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Nanoblends of Incompatible Polymers by Direct Space-Confined Polymerization

Shu‐Hua Chan、Yiyang Lin、Ching Ting2003-11-01Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTNanoblends of Incompatible Polymers by Direct Space-Confined PolymerizationShu-Hua Chan, Yi-Yang Lin, and Ching TingView Author Information Union Chemical Laboratories, Industrial Technology Research Institute, 321 Kuang-Fu Road, Se…

Mesoporous Materials and CatalysisPolymer Surface Interaction StudiesBlock Copolymer Self-Assembly

Selectivities of Potassium‐Calcium and Potassium‐Lead Exchange in Two Tropical Soils

Chip Appel、Q. Lena、R. D. Rhue 等 4 位作者2003-11-01Soil Science Society of America Journal

Measurement of cation selectivity in soils provides important information about the affinity and binding strength of a particular cation on soil surfaces. Gaines‐Thomas ( K GT ) selectivity coefficients were determined for a variety of K/Ca and K/Pb ratios on an Oxisol and Ultisol soil from Puerto Rico. The calculated…

Heavy metals in environmentClay minerals and soil interactions

Transcrystallinity in Surface Modified Aramid Fiber Reinforced Nylon 66 Composites

Alexander Y. Feldman、M. Fernanda González、G. Marom2003-11-01Macromolecular Materials and Engineering

Abstract Aramid (kevlar‐49) fibers were surface treated by two different methods to induce roughness and then used to produce unidirectional nylon 66 based composites. The transcrystallinity generated around the treated fibers was characterized by SEM and polarized light microscopy and compared with the regular transc…

Polymer crystallization and propertiesNatural Fiber Reinforced CompositesFiber-reinforced polymer composites

Electronic structure of neutral silicon-vacancy complex in diamond

S. S. Moliver2003-11-01Technical Physics

Quantum-chemical open-shell method with parametrization INDO is used to construct the model of a large unit cell for the [Si- V ] 0 impurity complex in diamond. It is shown that the ground spin-triplet state of the complex exerts tunnel (rather than Jahn-Teller) splitting associated with off-center shift of Si atom al…

High-pressure geophysics and materialsDiamond and Carbon-based Materials ResearchForce Microscopy Techniques and Applications

Growth of a dense polymer brush layer from solution

Michael Himmelhaus、T Bastuck、S. Tokumitsu 等 6 位作者2003-11-01Europhysics Letters (EPL)

The chemical grafting of alkanethiol-terminated poly(ethylene glycol) to a gold substrate from dimethylformamide solution was monitored by in situ ellipsometry for several molar concentrations. In the initial stage a layer of mushroom-like moieties forms and, on a much longer time scale, is followed by conformational…

Polymer Surface Interaction StudiesMolecular Junctions and NanostructuresForce Microscopy Techniques and Applications

Spectroscopic ellipsometry of metal phthalocyanine thin films

Aleksandra B. Djurišić、C.Y. Kwong、Tsz Wai Lau 等 7 位作者2003-11-01Applied Optics

Optical functions of cobalt phthalocyanine, nickel phthalocyanine (NiPc), and iron phthalocyanine (FePc) have been determined by use of spectroscopic ellipsometry in the spectral range 1.55-4.1 eV (300-800 nm). The samples were prepared by evaporation onto glass and silicon substrates. The optical functions were deter…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesSpectroscopy and Quantum Chemical Studies

Vertically aligned carbon nanotubes grown by plasma enhanced chemical vapor deposition

Hideki Sato、Hitoshi Takegawa、Yahachi Saito2003-11-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

Plasma enhanced chemical vapor deposition, which enables growth of carbon nanotubes directly onto substrates, is potentially suitable for preparing carbon nanotubes as electron sources in field emission displays. In this article, we report the growth of aligned carbon nanotubes by microwave plasma enhanced chemical va…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

Synthesis of Poly(ester amide)s Derived from Glycolic Acid and the Amino Acids: β‐Alanine or 4‐Aminobutyric Acid

