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Quantum-Hall Activation Gaps in Graphene

A. J. M. Giesbers、U. Zeitler、M. I. Katsnelson 等 6 位作者2007-11-14Physical Review Letters

We have measured the quantum-Hall activation gaps in graphene at filling factors $\ensuremath{\nu}=2$ and $\ensuremath{\nu}=6$ for magnetic fields up to 32 T and temperatures from 4 to 300 K. The $\ensuremath{\nu}=6$ gap can be described by thermal excitation to broadened Landau levels with a width of 400 K. In contra…

Magnetic Field Sensors TechniquesGraphene research and applicationsQuantum and electron transport phenomena

Impact of a Superhydrophobic Sphere onto Water

Duck-Gyu Lee、Ho‐Young Kim2007-11-14Langmuir

When a water drop hits a superhydrophobic solid surface, it bounces off the substrate like an elastic ball. Here we show that when a tiny superhydrophobic solid sphere impacts with water, it can bounce off the free surface just as it impacts with an elastic membrane. The motion of a sinking sphere is analytically calc…

Fluid Dynamics and Heat TransferElectrohydrodynamics and Fluid DynamicsSurface Modification and Superhydrophobicity

Strong UV absorption and visible luminescence in ytterbium-doped aluminosilicate glass under UV excitation

Magnus Engholm、Lars Norin、Daniel Åberg2007-11-14Optics Letters

A broad visible luminescence band and characteristic IR luminescence of Yb(3+) ions are observed under UV excitation in ytterbium-doped aluminosilicate glass. Samples made under both oxidizing and reducing conditions are analyzed. A strong charge-transfer absorption band in the UV range is observed for glass samples c…

Advanced Fiber Optic SensorsGlass properties and applicationsPhotonic Crystal and Fiber Optics

Studies on the resonance Raman spectra of polyaniline obtained with near‐IR excitation

Gustavo M. do Nascimento、Márcia L. A. Temperini2007-11-14Journal of Raman Spectroscopy

Abstract The effects of near‐IR (NIR) laser power over the Raman spectra of poly(aniline) emeraldine salt (PANI‐ES) and base (PANI‐EB) were investigated. The reasons for the existence of several bands from 1324 to 1500 cm −1 in the Raman spectra of poly(aniline) obtained at NIR region were also studied. The bands from…

Conducting polymers and applicationsAnalytical Chemistry and SensorsOrganic Electronics and Photovoltaics

Continuum theory for piezoelectric response of chiral nanotubes under uniaxial and torsional stresses

Paul J. Michalski、E. J. Melé2007-11-14Physical Review B

We develop and solve a continuum theory for the piezoelectric response of nanotubes under applied uniaxial and torsional stresses. We find that the piezoelectric response is controlled by the chiral angle, the aspect ratio, and two dimensionless parameters specifying the ratio of the strengths of the electrostatic and…

Mechanical and Optical ResonatorsThermal properties of materialsBoron and Carbon Nanomaterials Research

Spontaneous resolution of a 3D chiral polyoxometalate-based polythreaded framework consisting of an achiral ligand

Ya‐Qian Lan、Shun‐Li Li、Zhong‐Min Su 等 7 位作者2007-11-14Chemical Communications

Two enantiomerically 3D chiral POM-based architectures have been constructed based on the achiral ligand bbi, [V10O26](4-) polyoxoanion and mixed valence Cu(I/II) without a chiral auxiliary, and they represent the first examples of enantiomerically 3D POM-based compounds using achiral ligands.

