Materials Literature
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Poly(γ-benzyl l -glutamate) (PBLG) was bonded covalently to a flat substrate, and it formed an aligned dipole layer (PBLG−CRA film). Using the PBLG−CRA film as an orienting film for a nematic hydrogen-bonded liquid crystalline complex, 6OBA−9Py (formed from 4-(hexyloxy)benzoic acid (6OBA) and 4-nonylpyridine (9Py)), c…
The anomalous responses of M w to conversion and to comonomer stoichiometry, i.e., deviations from expected classic A−A + B−B step-growth polycondensation behavior, observed in poly( p -phenylene sulfide) synthesis from p -dichlorobenzene and sodium sulfide are shown to be a consequence of unequal rate constants for t…
Particle morphologies for 2 and 3 wt% Pd/K L-zeolite have been determined using X-ray absorption spectroscopy (XAS). X-ray absorption near edge structure–temperature programmed reduction (XANES-TPR) was used to check for the presence of unreduced palladium cations in the locked cages after reduction. A series of calcu…
A unique desintering phenomenon has been observed in gas‐pressure sintering of silicon nitrides with additives of yttria and alumina. The desintering phenomenon occurred, simultaneous with weight increase, only when a boron nitride crucible was used in combination with the application of high nitrogen pressure (5 MPa)…
The polymorphism of sulindac was investigated. Two polymorphs (I and II) and a new crystalline form (form III) of sulindac were prepared by recrystallization in different solvents. In addition, three new pseudopolymorphs (solvates) from acetone, chloroform, and benzene were obtained, with each containing 1 mol of solv…
The development of photocured, water based, epoxy acrylate coatings to negate the deleterious effect surface flaws have on the strength of glass is reported. Strengthening of both (a) glass rods that have been damaged in a controlled fashion and (b) production line bottles is demonstrated. In both cases strengthening…
thin films of different thicknesses were deposited by the flash evaporation method onto cleaned glass plates held at room temperature. Structural characterization was carried out using x-ray diffraction and transmission electron microscopy which revealed that the films are polycrystalline and the grain size increases…
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTHigh-Pressure NMR Studies of (Porphinato)iron-Catalyzed Isobutane Oxidation Utilizing Dioxygen as the Stoichiometric OxidantKevin T. Moore, István T. Horváth, and Michael J. TherienView Author Information Department of Chemistry, University of Pennsylvania Philadelphia…
We study theoretically the deformation of polyelectrolyte brushes in strong flows of good solvent using a scaling theory which calculates the deformation of grafted chains and the solvent flow profile within the brush in a mutually consistent fashion. We consider the cases of permeation flows normal to the grafting su…
This is the first of a three-part series of papers reporting on the development of an objective method of selecting compatible fusible interlinings for different outer fabrics to achieve superior garment handle and drape in tailored garments. Part I reports on the experimental work that establishes the desirable range…
Abstract Trypsin was immobilized in quasi‐soluble polyanion‐polycation complexes with retention of the enzyme activity. The activity of the immobilized enzyme strongly depends on pH of the prepared solution, composition, relative concentrations and molar masses of the polyelectrolytes. The highest activity of trypsin…
Corrosion fatigue tests on annealed type 316 (UNS S31600) stainless steel (SS) showed the maximum stress level for failure in 0.5 M sodium chloride (NaCl) aqueous solution at pH = 4.2 was one-third lower than in air after a similar number of cycles. Crack initiation mechanisms of corrosion fatigue were studied by scan…
UV-emitting, highly soluble poly(3,5-(dodecyloxy)phenylene) ( 2 ) has been prepared by the nickel-catalyzed polymerization of 3,5-dichloro(dodecyloxy)benzene ( 1 ) in the presence of excess zinc, triphenylphosphine, and 2,2‘-bipyridine. Structural characterization by 1 H and 13 C NMR spectroscopy agrees with the propo…
Abstract A study has been made of changes in residual stress distributions caused by weathering in polypropylene and polystyrene. Chemi‐crystallization has a major effect in polypropylene and an analysis based on the volumetric changes that occur on crystallization has been developed. Close to the surface, fractional…
An amorphous, C‐S‐H‐like phase with Ca/Si = 2 was synthesized from amorphous precipitated silica, calcium oxide, and water by mechanochemical treatment using a vibration mill at room temperature. The product was studied by XRD, 29 Si MASNMR, TEM, analytical TEM, and TGA‐DTA. After 14 h of treatment, the starting mater…
New ligands for in vivo chelation of Pu(IV) are being synthesized and evaluated in mice for efficacy and toxicity. Biokinetic studies of the new ligands, CaNa3-DTPA, and Pu(IV) are major components of those investigations. Young adult female mice were injected intravenously (iv) with 3H-inulin, 14C-CaNa3-DTPA, or 238P…
We have studied blends of polyethylene “homopolymer” (hydrogenated polybutadiene) with diblock copolymers of polyethylene-poly(ethylene- alt -propylene), E/EP, varying both homopolymer loading and the block copolymer and homopolymer molecular weights. The pure block copolymers form homogeneous melts which are miscible…
The combined physical analytical technique of thermogravimetric and infrared analysis (TG/IR) is described for the investigation of pharmaceutical solids. TG/IR provides an unequivocal identification of the volatile content of a pharmaceutical solid. In the case of pharmaceutical solvates, TG/IR provides identificatio…
TiO 2 nanocrystallites are prepared by hydrolysis of titanium tetraisopropoxide in the presence of N, N ‘-2,6-pyridinediylbis[undecamide]. The latter stabilizes the resulting semiconductor sol and provides sites at the surface of a nanocrystallite for selective binding of a uracil derivative by complementary hydrogen…
Cerium Concentration and Temperature Dependence of the Luminescence of SrGa2 S 4 : Ce , Na , a Blue‐Emitting Material for Electroluminescent and High Current Density Cathodoluminescent Displays, Ronot‐Limousin, I., Garcia, A., Fouassier, C., Barthou, C., Benalloul, P., Benoit, J.