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Semiconducting-like filament formation in TiN/HfO2/TiN resistive switching random access memories

Francesca De Stefano、Michel Houssa、J. A. Kittl 等 6 位作者2012-04-02Applied Physics Letters

The conduction mechanisms and nature of the filament formed in the low resistive state of TiN/HfO2/TiN resistive random access memories are studied from the temperature-dependence of their current-voltage characteristics. These characteristics are analyzed using the percolation theory of conductor networks, allowing u…

Advanced Memory and Neural ComputingElectronic and Structural Properties of OxidesFerroelectric and Negative Capacitance Devices

On the Influence of Surfactant Incorporation during Electroless Nickel Plating

Nkem O. Nwosu、Alan Davidson、C.S. Hindle 等 4 位作者2012-04-02Industrial & Engineering Chemistry Research

The effects of surfactants on the dynamics and characteristics of plain and composite electroless nickel plating (ENP) are highlighted and discussed herein. An outline of the rudiments of surfactants and some underlying selection criteria is presented at the outset, before emphasis is laid on the salient benefits of i…

Corrosion Behavior and InhibitionElectrodeposition and Electroless CoatingsCopper Interconnects and Reliability

Ultrafast excited state dynamics and dispersion studies of nonlinear optical properties in dinaphthoporphycenes

Debasis Swain、P. T. Anusha、T. Shuvan Prashant 等 7 位作者2012-04-02Applied Physics Letters

Ultrafast excited state dynamics of dinaphthoporphycenes were investigated using femtosecond and picosecond degenerate pump-probe techniques at 600 nm and 800 nm, respectively. Femtosecond pump-probe data indicated photo-induced absorption at 600 nm resulting from two-photon/single photon excitation, whereas picosecon…

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsNonlinear Optical Materials Studies

Effect of bird geometry and orientation on bird-target impact analysis using SPH method

Reza Hedayati、Saeed Ziaei‐Rad2012-04-02International Journal of Crashworthiness

In this study, a real mallard anatomy is numerically created from CT images and then analysed by SPH method. The result produced by the real bird is compared to that of the traditional bird models. The effects of considering the cavities, air and different orientations at which a mallard strikes a target are also inve…

Fluid Dynamics Simulations and InteractionsHigh-Velocity Impact and Material BehaviorElectromagnetic Launch and Propulsion Technology

Coordination-Driven Self-Assembly of 2D-Metallamacrocycles Using a New Carbazole-Based Dipyridyl Donor: Synthesis, Characterization, and C60 Binding Study

Sankarasekaran Shanmugaraju、Vaishali Vajpayee、Sun‐Mi Lee 等 6 位作者2012-04-02Inorganic Chemistry

A new carbazole-based 90° dipyridyl donor 3,6-di(4-pyridylethynyl)carbazole (L) containing carbazole-ethynyl functionality is synthesized in reasonable yield using the Sonagashira coupling reaction. Multinuclear NMR, electrospray ionization-mass spectrometry (ESI-MS), including single crystal X-ray diffraction analysi…

Metal-Organic Frameworks: Synthesis and ApplicationsSupramolecular Chemistry and ComplexesMagnetism in coordination complexes

Quantitative Analysis of Powder Mixtures by Raman Spectrometry: the influence of particle size and its correction

Zeng‐Ping Chen、Limei Li、Jing-Wen Jin 等 8 位作者2012-04-02Analytical Chemistry

Particle size distribution and compactness have significant confounding effects on Raman signals of powder mixtures, which cannot be effectively modeled or corrected by traditional multivariate linear calibration methods such as partial least-squares (PLS), and therefore greatly deteriorate the predictive abilities of…

Spectroscopy and Chemometric AnalysesAnalytical Chemistry and ChromatographyCrystallization and Solubility Studies

Resistive switching characteristics of solution-deposited Gd, Dy, and Ce-doped ZrO2 films