Advanced Nanomaterials in CatalysisMetal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and Applications

Surface polaritons on left-handed spheres

Stéphane Ancey、Yves Décanini、Antoine Folacci 等 4 位作者2007-11-14arXiv

We consider the interaction of an electromagnetic field with a left-handed sphere, i.e., with a sphere fabricated from a left-handed material, in the framework of complex angular momentum techniques. We emphasize more particularly, from a semiclassical point of view, the resonant aspects of the problem linked to the e…

physics.opticsMaterials Science

Magnetic Nanoparticles Grafted with Cyclodextrin for Hydrophobic Drug Delivery

Shashwat S. Banerjee、Dong‐Hwang Chen2007-11-14Chemistry of Materials

A novel magnetic nanocarrier, cyclodextrin (CD)−citrate−gum arabic modified magnetic nanoparticles (GAMNPs), for hydrophobic drug delivery was fabricated by grafting the citrate-modified CD onto the GAMNPs via carbodiimide activation. The analyses of the transmission electron microscopy and the dynamic light scatterin…

Nanoparticle-Based Drug DeliveryDendrimers and Hyperbranched PolymersAdvanced Drug Delivery Systems

Conjugated microporous poly(phenylene butadiynylene)s

Jia‐Xing Jiang、Fabing Su、Hongjun Niu 等 7 位作者2007-11-14OpenAlex

High surface area porous poly(phenylene butadiynylene) networks were obtained (BET surface area up to 842 m(2) g(-1)) by the palladium-catalyzed homocoupling of 1,3,5-triethynylbenzene and 1,4-diethynylbenzene.

Luminescence and Fluorescent MaterialsMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework Applications

Graphene Transistors Fabricated via Transfer-Printing In Device Active-Areas on Large Wafer

Xiaogan Liang、Zengli Fu、Stephen Y. Chou2007-11-14OpenAlex

We demonstrate a method that uses the pillars on a stamp to cut and exfoliate graphene islands from a graphite and then uses transfer printing to place the islands from the stamp into the device active-areas on a substrate with a placement accuracy potentially in nanometers. The process can be repeated to cover all de…

Graphene research and applicationsAdvancements in Semiconductor Devices and Circuit DesignQuantum and electron transport phenomena

Aggregation‐induced Emission (AIE)‐active Starburst Triarylamine Fluorophores as Potential Non‐doped Red Emitters for Organic Light‐emitting Diodes and Cl2 Gas Chemodosimeter

Zhijun Ning、Z. Chen、Qian Zhang 等 7 位作者2007-11-14OpenAlex

Abstract A new series of starburst triarylamine fluorophores SBCHO, DBCHO, CZCHO, CZCN, and SBCN, that incorporate diphenylamine or carbazole as the electron donor and dicyanovinyl or aldehyde as the electron acceptor, has been prepared and their photophysical properties are investigated. In sharp contrast to most red…

Molecular Sensors and Ion DetectionOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

A self-consistent theory for graphene transport

Shaffique Adam、E. H. Hwang、Victor Galitski 等 4 位作者2007-11-14OpenAlex

We demonstrate theoretically that most of the observed transport properties of graphene sheets at zero magnetic field can be explained by scattering from charged impurities. We find that, contrary to common perception, these properties are not universal but depend on the concentration of charged impurities n(imp). For…

Surface and Thin Film PhenomenaQuantum and electron transport phenomenaGraphene research and applications

Superhydrophobic surfaces: from structural control to functional application

Xi Zhang、Feng Shi、Jianjun Niu 等 5 位作者2007-11-14OpenAlex

A superhydrophobic surface is a surface with a water contact angle close to or higher than 150°. In this feature article, we review the historical and present research on superhydrophobic surfaces, including the characterization of superhydrophobicity, different ways to fabricate rough surfaces, and low-surface-energy…

Adhesion, Friction, and Surface InteractionsSurface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting Materials

On-site approximation for spin–orbit coupling in linear combination of atomic orbitals density functional methods

F Fernández-Seivane、M A Oliveira、S Sanvito 等 4 位作者2007-11-13Journal of Physics Condensed Matter

We have been kindly informed of some minor errors in the above paper. (1) On page 8003 equation (15) is not correct. The correct formulae (and the ones actually programmed) are shown in the pdf file. Since the correct formulae were employed in the program, all the results are correct. This mistake was pointed out by H…

Advanced NMR Techniques and ApplicationsAdvanced Chemical Physics StudiesMagnetism in coordination complexes

