Materials Literature
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We report on a method to locally remove material from carbon and boron nitride nanotubes using the low-energy focused electron beam of a scanning electron microscope. Using this method, clean precise cuts can be made into nanotubes, either part-way through (creating hingelike geometries) or fully through (creating siz…
Single crystals of NaxCoO2 with beta-phase (x=0.55, 0.60 and 0.65), alpha'-phase (x=0.75) and alpha-phase (x=0.9, 1.0) have been grown by the floating zone technique. The Na-extraction and hydration were carried out for the alpha'-sample to get superconducting phase of NaxCoO2.yH2O (x~0.3, y~1.3). Hydrated single crys…
Abstract The addition of zinc oxide (ZnO) as an activator for the sulfur vulcanization of rubbers enhances the vulcanization efficiency and vulcanizate properties and reduces the vulcanization time. The first part of this article deals with the reduction and optimization of the amount of ZnO. Two different rubbers, so…
The thin film synthesis and characterization of room temperature ferromagnetic semiconductor (In1−xFex)2O3−σ are reported. The high thermodynamic solubility, up to 20%, of Fe ions in the In2O3 is demonstrated by a combinatorial phase mapping study where the lattice constant decreases almost linearly as Fe doping conce…
We report the effect of air exposure on the electronic properties of pentacene single crystals. Air can diffuse reversibly in and out of the crystals and controls the physical properties. We discern two competing mechanisms that modulate the electronic transport. The presence of oxygen increases the hole conduction, a…
We have synthesized and investigated the magnetic and transport properties of a series of compounds, R2CoIn8 (R = rare earth). Compounds form in single phase with a tetragonal structure (space group P4/mmm, no. 162). The Ce compound shows heavy fermion behavior. The magnetic susceptibility of Pr2CoIn8 shows a marked d…
Using the fully relativistic screened Korringa-Kohn-Rostoker method I study the orbital magnetism in the half-metallic Heusler alloys. Orbital moments are almost completely quenched and they are negligible with respect to the spin moments. The change in the atomic-resolved orbital moments can be easily explained in te…
The observation of hysteresis effects in single molecule magnets like Mn$_{12}$-acetate has initiated ideas of future applications in storage technology. The appearance of a hysteresis loop in such compounds is an outcome of their magnetic anisotropy. In this Letter we report that magnetic hysteresis occurs in a spin…
We investigate the failure characteristics of complex networks within the framework of the fiber bundle model subject to the local load sharing rule in which the load of the broken fiber is transferred only to its neighbor fibers. Although the load sharing is strictly local, it is found that the critical behavior belo…
This article describes the structure determination of five homoleptic d(10) metal-aryl/alkylacetylides [RC triple bond CM] (M=Cu, R=tBu 1, nPr 2, Ph 3; R=Ph, M=Ag 4; Au 5) by using X-ray single-crystal and powder diffraction. Complex 1.C6H6 reveals an unusual Cu20 catenane cluster structure that has various types of t…
Nanoparticle orientation and alignment under tensile stress results in enhanced toughness in nanocomposite materials. This energy-dissipation mechanism, which is not observed in conventional polymer composites, is applicable to both semicrystalline and amorphous polymer-composite systems. The mechanism depends on the…
Physical models are used to determine the ultimate potential performance of carbon nanotube interconnects and compare them with minimum-size copper wires implemented at various technology generations. Results offer important guidance regarding the nature of carbon nanotube technology development needed for improving i…
Views Icon Views Article contents Figures & tables Video Audio Supplementary Data Peer Review Share Icon Share Twitter Facebook Reddit LinkedIn Tools Icon Tools Reprints and Permissions Cite Icon Cite Search Site Citation Khan A. Alim, Vladimir A. Fonoberov, Alexander A. Balandin; Origin of the optical phonon frequenc…
Rectification of heat transfer in nanodevices can be realized by combining the system inherent anharmonicity with structural asymmetry. We analyze this phenomenon within the simplest anharmonic system-a spin-boson nanojunction model. We consider two variants of the model that yield, for the first time, analytical solu…
Nascent polypeptide-associated complex (NAC) was identified in eukaryotes as the first cytosolic factor that contacts the nascent polypeptide chain emerging from the ribosome. NAC is highly conserved from yeast to humans. Mutations in NAC cause severe embryonically lethal phenotypes in mice, Drosophila, and Caenorhabd…
We numerically and theoretically study macroscopic properties of dense, sheared granular materials. In this process we first introduce an invariance in Newton's equations, explain how it leads to Bagnold's scaling, and discuss how it relates to the dynamics of granular temperature. Next we implement numerical simulati…
We investigate the zero-temperature phase diagram and spin-wave properties of a double exchange magnet with on-site Hubbard repulsion. It is shown that even within a simple Hartree -- Fock approach this interaction (which is often omitted in theoretical treatments) leads to qualitatively important effects which are hi…
Abstract In contrast to λ-(BETS)2MCl4 (M = Fe, Ga) with superconducting (Ga) or π–d coupled antiferromagnetic insulating (Fe) ground states, λ-(BEST)2MCl4 (M = Ga, Fe) are semiconducting at ambient pressure despite of the close similarity of the crystal structures. There exists another triclinic modification of BEST c…
Interference in the Fresnel regime of periodic structures creates a wide variety of intricate diffraction patterns. The diffraction patterns from both amplitude and phase gratings can bear a strong resemblance to the grating itself, or have much more complex structures. In this paper, we discuss a general approach for…
Two quantum chemistry theoretical models in the gas phase at the density functional theory B3LYP/LACVP(d) level of calculation are proposed to rationalize the hydrazine oxidation by cobalt(II) phthalocyanine (Co(II)Pc). This oxidation reaction involves the net transfer of four electrons. These theoretical models that…