Myung Soo Lee、Sungho Choi、Chee‐Hong An 等 4 位作者2012-04-02Applied Physics Letters

Several rare earth elements (Gd, Dy, and Ce) having different valence numbers were doped into a solution-synthesized ZrO2 film, and the corresponding resistive memory characteristics were discussed in relation to the oxygen vacancies and film microstructure. Pure and trivalent ion-doped ZrO2 films showed forming-free…

Semiconductor materials and devicesAdvanced Memory and Neural ComputingTransition Metal Oxide Nanomaterials

Resolution of identity approach for the Kohn-Sham correlation energy within the exact-exchange random-phase approximation

Patrick Bleiziffer、Andreas Heßelmann、Andreas Görling2012-04-02The Journal of Chemical Physics

Two related methods to calculate the Kohn-Sham correlation energy within the framework of the adiabatic-connection fluctuation-dissipation theorem are presented. The required coupling-strength-dependent density-density response functions are calculated within exact-exchange time-dependent density-functional theory, i.…

Advanced Chemical Physics StudiesSpectroscopy and Quantum Chemical StudiesMachine Learning in Materials Science

Synchrotron Infrared Measurements of Protein Phosphorylation in Living Single PC12 Cells during Neuronal Differentiation

Liang Chen、Hoi‐Ying N. Holman、Zhao Hao 等 7 位作者2012-04-02Analytical Chemistry

Protein phosphorylation is a post-translational modification that is essential for the regulation of many important cellular activities, including proliferation and differentiation. Current techniques for detecting protein phosphorylation in single cells often involve the use of fluorescence markers, such as antibodie…

Protein Structure and DynamicsEnzyme Structure and FunctionSpectroscopy Techniques in Biomedical and Chemical Research

Crucial Role of Protein Flexibility in Formation of a Stable Reaction Transition State in an α-Amylase Catalysis

Takahiro Kosugi、Shigehiko Hayashi2012-04-02Journal of the American Chemical Society

Conformational flexibility of proteins provides enzymes with high catalytic activity. Although the conformational flexibility is known to be pivotal for the ligand binding and release, its role in the chemical reaction process of the reactive substrate remains unclear. We determined a transition state of an enzymatic…

Protein Structure and DynamicsEnzyme Structure and FunctionEnzyme Production and Characterization

Influence of Substrate Wettability on the Morphology of Thin Polymer Films Spin-Coated on Topographically Patterned Substrates

Sudeshna Roy、Khalid Jamal Ansari、Surendra Sasikumar Jampa 等 5 位作者2012-04-02ACS Applied Materials & Interfaces

We show that the morphology of a thin polymer film spin coated directly on to a topographically patterned substrate is strongly influenced by the wettability of the substrate, in addition to other well-known parameters such as concentration of the polymer solution (c(n)), spin speed (RPM), and spin duration. Similar t…

Block Copolymer Self-AssemblyFluid Dynamics and Thin FilmsNanofabrication and Lithography Techniques

High-Temperature Ignition Delay Times and Kinetic Study of Furan

Liangjie Wei、Chenglong Tang、Xingjia Man 等 5 位作者2012-04-02Energy & Fuels

High-temperature ignition delay times of furan were measured behind the reflected shock waves at the elevated pressures (1.2–10.4 atm) for the mixtures with equivalence ratios of 0.5, 1.0, and 2.0 and furan concentrations of 0.25, 0.5 and 1% diluted in argon. An empirical equation was formulated to correlate the measu…

Thermochemical Biomass Conversion ProcessesAdvanced Combustion Engine TechnologiesCatalytic Processes in Materials Science

Design of ductile bulk metallic glasses by adding “soft” atoms

N. Zheng、Rui Qu、S. Pauly 等 7 位作者2012-04-02Applied Physics Letters

We propose a strategy for the design of ductile bulk metallic glasses (BMGs) through minor substitution using relatively large atoms, which make the bonding nature become more metallic and with it less shear resistant. Such a locally modified structure results in topological heterogeneity, which appears to be crucial…

Magnetic properties of thin filmsMetallic Glasses and Amorphous AlloysElectromagnetic wave absorption materials

Destabilization of Colloidal Suspensions by Multivalent Ions and Polyelectrolytes: From Screening to Overcharging