Neighbor network in a polydisperse hard-disk fluid: Degree distribution and assortativity

Alexandros Chremos、Philip J. Camp2007-11-13Physical Review E

The neighbor network in a two-dimensional polydisperse hard-disk fluid with diameter distribution p(sigma) approximately sigma(-4) is examined using constant-pressure Monte Carlo simulations. Graphs are constructed from vertices (disks) with edges (links) connecting each vertex to k neighboring vertices defined by a r…

Phase Equilibria and ThermodynamicsTheoretical and Computational PhysicsMaterial Dynamics and Properties

Effects of quasi‐nanogel particles on the rheological and mechanical properties of natural rubber: A new insight

Suman K. Mitra、Santanu Chattopadhyay、Anil K. Bhowmick2007-11-13Journal of Applied Polymer Science

Abstract The influence of sulfur‐crosslinked, quasi‐nanosized gels on the rheological and mechanical properties of raw natural rubber (NR) was investigated. Latex gels with different crosslink densities were prepared through the variation of the sulfur‐to‐accelerator ratio. These gels were characterized by dynamic lig…

Rheology and Fluid Dynamics StudiesPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Preparation and mechanical properties of acrylonitrile‐butadiene‐styrene copolymer/clay nanocomposites

Hun‐Sik Kim、Byung Hyun Park、Jae Hoon Choi 等 4 位作者2007-11-13Journal of Applied Polymer Science

Abstract Bis(3‐triethoxysilylpropyl) tetrasulfane (TSS) was reacted with the silanol groups of the commercially available clay, Closite®25A (C25A) to prepare TSS‐C25A, which was melt‐compounded with acrylonitrile‐butadiene‐styrene copolymer (ABS). The tetra sulfide groups of TSS‐C25A may chemically react with the viny…

Flame retardant materials and propertiesPolymer Nanocomposites and PropertiesSynthesis and properties of polymers

Divergent Approach for Synthesis and Terminal Modifications of Dendritic Polyphenylazomethines

Kensaku Takanashi、Kimihisa Yamamoto2007-11-13Organic Letters

In the past, dendritic polyphenylazomethines (DPA) have been synthesized via the convergent method. However, the convergent method has problems such as difficult terminal-group modifications and an increased number of steps. Therefore, we synthesized the terminal-protected DPA to construct the dendritic structure via…

Dendrimers and Hyperbranched PolymersRNA Interference and Gene DeliveryChemical Synthesis and Analysis

Synthesis and characterisation of new titanium amino-alkoxides: precursors for the formation of TiO 2 materials

Nathan Hollingsworth、Miki Kanna、Gabriele Kociok‐Köhn 等 5 位作者2007-11-13Dalton Transactions

Reaction of the amino-alkoxides HOCH(CH(2)NMe(2))(2) (Hbdmap) and HOC(CH(2)NMe(2))(3) (Htdmap) with [Ti(OR)(4)] yields a series of heteroleptic titanium alkoxides [Ti(OR)(4-n)(L)(n)] (L = bdmap, tdmap). Substitution of the monodentate alkoxide with the chelating alkoxides becomes progressively more difficult, with hom…

Polyoxometalates: Synthesis and ApplicationsOrganometallic Complex Synthesis and CatalysisCoordination Chemistry and Organometallics

The effect of crosslinker structure upon the rate of hydroperoxide formation in dried, crosslinked poly(vinylpyrrolidone)

Michael A. Tallon、Edward Malawer、N. I. Machnicki 等 6 位作者2007-11-13Journal of Applied Polymer Science

Abstract The hydroperoxide levels of two commercial types of crosslinked poly(vinylpolypyrrolidinone) (or crospovidone) disintegrants were studied as a function of time and temperature using the titanyl sulfate titration method. It was noted that the two crospovidone types exhibited significantly different rates of hy…

Synthesis and properties of polymersPolymer Nanocomposites and PropertiesSilicone and Siloxane Chemistry