Graphite interlayer formation during CVD diamond coating of iron base alloys: The analogy to metal dusting
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Preparation and properties of high-pretilt-angle polyimides based on an alicyclic dianhydride and long alkyloxy side-group-containing diamines
A series of polyimides were prepared by a solution polycondensation reaction between 3-carboxylmethylcyclopentane-1,2,4-tricarboxylic dianhydride and 4-alkyloxybenzene-1,3-diamines in N-methyl-2-pyrrolidone and chemical imidization with triethylamine and acetic anhydride. These polyimides possess great organo-solubili…
The Oxidation of HCN and Reactions with Nitric Oxide: Experimental and Detailed Kinetic Modeling
The oxidation of HCN has been conducted in a fused silica jet-stirred reactor (JSR) at atmospheric pressure and from 1 000 to 1400 K. The reduction of nitric oxide (NO) by HCN has also been studied in a JSR in the same operating conditions. A detailed chemical kinetic model for NO-reburning (751 reactions and 102 spec…
Photocatalytic Decomposition of N2O into N2 and O2 on the Silver(I) Ion-Exchanged ZSM-5 Catalyst
Abstract Ag+/ZSM-5 catalysts were prepared by an ion-exchange method. UV-irradiation of the Ag+/ZSM-5 catalysts in the presence of N2O led to the photocatalytic decomposition of N2O into N2 and O2 at 298 K. Investigations of the effective wavelength of the irradiated UV-light for the reaction as well as the in-situ ch…
Kinetics of layer-thinning transitions in overheated smectic films
The kinetic behavior of dislocation loops in overheated free-standing smectic-A films is reported. The loops open at velocities that are much faster than those seen in nonoverheated films. The velocities increase dramatically as a function of temperature and vary slightly as a function of film thickness. The behavior…
A Monte Carlo study on the effect of excluded volume interactions on the scattering from block copolymer micelles
Effects of excluded volume interaction on the form factor of a block copolymer micelle model have been investigated by performing Monte Carlo simulations. The micelles are modeled as a corona of semi-flexible chains tethered to a spherical core. Simulated form factors are analyzed using the model proposed by Pedersen…
Total scattering studies of silica polymorphs: similarities in glass and disordered crystalline local structure
Abstract The structure of amorphous silica has frequently been compared with its crystalline counterparts in an attempt to understand the glass structure beyond short-range correlations. This paper presents results from neutron total scattering measurements of several polymorphs of silica and shows how these can be us…
Reflectance measurements and optical constants in the extreme ultraviolet for thin films of ion-beam-deposited SiC, Mo, Mg_2Si, and InSb and of evaporated Cr
Reflectance measurements and optical constants of thin films of ion-beam-deposited SiC, Mo, Mg(2)Si, and InSb and of evaporated Cr have been measured in the extreme-ultraviolet (EUV) spectral region from 49.0 to 200.0 nm. In this spectral region no optical constant data were available for materials deposited by ion-be…
Dehydroxylation of Fe3+ , Mg-rich dioctahedral micas: (I) structural transformation
Abstract Celadonite and glauconite samples heated at different temperatures were studied by X-ray and electron diffraction. For dioctahedral micas the in-plane component of the translation between layers ( c cosβ/ a ), which is strongly dependent on the position of the vacant octahedral site, significantly decreases a…
Effect of catalyst residues on the chain structure and properties of a Phillips type polyethylen
Abstract A large number of high‐density polyethylene (HDPE) powder samples produced by Phillips technology were taken from an industrial polymerization reactor and their catalyst residue content was determined by X‐ray fluorescence spectroscopy. The chemical structure of the powder was characterized by diffuse reflect…
Elastically coupled magneto-electric elements with highly magnetostrictive amorphous films and PZT substrates
Elastically coupled magneto-electric (ME) elements were constructed and their fundamental properties were studied, so as to examine whether the elements exhibit considerable ME effect at room temperature. The elements had a hybrid structure, in which thin soft glass substrates with highly magnetostrictive amorphous Fe…
Structure and rheology of binary mixtures in shear flow
Results are presented for the phase separation process of a binary mixture subject to a uniform shear flow quenched from a disordered to a homogeneous ordered phase. The kinetics of the process is described in the context of the time-dependent Ginzburg-Landau equation with an external velocity term. The large-n approx…
The quasicrystal-to-crystal transformation. I. Geometrical principles
A geometrical model of the quasicrystal-to-crystal transformation is discussed on atomic scale. The central idea is to describe a quasiperiodic structure as a special type of incommensurately modulated structure. As a consequence thereof, the periodic average structure of a quasicrystal is also the average structure o…
THE CRYSTAL STRUCTURE OF YOSHIMURAITE, A LAYERED Ba-Mn-Ti SILICOPHOSPHATE, WITH COMMENTS ON FIVE-COORDINATED Ti4+
The crystal structure of yoshimuraite, ideally Ba2Mn2TiO(Si2O7)(PO4)(OH), has been determined and refined to residuals of R = 3.0 % and wR = 4.1 % using material from the Taguchi mine, Aichi Prefecture, Honshu, Japan. It is triclinic, P¯1, with cell parameters a 5.386(1), b 6.999(1), c 14.748(3) Å, a 89.98(1), b 93.62…
Effects of interaction between two bubble scatterers
The backscattering of sound from two regularly arranged bubbles is studied theoretically and experimentally. In well-controlled laboratory experiments a bistatic acoustic system is used to interrogate the scatterers, which are placed on a very fine thread at the same distance d from the combined beam axis of the set o…
The synthesis of low melting liquid crystalline lanthanide complexes with triflate counter-anions
Paramagnetic liquid crystalline complexes of the formula [LnL(LH)2][CF3SO3]2 have been synthesised, where LH is the ligand N-dodecyl-4-(3',4'-didodecyloxybenzoyloxy)salicylaldimine and Ln is a lanthanide metal. When compared with analogous nitrate complexes, the transition temperatures are rather low.
Atomic Force Microscopy of Single-Walled Carbon Nanotubes Using Carbon Nanotube Tip
We succeeded in observing individual single-walled carbon nanotubes (SWNTs) using an atomic force microscope (AFM) in the tapping mode by paying attention to the preparation of both samples and AFM tips. To disentangle the bundles of SWNTs, we added a small amount of amine into N,N-dimethylformamide. To achieve a high…
Cationic ordering in oxide glasses: the example of transition elements
Abstract Structural data have been obtained on the cation surroundings in multi-component silicate and borosilicate glasses using chemically selective spectroscopic and scattering methods, such as extended X-ray absorption and neutron scattering with isotope substitution (NSIS). Transition elements such as Ni or Ti ma…
Electrochemical Copolymerization of Pyrrole and Styrene
A semiconducting pyrrole−styrene block copolymer film was electrochemically synthesized in nitromethane. The product polymer was confirmed to be a copolymer of pyrrole and styrene and not a composite or a blend of PPy and PSt through electrochemical, spectral, and dissolving experiments.
Radiation-induced absorption and luminescence in specially hardened large-core silica optical fibers
Radiation-induced absorption and luminescence are measured in the visible spectral region in H/sub 2/-loaded and as-drawn fibers with KU and KS-4V silicas in the core in the process of /spl gamma/-irradiation (/sup 60/Co-source). The induced absorption in H/sub 2/-loaded fibers is shown to be much lower than in as-dra…