István Szilágyi、Amin Sadeghpour、Michal Borkovec2012-04-02Langmuir

The destabilization of charged colloidal suspensions is studied in the presence of polyelectrolytes and the corresponding oligomers. Two different systems are investigated, namely, negatively charged particles in the presence of polyamines and positively charged ones in the presence of polycarboxylates. Multivalent ol…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsElectrostatics and Colloid Interactions

Computed Tomography Imaging of Primary Lung Cancer in Mice Using a Liposomal-Iodinated Contrast Agent

Cristian T. Badea、Khannan K. Athreya、Gabriela Espinosa 等 10 位作者2012-04-02PLoS ONE

PURPOSE: To investigate the utility of a liposomal-iodinated nanoparticle contrast agent and computed tomography (CT) imaging for characterization of primary nodules in genetically engineered mouse models of non-small cell lung cancer. METHODS: Primary lung cancers with mutations in K-ras alone (Kras(LA1)) or in combi…

Nanoparticle-Based Drug DeliveryLung Cancer Diagnosis and TreatmentMedical Imaging Techniques and Applications

Actively tunable bistable optical Yagi-Uda nanoantenna

Ivan S. Maksymov、Andrey E. Miroshnichenko、Yuri S. Kivshar2012-04-02Optics Express

We propose and theoretically demonstrate a novel type of optical Yagi-Uda nanoantennas tunable via variation of the free-carrier density of a semiconductor disk placed in a gap of a metallic dipole feeding element. Unlike its narrowband all-metal counterparts, this nanoantenna exhibits a broadband unidirectional emiss…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

Theory of volume transition in polyelectrolyte gels with charge regularization

Jing Hua、Mithun K. Mitra、M. Muthukumar2012-04-02The Journal of Chemical Physics

We present a theory for polyelectrolyte gels that allow the effective charge of the polymer backbone to self-regulate. Using a variational approach, we obtain an expression for the free energy of gels that accounts for the gel elasticity, free energy of mixing, counterion adsorption, local dielectric constant, electro…

Hydrogels: synthesis, properties, applicationsPolymer Surface Interaction StudiesElectrostatics and Colloid Interactions

Double layer capacitance measured by organic field effect transistor operated in water

Tobias Cramer、Adrica Kyndiah、Mauro Murgia 等 6 位作者2012-04-02Applied Physics Letters

Pentacene ultra thin film transistors were exposed to water and operated with a conventional silicon/silicon oxide bottom gate and an electrolyte top gate controlled by a working electrode. The transistors are highly sensible (µV) to the electrochemical potential of the aqueous electrolyte. We show that dual gate oper…

Conducting polymers and applicationsAnalytical Chemistry and SensorsNeuroscience and Neural Engineering

Enhancement of perpendicular magnetic anisotropy through reduction of Co-Pt interdiffusion in (Co/Pt) multilayers

S. Bandiera、R. C. Sousa、B. Rodmacq 等 4 位作者2012-04-02Applied Physics Letters

We demonstrate that the effective magnetic anisotropy of sputtered (Co/Pt) multilayers can be doubled by limiting the interdiffusion occurring at Co/Pt interfaces. We present a way to decrease the interdiffusion by inserting an ultra-thin Cu layer at or near the Co/Pt interfaces. When such a material is sputtered on C…

Magnetic properties of thin filmsZnO doping and propertiesMagnetic Properties and Applications

TiO2 Derived by Titanate Route from Electrospun Nanostructures for High-Performance Dye-Sensitized Solar Cells

A. Sreekumaran Nair、Peining Zhu、Veluru Jagadeesh Babu 等 8 位作者2012-04-02Langmuir

We report the use of highly porous, dense, and anisotropic TiO(2) derived from electrospun TiO(2)-SiO(2) nanostructures through titanate route in dye-sensitized solar cells. The titanate-derived TiO(2) of high surface areas exhibited superior photovoltaic parameters (efficiency > 7%) in comparison to the respective el…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesAdvanced Nanomaterials in Catalysis