Materials Literature
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Stimulus-sensitive micelles are attractive anticancer drug delivery systems. Herein, we reported a novel strategy to engineer acid-sensitive micelles using a amphiphilic material synthesized by directly conjugating the hydrophilic poly(ethylene glycol) (PEG) with a hydrophobic stearic acid derivative (C18) using an ac…
Aqueous solutions of amphiphilic polymers often undergo a heat-induced phase separation, which is known as the lower critical solution temperature (LCST) phase transition. In the case of aqueous poly(2-isopropyl-2-oxazoline) (PIPOZ) solutions, the phase separation is followed, upon prolonged heat treatment, by an irre…
Gold cures: the depicted gold(III) complex self-assembles into supramolecular polymers which form nanofibrillar networks that display sustained cytotoxicity and can also act as carriers for other cytotoxic agents.
Surface-science investigations have contributed significantly to heterogeneous catalysis in the past several decades. Fundamental studies of reactive systems on metal single crystals have aided researchers in understanding the effect of surface structure on catalyst reactivity and selectivity for a number of important…
A novel method for the encapsulation of organic active agents in nanoparticle-armored polymer composite nanocontainers (analog of Pickering emulsions) is introduced. The multifunctionality of the constituents allows a fabrication path that does not require auxiliary materials. Embedding the composite nanocontainers in…
When a foreign atom is placed on a surface of a metal, the surrounding sea of electrons responds screening the additional charge leading to oscillations or ripples. On surfaces, those electrons are sometimes confined to two-dimensional surface states, whose spin-degeneracy is lifted due to the Rashba effect arising fr…
Well-ordered, thin oxide films have drawn some attention in recent years as suitable oxide supports for modeling highly dispersed metal catalysts at the atomic scale. It turned out, however, that ultrathin oxide films may exhibit interesting catalytic properties in their own right. In this review, we discuss phenomena…
The best of both worlds: BODIPY-based imaging probes can be tracelessly transformed into hybrid PET/fluorescence imaging reagents by direct 19F/18F exchange without the need for redesign. This approach has the potential to accelerate not only the development of imaging agents, but perhaps also the screening of therape…
We have investigated the thermal Hall effect of magnons for various ferromagnetic insulators. For pyrochlore ferromagnetic insulators Lu${}_{2}$V${}_{2}$O${}_{7}$, Ho${}_{2}$V${}_{2}$O${}_{7}$, and In${}_{2}$Mn${}_{2}$O${}_{7}$, finite thermal Hall conductivities have been observed below the Curie temperature ${T}_{C}…
We report on isothermal pulsed (20 ms) field magnetization, temperature dependent AC - susceptibility, and the static low magnetic field measurements carried out on 10 nm sized Pr0.5Ca0.5MnO3 nanoparticles (PCMO10). The saturation field for the magnetization of PCMO10 (~ 250 kOe) is found to be reduced in comparison w…
Hierarchically combining semi-empirical methods and first-principles calculations we gain a novel and noteworthy picture of the molecular-level mechanisms that govern the water-gas-shift (WGS) and reverse water-gas-shift (r-WGS) reactions on Rh catalysts. Central to this picture is that the WGS and r-WGS follow two di…
A new approach is developed to calculate temperature dependent Seebeck coefficient of heavily doped systems by using Boltzmann transport theory and electron density of states (DOS) obtained from density functional calculations. This approach is applied to heavily doped La:STO with DOS from tetrahedral method and Fermi…
We provide a compilation of metallic systems in which a low-temperature ferromagnetic or similar transition is observed. Our objective is to demonstrate the universal first-order nature of such transitions in clean systems in two or three spatial dimensions. Please contact the authors with information about omissions,…
A new series of push-pull arylvinyldiazines has been efficiently prepared by aldol condensation between the appropriate methyldiazine and aromatic aldehyde. The optical absorption and emission properties of these chromophores were studied in different solvents and media. These compounds act as polarity sensors with a…
International audience
Playing it cool: Almost all of the constituent parts of the complex [LnIII4MII8(OH)8(L)8(O2CR)8]X4, namely the lanthanide ions Ln3+, the transition-metal ions M2+, the bridging ligand L, the carboxylates, and the counterions X can be exchanged, thus allowing a thorough understanding of the individual contributions to…
The fluorescence of nanoparticles has attracted much attention in recent research, but in many cases the underlying mechanisms are difficult to evaluate due to the polydispersity of nanoparticles and their unknown structures, in particular the surface structures. Recent breakthroughs in the syntheses and structure det…
Upconversion emissions from rare-earth nanoparticles have attracted much interest as potential biolabels, for which small particle size and high emission intensity are both desired. Herein we report a facile way to achieve NaYF(4):Yb,Er@CaF(2) nanoparticles (NPs) with a small size (10-13 nm) and highly enhanced (ca. 3…
Palladium's pore cousin: a facile approach is described for the size-controlled preparation of porous single-crystalline Pd nanoparticles. These porous Pd nanoparticles exhibit size-independent catalytic activities for the Suzuki coupling and are more active than commercial Pd/C catalysts.
Recent advances in the growing field of nanoemulsions are opening up new applications in many areas such as pharmaceuticals, foods, and cosmetics. Moreover, highly controlled nanoemulsions can also serve as excellent model systems for investigating basic scientific questions about soft matter. Here, we highlight some…