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Fatigue of precipitate strengthened Cu–Ni–Si alloy

Scott Lockyer、F. W. Noble1999-10-01Materials Science and Technology

The fatigue resistance and tensile properties of a precipitate strengthened Cu–Ni–Si alloy have been investigated. Underaged material exhibited greater work hardening rates than either the peak aged or overaged material. It is proposed that this occurs because the δ-Ni2 Si precipitates can be cut by dislocations, but…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsAluminum Alloys Composites Properties

A detailed characterization of polyglycolide prepared by solid-state polycondensation reaction

Karsten Schwarz、Matthias Epple1999-10-01Macromolecular Chemistry and Physics

Polyglycolide (polyglycolic acid, PGA) was prepared by thermally induced solid-state polycondensation from sodium chloroacetate. This reaction leads to a composite of PGA with NaCl, out of which the latter can be extracted by washing with water. A highly porous polymer remains. The course of the reaction was followed…

biodegradable polymer synthesis and propertiesSynthesis and properties of polymersSilicone and Siloxane Chemistry

An evaluation of Re, as an alternative to Pt, for the 1 bar loop technique; an experimental study at 1400 degrees C

А. В. Борисов、J. H. Jones1999-10-01American Mineralogist

Previous investigators have shown that, at high pressure, Re is a good capsule material and that Fe loss to Re under these conditions is minimal (e.g., Herzberg and Zhang 1997). We present here the first systematic low-pressure study of Re loop stability and of Fe loss from silicate melts to Re loops as a function off…

High-pressure geophysics and materialsAdvanced Materials Characterization TechniquesMetallurgical and Alloy Processes

Crystallinity determination of native and stretched wool by X-ray diffraction

Jinan Cao、Craig A Billows1999-10-01Polymer International

A quantitative study on α–β transition of Merino wool upon stretching has been carried out by wide angle X-ray diffraction using Merino wool fibre bundles. Technical factors affecting this determination, such as subtraction of air scattering and the measurement of crystallinity are considered. The degree of crystallin…

Dyeing and Modifying Textile FibersTextile materials and evaluations

Peroxidase-catalyzed oxidative polymerization ofm-substituted phenol derivatives

Hiroyuki Tonami、Hiroshi Uyama、Shiro Kobayashi 等 4 位作者1999-10-01Macromolecular Chemistry and Physics

Peroxidase-catalyzed oxidative polymerization of m-substituted phenols has been performed in a mixture of a water-miscible organic solvent and buffer at room temperature under air to give a new class of polyphenols. The catalysts used were horseradish and soybean peroxidases (HRP and SBP, respectively). In the polymer…

biodegradable polymer synthesis and propertiesEnzyme-mediated dye degradationBiochemical and biochemical processes

Kinetic model of phase separation in binary mixtures with hard mobile impurities

Valeriy V. Ginzburg、Gongwen Peng、Feng Qiu 等 5 位作者1999-10-01Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

We develop a mean-field rate-equation model for the kinetics of phase separation in binary mixtures with hard mobile impurities. For impurities preferentially wet by one of the components, the phase separation is arrested in the late stage. The "steady-state" domain size depends strongly on both the particle diffusion…

Material Dynamics and PropertiesGranular flow and fluidized bedsnanoparticles nucleation surface interactions

In-situ corrosion investigation at Masnedø CHP plant - a straw-fired power plant

Melanie Montgomery、A. Karlsson1999-10-01Materials and Corrosion

Various austenitic and ferritic steels were exposed on a water-cooled probe in the superheater area of a straw-fired CHP plant. The temperature of the probe ranged from 450–600°C and the period of exposure was 1400 hours. The rate of corrosion was assessed based on unattacked metal remaining. The corrosion products an…

Hydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual StressesNon-Destructive Testing Techniques

Anisotropic Shrinkage in Tape‐Cast Alumina: Role of Processing Parameters and Particle Shape

P. Markondeya Raj、W. Roger Cannon1999-10-01Journal of the American Ceramic Society

Aqueous suspensions of alumina and other powders containing no visible morphological anisotropy were tape cast under different conditions to study the role of processing parameters and powder characteristics in the origin of in‐plane sintering shrinkage anisotropy. High anisotropic shrinkage, with the typical shrinkag…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesPowder Metallurgy Techniques and Materials

Ultrafast optical properties of gold nanoshells

Richard D. Averitt、Sarah L. Westcott、Naomi J. Halas1999-10-01Journal of the Optical Society of America B

We present the results of ultrafast pump–probe measurements on films of gold-coated gold sulfide nanoshells. The measured change in transmission (ΔT/T) agrees with theoretical calculations that relate the increase in the electron temperature to changes in the Drude and interband components of the gold shell dielectric…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchMolecular Junctions and Nanostructures

Alignment of cholesteric liquid crystals using periodic anchoring

L. Komitov、G. P. Bryan‐Brown、E. L. Wood 等 4 位作者1999-10-01Journal of Applied Physics

Previous work has shown that when short-pitch cholesteric liquid crystals are aligned in cells with the helical axis in the plane of the substrate in a well-defined direction, then application of an electric field across the cells may result in microsecond in-plane switching due to the flexoelectric effect. Moreover,…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsAdvanced Materials and Mechanics

Development and Validation of ALFUS: An Irradiation Behavior Analysis Code for Metallic Fast Reactor Fuels

