Materials Literature
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This paper deals with the columbite FexMn1−xNb2O6 (x = 0, 0.25, 0.50, 0.75 and 1) solid solution. After synthesis under vacuum, structural and magnetic properties were studied by means of X-ray diffraction, Rietveld refinement, electron paramagnetic resonance and magnetization measurements. This investigation showed t…
Ionic LC-dendrimers were obtained by proton-transfer reaction of alkanoic acid and primary amino groups of poly(amidoamine) dendrimer in a 1:1 molar ratio. The ion complexes containing stearate, palmitate or myristate ions showed a smectic A phase. However, the ion complexes containing laurate and decanoate ions exhib…
A number of AB 2 monomers containing either one azide and two acetylene functions or vice versa have been prepared. Upon polymerization, these compounds were found to give rise to hyperbranched oligomers as detected by NMR spectroscopy. However, the formation of high-molecular-weight polymers could not be proven by GP…
An efficient system for the production of (R)-hydroxyalkanoic acids (RHAs) was developed in natural polyhydroxyalkanoate (PHA)-producing bacteria and recombinant Escherichia coli. Acidic alcoholysis of purified PHA and in vivo depolymerization of PHA accumulated in the cells allowed the production of RHAs. In recombin…
Ceramic pellets of different compositions of Na 1−xKxNbO 3 system (x = 0 to 0.5) have been prepared using ‘solid-state reaction’ method. Pellets of 6 mm diameter have been prepared under two conditions; first, the calcined mixtures were pressed at 0.2 MPa and sintered in a tube furnace opened at both ends; and second,…
We study dielectric properties of a dilute suspension of ferroelectric particles in a nematic liquid crystal(LC)host. It is supposed that submicron particles do not disturb the LC alignment and the suspension macroscopically appears similar to a pure LC. We propose theoretical model for effective dielectric function o…
Poly(N-vinyl-2-pyrrolidone)-stabilized Pd-nanoclusters, for the first time exclusively supported on the hydrotalcite lateral surface, showed a remarkable catalytic performance in the selective hydrogenation of 3-hexyn-1-ol, which can be ascribed to both the influence of the protecting polymer PVP as well as the nature…
The electrochromic polymer poly(3,4-ethylenedioxythiophene)-poly(styrene sulfonate) (PEDOT-PSS) spin-coated on ITO/glass was patterned with a soft lithographic method in order to diffract the incident light and thereby modify absorption of light by the film to improve the electrochromic efficiency of the polymer. The…
The Pnma-Imma-I4/mcm phase transitions of SrZrO3 have been successfully observed by measuring the variation of energies of phonon modes as a function of temperature. The squares of phonon mode frequencies, ω02, exhibit a linear relation with temperature, T, on both sides of the phase transitions. An unusual value of -…
We report on observations of transient behavior of currents induced by the polarity reversal of a dc voltage applied across a nematic liquid-crystal cell. The curve of the time-evolved transient current reveals two peaks for the external voltage larger than a characteristic value. The temperature dependence of drift m…
Hydrogen gas storage ability in carbon and boron nitride (BN) clusters was investigated by molecular orbital calculations. From single point energy calculations, H2 molecules would enter from hexagonal rings of C60 and B36N36 clusters and octagonal rings of B24N24 cluster because of lower energy barrier. Chemisorption…
The title compound is a charge transfer complex with an experimental low lying excitation located around 420 nm. It is used as a model compound for the investigation of a possible strategy towards NLO materials obtained by “through space” charge transfer. Its solid state structure (Pc space group) reveals non-centrosy…
The deformation of metal plates and tubes achievable through the use of liquid shock waves generated in a shock tube is studied, with reference to both free-forming and forming the metal into dies, as well as to imprinting detailed features. The process is highly controllable, in terms of the magnitude and duration of…
Oxyfluoride glasses were developed with composition 30SiO2·15AlO1.5·28PbF2·22CdF2·(4.9 – x)GdF3·0.1HoF3·x YbF3 (x ¼ 0; 0.1, 0.2, 0.5, 1, 2, 3, and 4) in mol%. Powder X-ray diffraction analysis revealed that the heat-treatments of the oxyfluoride glasses at the first crystallization temperature cause the precipitation…
The aim of this work is the transient analysis of hybrid systems based on high-temperature Solid Oxide Fuel Cells (SOFC). The cell models were presented and discussed in Part A of this work. In this part attention is focused on the anode recirculation system. In a SOFC hybrid system it is necessary to recirculate part…
The syntheses of a number of azo and azine dyes with various surface attachment groups is described. The dyes use different methods of achieving surface complexing and are evaluated for their suitability as multiple labels for SERRS. The surface complexing agents, 8-hydroxyquinoline, benzotriazole, and pyridine are bo…
Pembaruan utama pada edisi keenam dari buku klasik ini adalah pada fokus pembahasannya yang lebih menekankan pada kesamaan di dalam bidang material yang beragam jenisnya ini. Ini terlihat dari pembahasan mengenai struktur dan sifat material, yang berlaku umum untuk semua jenis material, dan bukan dibagi berdasarkan ke…
Several new enaminoketone mesogens were synthesized and coordinated to various metal salts to yield a variety of novel rodlike metal-containing liquid crystals. The mesophases were characterized by polarized optical microscopy (POM), differential scanning calorimetry (DSC) and small-angle X-ray scattering (SAXS). Wher…
The corrosion behavior of a dense material (hot pressed with 2.5 wt % as a sintering aid) in aqueous acid solutions containing different aggressive anions such as chlorides, perchlorates, sulfates, oxalates, and fluorides was investigated by means of several experimental techniques. The methodology adopted consists in…
Formation of flat gold nanostructures occurs by the reduction of a Langmuir monolayer of hydrophobized chloroaurate ions using anthranilic acid as a reducing agent present in the subphase. Vigorous shaking of the aqueous chloroauric acid solution with a solution of surfactant, such as octadecylamine (ODA) or benzyldim…