Alfonso Rodríguez‐Galán、Montserrat Vera、Katia Jiménez 等 5 位作者2003-11-01Macromolecular Chemistry and Physics

Abstract The polymerization of metal salts of N ‐chloroacetyl‐ β ‐alanine and N ‐chloroacetyl‐4‐aminobutyric acid was investigated. The former gives a mixture of polymer and a seven‐membered cyclic compound constituted of glycolic and β ‐alanine units, and its reaction proceeds in the solid state. However, liquefactio…

biodegradable polymer synthesis and propertiesSynthesis and properties of polymersAntimicrobial agents and applications

Recent progress in applications of ligand‐stabilized metal nanoclusters

Naoki Toshima2003-11-01Macromolecular Symposia

Abstract Due to a nanotechnology boom in science and technology, the metal nanoclusters or nanoparticles stabilized by polymers and organic ligands have achieved much attention recently all over the world. We have studied on the preparation of polymer‐stabilized metal nanoclusters by chemical methods, and applied them…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis

Differential Pulse Polarographic and UV‐Vis Spectrophotometric Study of Inclusion Complexes Formed by 1,4‐Dihydropyridine Calcium Antagonists, Nifedipine and Nicardipine with β‐Cyclodextrin

Claudia Yáñez、Luis J. Núñez‐Vergara、J.A. Squella2003-11-01Electroanalysis

Abstract The formation of inclusion complexes of well‐known 1,4‐dihydropyridine calcium antagonists, such as nifedipine (NF) and nicardipine (NC), with β‐cyclodextrin (βCD) was investigated by differential pulse polarography (DPP) and UV‐vis spectrophotometry. The equimolar variation method indicated the formation of…

Multicomponent Synthesis of HeterocyclesNonlinear Optical Materials ResearchAnalytical Methods in Pharmaceuticals

Insulator-Coated Carbon Nanotubes Synthesized by Pulsed Laser Deposition

Takashi Ikuno、Mitsuhiro Katayama、Kazunori Kamada 等 7 位作者2003-11-01Japanese Journal of Applied Physics

We present a method for synthesizing insulator-coated carbon nanotubes by pulsed laser deposition. Isolated multi-walled carbon nanotubes (MWNTs) were coated with an SiO x thin layer in a multishell form. The product showed that a stoichiometric SiO 2 thin layer was uniformly wrapped around a MWNT, and reflected the s…

Carbon Nanotubes in CompositesGraphene research and applicationsDiamond and Carbon-based Materials Research

Aluminum Effect on Dissolution and Precipitation under Hyperalkaline Conditions

Nikolla Qafoku、Calvin C. Ainsworth、James E. Szecsody 等 4 位作者2003-11-01Journal of Environmental Quality

Substantial amounts of self-boiling, Al-rich, hyperalkaline, and saline high-level waste fluids (HLWF) were deposited to the vadose zone at the Hanford Site, in Washington State. The objective of this study was to investigate the effects of similar fluids on the extent of dissolution and precipitation in the sediments…

Groundwater and Isotope GeochemistryClay minerals and soil interactionsMine drainage and remediation techniques

Effect of Yarn Hairiness on Energy Consumption in Rotating a Ring-Spun Yarn Package

Lingli Chang、Zheng-Xue Tang、Xungai Wang2003-11-01Textile Research Journal

The effect of yarn hairiness on energy consumption when rotating a ring-spun yarn package is investigated theoretically and experimentally. A theoretical model is developed to calculate the energy required to rotate hair fibers, based on hair length and number as well as package speed and size. A single spindle test r…

Textile materials and evaluationsStructural Analysis and OptimizationMaterial Properties and Processing

Carbon isotope “stratigraphy” in a single graphite crystal: Implications for the crystal growth mechanism of fluid-deposited graphite

