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On the Boundary Conditions of Electrochemical Hydrogen Permeation Through Iron

Tong‐Yi Zhang、Yongping Zheng、Qiu‐Yun Wu1999-05-01Journal of The Electrochemical Society

The constant concentration (CC), constant flux (CF), flux continuity (FC), and hybrid of flux continuity and constant concentration (FCCC) boundary conditions for electrochemical hydrogen permeation through iron or steel samples are reviewed and used to evaluate the hydrogen diffusivity from the permeation tests on fu…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsElectrodeposition and Electroless Coatings

XAFS spectroscopy in catalysis research: AXAFS and shape resonances

D.C. Koningsberger、Barbara L. Mojet、Jeff Miller 等 4 位作者1999-05-01Journal of Synchrotron Radiation

Two new techniques in X-ray absorption spectroscopy (XAS) have recently been developed which provide previously unobtainable information on supported noble metal catalysts. Atomic X-ray absorption fine structure (AXAFS) provides direct information on the average changes in interatomic potential of the metal particles…

Advanced Chemical Physics StudiesX-ray Spectroscopy and Fluorescence AnalysisMachine Learning in Materials Science

Electroluminescence-a technique to detect the initiation of degradation in polymeric insulation

S.S. Bamji1999-05-01IEEE Electrical Insulation Magazine

The EL technique is at least two orders of magnitude more sensitive than PD detection and can detect the initiation of polymeric ageing. It can also detect the conversion of a water tree to an electrical tree.

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationElectrostatic Discharge in Electronics

ANALYSIS OF THE ELASTIC MODULUS OF AGAR GEL BY INDENTATION

Kelly Ross、Martin G. Scanlon1999-05-01Journal of Texture Studies

ABSTRACT This study used the approach taken by Bourne to obtain the compressive and shear components for an agar gel. But in addition, the low strain regime for the same experiments was used to evaluate the gel's elastic modulus using the theory of elasticity. Compression testing, using lubricated teflon platens and a…

Meat and Animal Product QualityMicroencapsulation and Drying ProcessesCollagen: Extraction and Characterization

Extinction of light in dispersive media with high particle concentrations: applicability limits of the interference approximation

V. P. Dick、Arkady P. Ivanov1999-05-01Journal of the Optical Society of America A

We investigated the limits of applicability of the interference approximation (ITA), which is often used to calculate light fields in dispersive media with high particle concentrations. We analyzed the conditions under which the use of the ITA leads to an error in calculation of the dispersive-medium extinction coeffi…

Atmospheric aerosols and cloudsPlant and animal studiesGlass properties and applications

Fundamental quantities and units for ionizing radiation — ICRU report 60

Craig Edwards1999-05-01Medical Engineering & Physics

Geopolymer apron cassava starch/BC/Fe3O4/glycerin has been synthesized for various amount of Fe3O4 (0.5%, 1%, and 1.5%) into cassava starch and black carbon (BC) solutions. The quantitative analysis from Fourier transforms infra-red (FTIR) was used to determine the optical properties, dielectric function, energy loss…

Radiation Dose and ImagingGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies

XANES studies at the Al K-edge of aluminium-rich surface phases in the soil environment

Colin Doyle、Samuel J. Traina、H. Ruppert 等 6 位作者1999-05-01Journal of Synchrotron Radiation

Aluminum is highly abundant in the Earth's crust where it is present in a wide variety of primary and secondary aluminosilicate minerals, amorphous phases, and aqueous solution species. The speciation and coordination of AI in many of these phases, particularly those that are X-ray amorphous or present as thin surface…

X-ray Spectroscopy and Fluorescence AnalysisElectron and X-Ray Spectroscopy TechniquesIon-surface interactions and analysis

Preparation of barium strontium titanate powder from citrate precursor

Chen‐Feng Kao、Wein‐Duo Yang1999-05-01Applied Organometallic Chemistry

TiCl4 or titanium isopropoxide reacted with citric acid to form a titanyl citrate precipitate. Barium strontium citrate solutions were then added to the titanyl citrate reaction to form gels. These gels were dried and calcined to (Ba,Sr)TiO3 powders. The gels and powders were characterized by DSC/TGA, IR, SEM and XRD…

Bone Tissue Engineering MaterialsAdvanced ceramic materials synthesisSilicone and Siloxane Chemistry

XANES study of the support effect on the state of platinum catalysts

Hisao Yoshida、Yoshiteru Yazawa、Naoya Takagi 等 7 位作者1999-05-01Journal of Synchrotron Radiation

Pt I~u and Ln-edges XANES clarified the oxidation state of platinum catalysts supported on various metal oxides. The acidbase property seemed one of the most dominant factors to control the electron state of platinum. On the reduced samples, there was a tendency that acidic support reduced the 5d-electron density of p…

Catalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Dielectric and structural characteristics of perovskites and related materials as a function of tolerance factor

Ian M. Reaney、Rick Ubic1999-05-01Ferroelectrics

The temperature coefficient of the dielectric permittivity (τϵ) and resonant frequency (τf) of perovskites and related materials is important in the application of these ceramics to microwave filters and resonators. Recent work has directly related changes in τϵ, and therefore τf, to the onset of octahedral tilting in…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Humidity-Dependent Air Permeability of Textile Materials1

