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Synthesis of Ultra-Large-Pore SBA-15 Silica with Two-Dimensional Hexagonal Structure Using Triisopropylbenzene As Micelle Expander

Liang Cao、Tiffany Man、Michał Kruk2009-03-02Chemistry of Materials

It is proposed herein that in order to obtain ultralarge-pore ordered mesoporous silicas using surfactant-templated synthesis with micelle expanders, one should select a micelle swelling agent with a moderate swelling ability to achieve an appreciable pore diameter enlargement while avoiding the formation of heterogen…

Metal-Organic Frameworks: Synthesis and ApplicationsMesoporous Materials and CatalysisCovalent Organic Framework Applications

RGB Emission through Controlled Donor Self‐Assembly and Modulation of Excitation Energy Transfer: A Novel Strategy to White‐Light‐Emitting Organogels

Chakkooth Vijayakumar、Vakayil K. Praveen、Ayyappanpillai Ajayaghosh2009-03-02Advanced Materials

A white-light-emitting organogel is designed by the controlled self-assembly of a bischolesterol-functionalized OPV donor that allows slow energy migration and partial energy transfer in the gel state to an encapsulated acceptor. The white-light emission occurs because of the combination of blue-light emission from th…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Structure–Property Relation of SrTiO3/LaAlO3 Interfaces

Mark Huijben、Alexander Brinkman、Gertjan Koster 等 6 位作者2009-03-02OpenAlex

Abstract A large variety of transport properties have been observed at the interface between the insulating oxides SrTiO 3 and LaAlO 3 such as insulation, 2D interface metallicity, 3D bulk metallicity, magnetic scattering, and superconductivity. The relation between the structure and the properties of the SrTiO 3 /LaA…

Semiconductor materials and devicesMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Edge States in Graphene: From Gapped Flat-Band to Gapless Chiral Modes

Wang Yao、Shengyuan A. Yang、Qian Niu2009-03-02arXiv

We study edge states in graphene systems where a bulk energy gap is opened by inversion symmetry breaking. We find that the edge bands dispersion can be controlled by potentials applied on the boundary with unit cell length scale. Under certain boundary potentials, gapless edge states with valley-dependent velocity ar…

Graphene research and applicationsQuantum and electron transport phenomenaTopological Materials and Phenomena

Nanotechnology for parasitic plant control

Alejandro Pérez‐de‐Luque、Diego Rubiales2009-03-02OpenAlex

The field of nanotechnology opens up novel potential applications for agriculture. Nanotechnology applications are already being explored and used in medicine and pharmacology, but interest for use in crop protection is just starting. The development of nanodevices as smart delivery systems to target specific sites an…

Nanoparticles: synthesis and applicationsQuantum Dots Synthesis And PropertiesLegume Nitrogen Fixing Symbiosis

Understanding the Molecule−Surface Chemical Coupling in SERS

Seth M. Morton、Lasse Jensen2009-03-02OpenAlex

The enhancement mechanism due to the molecule-surface chemical coupling in surface-enhanced Raman scattering (SERS) has been characterized using time-dependent density functional theory. This has been achieved with a systematical study of the chemical enhancement of meta- and para-substituted pyridines interacting wit…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications

Complementary Media Invisibility Cloak that Cloaks Objects at a Distance Outside the Cloaking Shell

Yun Lai、Huanyang Chen、Zhao-Qing Zhang 等 4 位作者2009-03-02OpenAlex

Based on the concept of complementary media, we propose an invisibility cloak operating at a finite frequency that can cloak an object with a prespecified shape and size within a certain distance outside the shell. The cloak is comprised of a dielectric core and an "antiobject" embedded inside a negative index shell.…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Self-Organized Porphyrinic Materials

Charles Michael Drain、Alessandro Varotto、Ivana Radivojevic2009-03-02OpenAlex

The self-assembly and self-organization of porphyrins and related macrocycles enables the bottom-up fabrication of photonic materials for fundamental studies of the photophysics of these materials and for diverse applications. This rapidly developing field encompasses a broad range of disciplines including molecular d…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresSurface Chemistry and Catalysis

Rhapontikrhabarberwurzel zur Behandlung von menopausalen Beschwerden

Marietta Kaszkin-Bettag、Günter Vollmer、Reinhard Rettenberger 等 4 位作者2009-03-01Erfahrungsheilkunde

Der Extrakt ERr 731 aus der Rhapontikrhabarberwurzel wird bei Menopausenbeschwerden eingesetzt. Zwei placebokontrollierte Doppelblindstudien mit perimenopausalen Frauen belegen eine signifikante Reduktion der Beschwerden. Beobachtungsstudien zeigen keine Endometriumhyperplasie oder Zunahme der Brustdichte. Wirksamkeit…

Phytochemistry and Bioactive Compounds

Insulation impregnation quality rating for electric motors windings by utrasonic and vacuum-filling methods

N. I. Berezinets、V. I. Korotkov、L. V. Rodova 等 4 位作者2009-03-01Russian Electrical Engineering

Results are presented of comparative trials of insulation systems in traction motor armature impregnated by compounds using ultrasonic and vacuum-filling methods. The advantages of vacuum-filling impregnation are shown and the main trends in the revision of equipment and technology for the ultrasonic method are determ…

Industrial Engineering and TechnologiesEngineering Technology and MethodologiesMaterial Properties and Applications

FMR studies of half metallic ferromagnetic thin films Co2MnSn and Co2MnGe

Resul Yilgin、S. Kazan、Bulat Rameev 等 5 位作者2009-03-01Journal of Physics Conference Series

