Materials Literature
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In this paper, we develop a new ionic polymer–metal composite (IPMC) by replacing a typical platinum or gold electrode with a multi-walled carbon nanotube (MWNT)–graphene based electrode. A solvent of MWNT and graphene is formed on both sides of the ionic polymer membranes as electrodes by means of spray coating and b…
Photoelectron angular distributions from both C(60) and C(70) were recorded for low laser intensity femtosecond and picosecond pulses. Rich structure is seen for electron kinetic energies that lie below the photon energy. Strong, broad peaks are observed for photoelectron energies corresponding to single-photon ioniza…
Abstract It is widely recognized that nonradiative quenching of excitons by other excitons and polarons become the dominant decay mechanism of these excitons at high excitation densities. These quenching processes cause the roll‐off in the efficiency of organic light‐emitting devices (OLEDs) and prevent lasing at high…
In vitro human mesenchymal stem cell (hMSC) proliferation and differentiation is dependent on scaffold design parameters and specific culture conditions. In this study, we investigate how scaffold microstructure influences hMSC behavior in a perfusion bioreactor system. Poly-L-lactic acid (PLLA) scaffolds are fabricat…
In the study, a retrieval approach is extended to determine the effective dynamic properties of a finite multilayered acoustic metamaterial based on the theoretical reflection and transmission analysis. The accuracy of the method is verified through a comparison of wave dispersion curve predictions from the homogeneou…
In this paper, Bi(2)O(3) and rare earth (La, Ce)-doped Bi(2)O(3) visible-light-driven photocatalysts were prepared in a Triton X-100/n-hexanol/cyclohexane/water reverse microemulsion. The resulting materials were characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), Brunauer-Emmett-T…
The new generation of medical implants made by titanium is functionalized with different coatings to improve their bioactivity and reduce a risk of infection. This article describes how these goals can be achieved via deposition of silver nanoparticles and calcium phosphate coating. TiO(2) nanotubes were grown on a Ti…
Abstract Although smouldering ignition of upholstery items remains a leading cause of residential fire deaths, relatively little research is conducted on the topic. An experimental investigation of the effect of sample size on the ignition and spread of smouldering and flaming in polyurethane foam under natural flow c…
PURPOSE: Nanoparticle relaxation time measurements have many applications including characterizing molecular binding, viscosity, heating, and local matrix stiffness. The methods capable of in vivo application are extremely limited. The hypothesis investigated by the authors was that the relaxation time could be measur…
Here, we study the nature of metal-metal bonding in the ThCr(2)Si(2) structure type by probing the rate-limiting steps in the oxidative deintercalation of KNi(2)Se(2). For low extents of oxidation, alkali ions are removed exclusively to form K(1-x)Ni(2)Se(2). For greater extents of oxidation, the rate of the reaction…
A powder sample of CsMnMoO 3 F 3 oxyfluoride has been prepared by solid state synthesis. The pyrochlore-related crystal structure of CsMnMoO 3 F 3 has been refined by the Rietveld method at T = 298 K (space group Fd- 3 m, a = 10.59141(4) Å, V = 1188.123(8) Å 3; R B = 3.44%). The stability of the cubic phase has been o…
Angle-dispersive X-ray diffraction measurements have been performed in acanthite, Ag(2)S, up to 18 GPa in order to investigate its high-pressure structural behavior. They have been complemented by ab initio electronic structure calculations. From our experimental data, we have determined that two different high-pressu…
The current design standard for asphalt mixtures provides guidance on selection of aggregates, asphalt binder and includes requirements for the amount of mineral filler to be included. The amount of filler that can be included is limited to a ratio in the range of 0.6–1.2 by mass of the binder. However, this range is…
Abstract High-resolution γ-ray measurements were carried out on the Joint European Torus (JET) in an experiment aimed at accelerating 4 He ions in the MeV range by coupling third harmonic radio frequency heating to an injected 4 He beam. For the first time, Doppler broadening of γ-ray peaks from the 12 C(d, pγ) 13 C a…
We show how strain stiffening affects the elastic response to internal forces, caused either by material defects and inhomogeneities or by active forces that molecular motors generate in living cells. For a spherical force dipole in a material with a strongly nonlinear strain energy density, strains change sign with d…
Elastin-like polypeptides (ELP) aggregate in response to mild hyperthermia, but remain soluble under normal physiologic conditions. ELP macromolecules can accumulate in solid tumors because of the enhanced permeability and retention effect. Tumor retention of ELPs can be further enhanced through hyperthermia-induced a…
Ionic liquid based, microwave-assisted extraction (ILMAE) was successfully applied to the extraction of proanthocyanidins from Larix gmelini bark. In this work, in order to evaluate the performance of ionic liquids in the microwave-assisted extraction process, a series of 1-alkyl-3-methylimidazolium ionic liquids with…
CuO/ZnO nanocomposites were synthesized on Al(2)O(3) substrates by a hybrid plasma-assisted approach, combining the initial growth of ZnO columnar arrays by plasma-enhanced chemical vapor deposition (PE-CVD) and subsequent radio frequency (RF) sputtering of copper, followed by final annealing in air. Chemical, morphol…
Thermal management technology plays a key role in the continuing miniaturization, performance improvements, and higher reliability of electronic systems. For the past decade, and particularly, the past 4 years, the Defense Advanced Research Projects Agency (DARPA) has aggressively pursued the application of micro- and…
Cardiovascular implants must resist infection and thrombosis. A nanocomposite polymeric material [polyhedral-oligomeric-silsesquioxane-poly(carbonate-urea)urethane; POSS-PCU] demonstrates ideal properties for cardiovascular applications. Silver nanoparticles or nanosilver (NS) are recognized for efficient antibacteria…