Takanari Ogata、Takeshi Yokoo1999-10-01Nuclear Technology

An irradiation behavior analysis code for metallic fast reactor fuel, ALFUS, has been revised so that it can be applied to stress-strain analysis of U-Pu-Zr ternary fuel pins. The stress-strain calculation in ALFUS is closely coupled with models for slug deformation mechanisms, such as swelling due to accumulation of…

Nuclear reactor physics and engineeringNuclear Materials and PropertiesNuclear and radioactivity studies

Physical nature of critical modes in Fibonacci quasicrystals

Enrique Maciá1999-10-01Physical review. B, Condensed matter

We report on the possibility of modulating the transport properties of critical normal modes in Fibonacci quasicrystals by using the mass ratio as a tuning parameter. The relationship between the spatial structure and the transport properties of these modes is studied analytically in terms of the transmission and Lyap…

Quasicrystal Structures and PropertiesX-ray Diffraction in CrystallographyMineralogy and Gemology Studies

Local structure of a trapped photoexcited state of a Fe-Co cyanide studied by x-ray-absorption fine-structure spectroscopy

Toshihiko Yokoyama、Manabu Kiguchi、Toshiaki Ohta 等 6 位作者1999-10-01Physical review. B, Condensed matter

The local structure of a trapped photoexcited state of a Fe-Co cyanide magnetic material, ${\mathrm{Na}}_{0.4}{\mathrm{Co}}_{1.3}\mathrm{Fe}(\mathrm{CN}{)}_{6}\ensuremath{\cdot}5{\mathrm{H}}_{2}\mathrm{O},$ was investigated by Fe and Co K-edge x-ray-absorption fine-structure spectroscopy. The excited state was prepare…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies

Thermal degradation mechanisms of polyetherimide investigated by direct pyrolysis mass spectrometry

Sabrina Carroccio、Concetto Puglisi、Giorgio Montaudo1999-10-01Macromolecular Chemistry and Physics

The thermal degradation mechanisms of poly[2,2′-bis(3,4-dicarboxyphenoxy)phenylpropane-2-phenylenediimide] (PEI) have been investigated by thermogravimetry (TG) and by direct pyrolysis mass spectrometry (DPMS). TG data show that PEI has a main decomposition step centred at about 510°C followed by a less marked step in…

Polymer crystallization and propertiesFuel Cells and Related MaterialsSynthesis and properties of polymers

Thermodynamic Stability and Anisotropic Fluctuations in the Cylinder-to-Sphere Transition of a Block Copolymer

Chang Y. Ryu、Timothy P. Lodge1999-10-01Macromolecules

The stability and fluctuations of the cylinder (C) and sphere (S) morphologies in the vicinity of the C and S equilibrium have been examined for a poly(styrene- b -isoprene- b -styrene) triblock copolymer by rheology, small-angle X-ray scattering (SAXS), and transmission electron microscopy (TEM). The spinodal tempera…

Polymer crystallization and propertiesRheology and Fluid Dynamics StudiesBlock Copolymer Self-Assembly

Electron diffraction from micro‐ and nanoparticles of hydroxyapatite

Suvorova、Buffat1999-10-01Journal of Microscopy

Hydroxyapatite (HAP) obtained from aqueous solutions under different conditions has been examined by high-resolution transmission electron microscopy (HRTEM) and electron diffraction, including selected-area electron diffraction (SAED) and microdiffraction. A Philips CM300 field-emission gun electron microscope with a…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesX-ray Diffraction in Crystallography

Corrosion-Sensing Behavior of an Acrylic-Based Coating System

J. Zhang、G. S. Frankel1999-10-01CORROSION

Paint systems containing color-change or fluorescing compounds were found to be sensitive to underlying corrosion processes by reacting to the pH increase associated with the cathodic reaction that accompanies corrosion. The sensitivity of acrylic-based coating systems for detection of cathodic reactions associated wi…

Corrosion Behavior and InhibitionAnalytical Chemistry and SensorsConcrete Corrosion and Durability

Processing and Properties of Nanograin Silicon Carbide

Robert Vaßen、Detlev Stöver1999-10-01Journal of the American Ceramic Society

The manufacture of fine‐grained SiC ceramics by using nanophase SiC powders with particle sizes of about 20 nm is described. Conventional sintering of these powders led to extreme grain growth and hence the nanophase microstructure was destroyed. Pressure‐assisted sintering was applied to reduce the sintering temperat…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Monodomain liquid crystalline networks: reorientation mechanism from uniform to stripe domains

Eugene R. Zubarev、Sergei A. Kuptsov、Tat'yana I. Yuranova 等 5 位作者1999-10-01Liquid Crystals

Monodomain acrylate-based networks have been synthesized by a two-step cross-linking procedure using gamma-irradiation. Strain-induced reorientation of the nematic director is studied by X-ray diffraction measurements. The geometrical shape (aspect ratio) of the monodomain films is found to affect drastically the dyna…

Liquid Crystal Research AdvancementsAdvanced Materials and MechanicsPlant Reproductive Biology

Protein microcrystals and the design of a microdiffractometer: current experience and plans at EMBL and ESRF/ID13

Anastassis Perrakis、F. Cipriani、Jean-Charles Castagna 等 7 位作者1999-10-01Acta Crystallographica Section D Biological Crystallography

There is a growing demand for the examination of protein microcrystals at third-generation synchrotron sources. After successful pilot experiments at EMBL/ESRF, which proved that protein microcrystals are often suitable for data collection, operation of the microfocus beamline ID13 was made more user-friendly and suit…

Protein Structure and DynamicsEnzyme Structure and FunctionX-ray Spectroscopy and Fluorescence Analysis