Thin films of Heusler alloys Co 2 MnSn and Co 2 MnGe prepared on sapphire a -plane substrates by RF-sputtering have been investigated by ferromagnetic resonance (FMR) technique. The magnetic anisotropies of the Co 2 MnSn and Co 2 MnGe thin films have been probed and the effective magnetization values have been extract…

Magnetic properties of thin filmsSemiconductor materials and interfacesHeusler alloys: electronic and magnetic properties

Observation of magnetocaloric effect in the LaMn1.9Fe0.1Si2compound at low fields in the vicinity of phase transition around room temperature

O. Nane、Hasan Ağıl、Berdan Özkurt 等 5 位作者2009-03-01Journal of Physics Conference Series

Low field magnetic and magnetocaloric properties of the compound LaMn 1.9 Fe 0.1 Si 2 have been investigated. Using the M-H data measured at various temperatures, we have derived the magnetic entropy change | ΔS | as a function of temperature and magnetic field, by using the Maxwell relation. The temperature dependenc…

High-pressure geophysics and materialsMagnetic and transport properties of perovskites and related materialsRare-earth and actinide compounds

Interplay of 3d and 4f magnetism in RCrSb3

Manjusha Inamdar、S. Ramakrishnan、A. Thamizhavel 等 4 位作者2009-03-01Journal of Physics Conference Series

RCrSb 3 crystallizes in a quasi two dimensional structure with RSb and CrSb 2 layers stacked along a axis. This system displays rich magnetic structure due to complex magnetic interaction between 3d moments of Cr and 4f moments of rare earth ion. In this work, we present a comparative study on the heat capacity of R(L…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsHeusler alloys: electronic and magnetic properties

First report of Protokeelia spinifera and Rhopalodia iriomotensis from China, with comments on their systematic positions

Yang Li、Yahui Gao、Songhui Lü2009-03-01Journal of Systematics and Evolution

Abstract Protokeelia is described as a new and rare pennate diatom genus in China. Its valve includes two parts: ventral valve and dorsal valve. The ventral valve is more or less convex or concave. The raphe runs in a distinct elevated and thickened siliceous ridge. In the internal valve, beneath the raphe are fibulae…

Marine Biology and Ecology ResearchDiatoms and Algae ResearchAquatic Invertebrate Ecology and Behavior

Comparability of Electroultrafiltration and Ammonium Acetate–Lactate Extraction Data for Phosphorus and Potassium in Pseudogley Soils

Tihana Teklić、Vladimir Vukadinović、Blaženka Bertić 等 4 位作者2009-03-01Communications in Soil Science and Plant Analysis

The aim of this research was to compare two standardized soil extraction methods [electroultrafiltration (EUF) and ammonium acetate–lactate (AL)] regarding potassium (K) and phosphorus (P) availability in pseudogley soils. In total, 60 pseudogley soil samples from 12 agricultural sites in eastern Croatia (each represe…

Soil Carbon and Nitrogen DynamicsClay minerals and soil interactionsAgriculture, Soil, Plant Science

Kinetics of the thermal decomposition of 1,2-dioxaspiro[2,5]octane

С. А. Грабовский、Е. А. Марков、Е. Г. Галкин 等 4 位作者2009-03-01Kinetics and Catalysis

The products and kinetics of the thermolysis of 1,2-dioxaspiro[2,5]octane in cyclohexanone and cyclohexanone-CCl 4 mixtures are studied. 1,2-Dioxaspiro[2,5]octane is consumed via two parallel routes: isomerization to oxepan-2-one and solvent (cyclohexanone) oxidation with the partial escape of radicals from the cage (…

Chemical Reaction MechanismsThermal and Kinetic AnalysisChemical Thermodynamics and Molecular Structure

Identification of peroxo groups in supramolecular layered structures as probed by Raman spectroscopy

T. A. Tripol’skaya、I. V. Pokhabova、Petr V. Prikhodchenko 等 6 位作者2009-03-01Russian Journal of Inorganic Chemistry

Peroxide-containing supramolecular structures prepared by reacting lithium aluminum layered double hydroxides (Li-Al LDHs) with concentrated hydrogen peroxide solutions were characterized by Raman spectroscopy. These compounds were formulated as [LiAl 2 (OH) 6 ](OH) · H 2 O 2 · H 2 O(I) and [LiAl 2 (OH) 6 ](OOH) · H 2…

Polyoxometalates: Synthesis and ApplicationsLayered Double Hydroxides Synthesis and ApplicationsThermal Expansion and Ionic Conductivity

Mysterious charge ordering on θ-(BEDT-TTF)2RbZn(SCN)4

Tsuyoshi Takeno、Kei Kobayashi、Yutaka Nishio 等 6 位作者2009-03-01Journal of Physics Conference Series

We have performed thermal studies of a charge disproportionation induced metal-insulator transition in θ-(BEDT-TTF) 2 RbZn(SCN) 4 system. We have detected a sharp peak in a heating process and a broad hump in a cooling process with a remarkable hysteresis. This peculiar transition could be easily suppressed by a rapid…

Magnetism in coordination complexesOrganic and Molecular Conductors ResearchSolid-state spectroscopy and crystallography

Preparation of Ca2Ti2O6pyrochlore films by MOCVD

Yuanwei Zhang、Jie Yu、Rong Tu 等 4 位作者2009-03-01Journal of Physics Conference Series

Ca-Ti-O films were prepared on quartz substrates by MOCVD using the precursors of Ti(O-i-Pr) 2 (dpm) 2 and Ca(dpm) 2 . The effects of deposition conditions on the crystal structure and microstructure of Ca-Ti-O films were investigated. The deposition temperatures (T dep ) were changed from 787 to 1187 K and the total…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisNuclear materials and radiation effects