and composites

Study of plastic compounds containing polypropylene and wood derived fillers from waste of different origin

Armanda Vīksne、Rita Bērziņa、Inga Andersone 等 4 位作者2010-03-20Journal of Applied Polymer Science

Abstract The scope of the article was to study the perspectives of the using of wood derived fillers (WDF) from waste of different origin as fillers of polypropylene. The WDF used in this study was hard wood flour (HW), birch veneer polishing dust (VD) and tetra‐pack carton cellulose fiber (TC). Some mechanical streng…

Wood Treatment and PropertiesNatural Fiber Reinforced CompositesInnovations in Concrete and Construction Materials

A Facile Approach to Fabrication of Hexagonal‐Phase NaYF4:Yb3+, Er3+ Hollow Nanospheres: Formation Mechanism and Upconversion Luminescence

Junwei Zhao、Xiaomin Liu、Di Cui 等 13 位作者2010-03-20European Journal of Inorganic Chemistry

Abstract The hexagonal‐phase NaYF4:Yb3+, Er3+ hollow nanospheres (HNS) have been successfully prepared for the first time by means of a hydrothermal route with the aid of polyethylenimine (PEI) as a surfactant. The nitrogen adsorption/desorption isotherms demonstrated the porous nature of the NaYF4 HNS. The formation…

Advanced Photocatalysis TechniquesLuminescence Properties of Advanced MaterialsInorganic Fluorides and Related Compounds

Rheological and mechanical characteristics of low density polyethylene/ethylene‐vinyl acetate/organoclay nanocomposites

Afsoon Behradfar、Akbar Shojaei、Nasrin Sheikh2010-03-20Polymer Engineering and Science

Abstract Attempts were made to trace the effect of organoclay (OC) on the rheological and mechanical behaviors of the low density polyethylene (LDPE)/ethylene‐vinyl acetate (EVA) blends. To do this effectively, in addition to LDPE/EVA/OC system, pure LDPE and LDPE/EVA blends were also examined as model systems. The rh…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer Science and PVC

Effect of Creep of Ferritic Interconnect on Long‐Term Performance of Solid Oxide Fuel Cell Stacks

W. N. Liu、Xin Sun、Mohammad A. Khaleel2010-03-20Fuel Cells

Abstract High‐temperature ferritic alloys are potential candidates as interconnect (IC) materials and spacers due to their low cost and coefficient of thermal expansion (CTE) compatibility with other components for most of the solid oxide fuel cells (SOFCs). However, creep deformation becomes relevant for a material w…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsNuclear Materials and Properties