Phillip Gibson、D. Rivin、Cyrus Kendrick 等 4 位作者1999-05-01Textile Research Journal

Changes in fabric structure as hygroscopic fibers swell at high humidities can have a large influence on the measured air permeability of fabrics such as cotton, wool, silk, and nylon. The variation of air permeability as a function of relative humidity is of practical importance in ranking and evaluating candidate te…

Thermoregulation and physiological responsesTextile materials and evaluationsAerosol Filtration and Electrostatic Precipitation

Experimental Evaluation of Toughening Mechanisms in Alumina‐Zirconia Composites

Yu-Seon Shin、Young‐Woo Rhee、Suk‐Joong L. Kang1999-05-01Journal of the American Ceramic Society

The contributions of transformation toughening and microcrack toughening in an 85Al 2 O 3 15ZrO 2 (vol%) composite were quantitatively evaluated. Three types of hot‐pressed samples with similar size (∼0.5 µm) and size distribution of ZrO 2 grains, but with different contents (vol%) of monoclinic‐ ( m ‐) ZrO 2 (0 (AZS)…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

FeO 4 : A unique example of a closed-shell cluster mimicking a superhalogen

G. L. Gutsev、Shiv N. Khanna、B. K. Rao 等 4 位作者1999-05-01Physical Review A

First-principles calculations based on the generalized gradient corrected density-functional theory reveal that iron tetraoxide $({\mathrm{FeO}}_{4}),$ in spite of its closed-shell structure, has an electron affinity that is larger than that of any known halogen atom. This novel property is shown to be a manifestation…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Molecular Dynamics and Crystallization Behavior of Chiral Isooctyloxycyanobiphenyl as Studied by Dielectric Relaxation Spectroscopy

Maria Massalska-Arodź、Graham Williams、Dale K. Thomas 等 5 位作者1999-05-01The Journal of Physical Chemistry B

The complex dielectric permittivity of right-handed isooctyloxycyanobiphenyl (IOOCB) has been studied in the frequency range 10 -1 −10 5 Hz and over a wide temperature range. On cooling the isotropic liquid a supercooled liquid is formed that becomes a glass below 220 K. On heating the glass, the material crystallized…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesThermodynamic properties of mixtures

Critical dependency of the conductivity of polypyrrole and polyaniline films on the hydrophobicity/hydrophilicity of the substrate surface

P-C. Wang、Z. Huang、Alan G. MacDiarmid1999-05-01Synthetic Metals

The conductivity, electronic properties and morphology of polypyrrole and polyaniline films deposited from aqueous solutions of the polymerizing monomer differ greatly according to whether they are deposited on a hydrophobic or hydrophilic substrate surface. For each polymer the conductivity of the film deposited on a…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

The rheology and microstructure of concentrated, aggregated colloids

Leonardo E. Silbert、J. R. Melrose、R. C. Ball1999-05-01Journal of Rheology

The rheology of concentrated, aggregated colloidal suspensions is determined through particulate simulations. Aggregating systems experience a large viscous enhancement over nonaggregating systems, this being due to the increase in the component of the viscosity arising from the repulsive colloid (thermodynamic) force…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsRheology and Fluid Dynamics Studies

16.4L: Late‐News Paper: A Novel Wide‐Viewing‐Angle Technology: Ultra‐Trans View™

S. H. Lee、S. L. Lee、H. Y. Kim 等 4 位作者1999-05-01SID Symposium Digest of Technical Papers

Abstract A novel nematic liquid crystal display of in‐plane switching controlled by fringe‐field has been developed. The device exhibits wide viewing angle over 160° and high transmittance comparable to the twisted nematic TN cell, a solution for long standing problem of previous wide viewing angle technologies with l…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsAdvanced Optical Imaging Technologies

Effects of Tungsten on Corrosion and Kinetics of Sigma Phase Formation of 25% Chromium Duplex Stainless Steels

J.-S. Kim、Hyosang Kwon1999-05-01CORROSION

Duplex stainless steels (DSS) of 25% Cr-7% Ni-x% Mo-y% W-0.25% N (x = 1.5 to 3, and y = 0 to 3) were designed with the same pitting resistance equivalent (PRE) value of 42 by varying the contents of Mo and W. Effects of W on pitting and stress corrosion of the solution-annealed or aged alloys in chlorides were examine…

Metal and Thin Film MechanicsMicrostructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metals

Cure and Mechanical Behavior of Rubber Compounds Containing Ground Vulcanizates: Part III. Tensile and Tear Strength

D. Gibala、D. A. Thomas、G. R. Hamed1999-05-01Rubber Chemistry and Technology

Abstract A black-filled styrene-butadiene rubber (SBR) vulcanizate was ambiently ground, then used as an additive to the original, uncured compound. Sheets of the resulting composite (matrix/ground rubber particulate) were cured, and tensile and trouser tear strength determined. The composite had reduced tensile stren…

Polymer Nanocomposites and PropertiesStructural Analysis of Composite MaterialsEngineering and Material Science Research

Applications of advanced materials technologies to vacuum electronic devices

J.P. Calame、David K. Abe1999-05-01Proceedings of the IEEE

The applications of advanced engineering materials in modern vacuum electronic devices are reviewed. Unique materials with desirable thermal, mechanical, electrical, and magnetic properties are playing a crucial role in raising the average power capability, bandwidth, and efficiency of microwave and millimeter wave am…

Magnetic properties of thin filmsGyrotron and Vacuum Electronics ResearchMagnetic Properties of Alloys