Materials Literature
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The reaction of triethanolamine (teaH(3)) with [Fe(III)(3)O(O(2)CCH(3))(6)(H(2)O)(3)]Cl·6H(2)O and Ln(NO(3))(3)·6H(2)O in acetonitrile yields [Fe(16)Ln(4)(tea)(8)(teaH)(12)(μ-O(2)CCH(3))(8)](NO(3))(4)·16H(2)O·xMeCN (Ln = Sm (1), Eu (2), Gd (3), Tb (4), Dy (5), Ho (6); x = 10 or 11). These 20-membered metallo-ring comp…
The state-of-the-art theoretical evaluation and rationalization of the magnetic interactions (J(AB)) in molecule-based magnets is discussed in this critical review, focusing first on isolated radical···radical pair interactions and afterwards on how these interactions cooperate in the solid phase. Concerning isolated…
In this communication, we report on acid-driven, microwave-assisted production of fluorescent carbon nitride dots (CNDs) on a large scale by microwave irradiation of N,N-dimethylformamide (DMF) solution in the presence of acids including chlorosulfonic acid (CSA), H2SO4, HCl, or HNO3. It suggests these CNDs are well w…
Novel luminescent silver nanoclusters (AgNCs) were synthesized utilizing DNA as templates by a simple, rapid and one-pot procedure. Luminescence studies indicated that these DNA-AgNCs exhibited strong emission with peak maximum at 624 nm. The fluorescence of the DNA-AgNCs was found to be quenched by Cu(2+) enabling it…
The optical use of colloidal silicon nanocrystals (Si NCs) has gained increasing attention for its possible contributions to building a sustainable society that ideally uses resources and energy with high efficiency without causing damage to the environment or human health. Si wafers (E(g) ≈ 1.1 eV) dominate modern mi…
The synthesis of graphene paper with controllable properties via chemical reduction of exfoliated graphene oxides was investigated. UV-Vis absorption spectra, elemental analysis, FT-IR spectra, X-ray diffraction (XRD), thermo-gravimetric analysis (TGA), mechanical analysis, electrical conductivity and cyclic voltammet…
The increasing need for biodegradable polymers in medical applications, attempts to use renewable resources instead of fossil resources for material synthesis, and highly efficient polymerization methods that meet the requirements of green chemistry draw attention to fatty acid-based biodegradable polymers. In the pre…
A newly developed method for the edge-selective functionalization of “pristine” graphite with 4-aminobenzoic acid was applied for the synthesis of 4-aminobenzoyl-functionalized graphite (AB-graphite) through a “direct” Friedel–Crafts acylation in a polyphosphoric acid (PPA)/phosphorus pentoxide medium (P2O5). The AB m…
A series of composites containing resorcinol-formaldehyde resin and graphene oxide was prepared by a sol–gel process. The composites were pyrolyzed in an inert atmosphere to form graphene sheet-containing activated carbon (AC) by using an excess amount of KOH as an activating agent. The chemical structure, physical pr…
Monodisperse cubic-phase KYF(4) : Eu(3+) nanocrystals (NCs) were synthesized via a modified thermal decomposition method. The optical properties of Eu(3+) in KYF(4) NCs including multiple luminescence centers, site symmetry, luminescence dynamics, as well as crystal-field levels of Eu(3+) were investigated in detail b…
Here we report the colloidal synthesis of size-tunable SnS nanocrystals that have an unusual meta-stable cubic zinc-blende phase instead of the more stable layered orthorhombic phase. The single-crystalline zinc-blende SnS nanocrystals with sizes of 8 nm, 60 nm, and 700 nm were achieved by injecting the sulfur-oleylam…
A single-chain magnet consisting of Co(II) chains with (EO-N(3))(2) and (μ-COO)(2)(μ-EO-N(3)) bridges reversibly transforms into an antiferromagnetic phase with metamagnetic character and modified slow magnetic relaxation upon dehydration.
This article describes recent advances that have been made in the development of methods for post-grafting of silica surfaces using functionalized organosilanes. While procedures employing conventional trialkoxysilane precursors have been utilized to immobilize organic and biological molecules onto inorganic supports,…
Arrays of ZnO nanorods (NRs) were successfully converted into nanotubes (NTs), used as photoelectrodes in photoelectrochemical (PEC) cells after their sensitization with CdSe quantum dots (QDs) and a strong correlation between the PEC performance and geometrical structure of ZnO NTs@CdSe(QDs) and ZnO NRs@CdSe(QDs) was…
The polystyrene–chemically converted graphene composite (PS-CCG) prepared by solution blending followed by compression molding, exhibited a percolation threshold as low as 0.19 vol.% and an electrical conductivity as high as 72.18 S m−1 at only ∼2.45 vol.%. The superior electrical conductivity of PS-CCG is the result…
Vertically aligned ZnO nanowires (NWs) with a length of 1.5–10 μm and a mean diameter of ca. 150 nm were grown by chemical vapour deposition onto a c-oriented ZnO seed layer which was deposited by atomic layer deposition on Si substrates. The substrates were then spin-coated with an ethanol solution containing Pd nano…
Bucky gels are gelatinous composite materials consisting of carbon nanotubes and ionic liquids. This article gives an overview of some promising applications of bucky gels reported mostly in the last few years and a possible extension to the dispersion of graphene sheets.
BACKGROUND: Stem cell therapy has emerged as a promising addition to traditional treatments for a number of diseases. However, harnessing the therapeutic potential of stem cells requires an understanding of their fate in vivo. Non-invasive cell tracking can provide knowledge about mechanisms responsible for functional…
Single-stranded RNAs host fluorescent silver nanoclusters, analogous to previously studied Ag:DNAs. C and G homopolymers stabilize visible- to IR-emitting silver complexes at neutral pH in both RNA and DNA, but A and T/U do not. Cluster fluorescence is sensitive to sugar as well as base type.
A bifunctional imidazolium linker was used for the production of highly crosslinked element organic frameworks by Suzuki-coupling with tetrafunctional boronic acids. The resulting porous materials are good heterogeneous organocatalysts in the N-heterocyclic carbene-catalyzed conjugated umpolung of α,β-unsaturated cinn…