Materials Literature
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Abstract The question of whether palladium nanoclusters are the actual catalysts in the so‐called ‘cluster–catalyzed Sonogashira cross‐coupling’ is investigated, using the coupling of phenylacetylene with 4‐bromobenzonitrile as a model reaction. By combining a detailed kinetic analysis with transmission electron micro…
Stereoelectronic effects have been identified as contributing factors to the conformational stability of collagen-mimetic peptide sequences. To assess the relevance of these factors within other protein structural contexts, three polypeptide sequences were prepared in which the sequences were derived from the canonica…
Purpose To evaluate the corrosion inhibition potential of Datura metel in acid medium on mild steel (MS) with a view to develop green corrosion inhibitors. Design/methodology/approach Acid extract of the D. metel was studied for its corrosion inhibitive effect by electrochemical and weight loss methods. Using weight l…
Liquid crystal photo‐alignment using azo‐dyes is reviewed. This alignment method is very different from previously reported ones, such as photo‐crosslinking, photo degradation and photo‐isomerization. It will be shown that this photo‐aligning method can provide a controllable pretilt angle and strong anchoring energy…
PURPOSE: To prospectively and intraindividually compare the effect of magnetic resonance (MR) imaging at a higher magnetic field strength (3.0 T) on contrast-to-noise ratio (CNR) at different doses of a T1-shortening contrast agent in patients with contrast-enhancing brain lesions, with 1.5-T MR imaging as a reference…
Edible antimicrobial films are an innovation within the biodegradable active packaging concept. They have been developed in order to reduce and/or inhibit the growth of microorganisms on the surface of foods. This study developed an edible antimicrobial film based on yam starch (Dioscorea alata) and chitosan and inves…
The ferroic and electroactive properties of the recently identified ferroelectrets are based on the quasi‐permanent internal electric charging of the cellular structure in polymer foams. Drawing on the wealth of expertise and insight that was obtained on cellular polypropylene (PP) and in particular on structure‐prope…
Five single-phase Mo−V−O-based mixed metal oxides, Mo−V−O, Mo−V−Te−O, Mo−V−Sb−O, Mo−V−Te−Nb−O, and Mo−V−Sb−Nb−O, all of which assume the same orthorhombic structure, were prepared by hydrothermal method, and propane ammoxidation to acrylonitrile (AN) using these mixed oxides as catalysts was performed in order to clar…
Abstract Single and multilayered structures at nano‐length scale are very attractive materials due to their high strength, toughness, and wear resistance relative to conventional laminated composites. In this study, single layered Al, SiC, and multilayered Al/SiC composites were synthesized by DC/RF magnetron sputteri…
Abstract— Refractive indices of two photocurable polymers, NOA65 and NOA81 (Norland Optical Adhesive), and two series of Merck liquid crystals, E‐series (E44, E48, and E7) and BL‐series (BL038, BL003 and BL006), and two UCF high‐birefringence liquid‐crystal mixtures were measured using an Abbe refractometer in the vis…
Electrical aging and relaxation in solid dielectrics are phenomena studied for decades but still largely poorly understood. The lack of understanding, or sometimes the misunderstanding, are partly due to inadequate or deficient theories and partly due to wrong interpretation of theories or concepts developed for other…
Two novel trimetallic coordination polymers containing bridging bicapped Keggin mixed Mo/V polyoxoanions and asymmetrical aromatic amine bridging ligands 2,3‘-bipyridine (2,3‘-bipy) or 2,4‘-bipyridine (2,4‘-bipy), [Cu I 6 (2,3‘-bipy) 6 (2,3‘-bipy-2‘-O) 2 ][V IV 2 Mo V 5 Mo VI 7 O 38 (PO 4 )] [2,3‘-bipy-2‘-OH = 3-(pyri…
The Modulus of Elasticity (MOE) and the hardness of fibril reinforced hydroxypropyl cellulose films were determined by nanoindentation. In addition, the fibril alignment in the composites was analysed by Transmission Electron Microscopy (TEM) and Atomic Force Microscopy (AFM). The results show that the formation of fi…
Nanosize zinc ferrite samples with an average particle size of 6–65 nm were prepared by a new chemical reaction involving nitrates of Zn and Fe and investigated for magnetic behaviour and defect structure. The sample with an average particle size of 6 nm has considerable inversion in cation distribution as shown by it…
n-butanol has been chosen as an organic additive in the SiO(2)-EO(106)PO(70)EO(106)-H(2)O system at low HCl concentrations, for the generation of large-pore mesoporous silicas with easily tailored textural and structural properties. As opposed to previous reports on syntheses of cubic mesoporous silica that are usuall…
Reaction of in situ generated copper(II)-monosubstituted Keggin polyoxometalates and copper(II)-bipyridine-oxalate complexes in the corresponding alkaline acetate buffer led to the formation of hybrid metal organic-inorganic compounds K(2)[{SiW(11)O(39)Cu(H(2)O)}{Cu(2)(bpy)(2)(H(2)O)(2)(mu-ox)}(2)].14H(2)O (1), K(14)[…
Solid-state 13C NMR experiments and quantum chemical Density Functional Theory (DFT) calculations of acetone adsorption were used to study the location of protons in anhydrous 12-tungstophosphoric acid (HPW), the mobility of the isolated and hydrated acidic protons, and the acid strength heterogeneity of the anhydrous…
We developed an Index of Biotic Integrity (IBI) for the Interior Plateau Ecoregion (IPE), USA, which assessed effects of human disturbance on the biotic condition of stream diatom communities. We selected 7 metrics from 59 diatom attributes at reference and impaired sites (training sites), based on significant differe…
Self-diffusion by vacancy mechanism is studied in two metals of hexagonal close packed structure, namely Hafnium and Zirconium. Computer simulation techniques are used together with many-body potentials of the embedded atom type. Defect properties are calculated at 0 K by molecular static while molecular dynamic is us…