M. Santosh、Hideki Wada、M. Satish‐Kumar 等 4 位作者2003-11-01American Mineralogist

A 2 cm long and 0.8 cm thick, single graphite crystal embedded in quartz, feldspar, and orthopyroxene of a granulite-facies metamorphic rock from southern India exhibits unique homogeneity in δ 13 C values along layers parallel to the (0001) surface and smooth unidirectional variation of about 1‰ along the c-crystallo…

Radioactive element chemistry and processingClay minerals and soil interactionsGraphite, nuclear technology, radiation studies

N‐(2‐Hydroxypropyl)methacrylamide (HPMA) Copolymer‐Linked Nitroxides: Potential Magnetic Resonance Contrast Agents

Yuan Huang、Anjan Nan、Gerald M. Rosen 等 7 位作者2003-11-01Macromolecular Bioscience

Abstract N ‐(2‐Hydroxypropyl)methacrylamide (HPMA) copolymer‐linked nitroxides were synthesized as macromolecular contrast agents for MR imaging. Molar relaxivities of HPMA copolymer‐linked nitroxides increased linearly in proportion to the number of nitroxides attached per gram of copolymer. HPMA copolymer‐linked nit…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Magnetic force control with composite of giant magnetostrictive and piezoelectric materials

Tasuku Ueno、Jinhao Qiu、Junji TANI2003-11-01IEEE Transactions on Magnetics

We propose a new magnetic force control device, composed of a giant magnetostrictive material (Terfenol-D) and a piezoelectric material (PZT), for coilless magnetic force control. The device uses the inverse magnetostrictive effect, whereby the variation of magnetization of a Terfenol-D rod controlled by PZT is conver…

Phase Change Materials ResearchMagnetic Properties and Applications

Novel Thermoplastic Elastomers Based on Acrylonitrile-Butadiene-Styrene Terpolymer (ABS) from Waste Computer Equipment and Nitrile Rubber

S. Anandhan、P. P. De、S. K. De 等 5 位作者2003-11-01Rubber Chemistry and Technology

Abstract Acrylonitrile-butadiene-styrene terpolymer (ABS) is one of the engineering plastics most frequently used as outer casings for computer equipment such as monitors, keyboards and other similar components. In an attempt to recycle, blends of scrap computer plastics (SCP) based on ABS with nitrile rubber (NBR) we…

Advanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and PropertiesPolymer Science and PVC

Influence of Varying Structural Parameters on Abrasion Characteristics of 50/50 Wool/Polyester Blended Fabrics

Fatma Kalaoğlu、Emel Önder、Bülent Özipek2003-11-01Textile Research Journal

This paper reports an analysis of the influence of polyester and yarn type on the abrasion resistance of 50/50 wool/polyester blended woven fabrics. Recently developed polyester fibers put into the blend and two-strand Sirospun yams are compared with 2.5 denier standard polyester and two-fold ring yarns. Mass losses o…

Mechanical Behavior of CompositesDyeing and Modifying Textile FibersTextile materials and evaluations

Selective Selenate Adsorption on Cationated Amino-Functionalized MCM-41

Toshiyuki Yokoi、Takashi Tatsumi、Hideaki Yoshitake2003-11-01Bulletin of the Chemical Society of Japan

Abstract A large distribution coefficient and large sorption capacity were observed during selenate adsorption by cation (Fe3+, Cu2+, and H+)-anchored diamino-functionalized MCM-41. Moreover, these synthetic adsorption media showed excellent selectivity for selenate sorption in the presence of other anions. In a pure…

Adsorption and biosorption for pollutant removalMesoporous Materials and CatalysisChemical Synthesis and Characterization

Structural Characterization and Properties of Lyocell Fibers After Fibrillation and Enzymatic Defibrillation Finishing Treatments

F. Carrillo、X. Colom、J. Valldeperas 等 6 位作者2003-11-01Textile Research Journal

The mechanical, structural, and dyeing properties of solvent-spun lyocell fibers in a plain weave fabric are studied before and after industrial treatments of mechanical fibrillation and enzymatic defibrillation. Stress-strain relationships, surface morphology, crystallinity, and dye uptake are assessed for each of th…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesAgricultural and Food Sciences