Materials Literature
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In this paper we report on the positron lifetime results obtained for brown and colourless natural diamond. Optical effects of the observed vacancy defects in brown, high pressure, high temperature (HPHT) treated colourless and naturally colourless type IIa diamond samples were studied by combining the positron measur…
Abstract Naturally amorphous biopolyester poly(3‐hydroxybutyrate‐ co ‐4‐hydroxybutyrate) (P3/4HB) containing 21 mol % of 4HB was blended with semi‐crystal poly(butylene succinate) (PBS) with an aim to improve the properties of aliphatic polyesters. The effect of PBS contents on miscibility, thermal properties, crystal…
The formation and properties of (110)-textured P-doped microcrystalline CVD diamond were studied. Based on several microscopy techniques, with a special emphasis on electron backscattered diffraction, a detailed determination of the grain orientations with respect to the exact [110] axis is given. The different orient…
Abstract Three sulfonato‐containing fluorene‐based anionic water‐soluble conjugated polymers, which are specially designed to link fluorene with alternating moieties such as bipyridine ( P1 ), pyridine ( P2 ), and benzene ( P3 ) have been synthesized via the Pd‐catalyzed Sonogashira‐coupling reaction, respectively. Th…
A simple one-dimensional Monte Carlo model has been developed to simulate the chemical vapour deposition (CVD) of a diamond (100) surface. The model considers adsorption, etching/desorption, lattice incorporation, and surface migration along and across the dimer rows. The top of a step-edge is considered to have an in…
Abstract Polyaniline soluble in organic solvents was prepared using dodecylbenzenesulphonic acid (DBSA) as functional dopant. The solubility parameter was calculated and the most suitable solvent chloroform was checked for the solubility and the most compatible polymer PMMA was selected for blending. Miscibility was m…
Abstract The dissolution of hydroxyapatite (HAP) and fluorapatite (FAP) has been studied (25 °C, 0.1 M NaCl medium) within the pH ranges 2–11 (FAP) and 4–10 (HAP). A range of techniques has been utilized to achieve understanding in how these two abundant minerals may interact with their natural surroundings (e.g., bod…
Abstract Here, a colloidal templating procedure for generating high‐density arrays of gold macroporous microwells, which act as discrete sites for surface‐enhanced Raman scattering (SERS), is reported. Development of such a novel array with discrete macroporous sites requires multiple fabrication steps. First, selecti…
In this study, lead-free 0.95(K0.5Na0.5)NbO3-0.05Li(Sb1 − x Nb x )O3 system ceramics were fabricated according to the amount of Nb substitution for Sb site of LiSbO3 ceramics and their dielectric and piezoelectric characteristics were investigated. With increasing the amount of Nb substitution, electromechanical coupl…
Hydrogen constitutes nearly half of all atoms in proteins and their positions are essential for analyzing hydrogen-bonding interactions and refining atomic-level structures. However, most protein structures determined by experiments or computer prediction lack hydrogen coordinates. We present a new algorithm, HAAD, to…
The adsorbate–substrate interaction between carbon monoxide and clean and hydroxylated surfaces of anatase (001) was simulated by periodic DFT calculations. For the clean surface, different periodicities were taken into account in order to investigate the influence of lateral effects. The results show that the molecul…
Abstract Phenylacetylene derivatives containing carbazole ( 1 ) and fluorene ( 2 ) moieties were polymerized by [Rh(nbd)Cl] 2 into corresponding polymers P 1 and P 2 of high molecular weights ( M w ∼ 150 × 10 3 –465 × 10 3 ) in high yields (up to 98%). The polymers were characterized by NMR, IR, UV, PL, and CV techniq…
According to the predictions of first-principles calculations, single-wall silicon carbide nanotubes exhibit several unusual properties: they are semiconducting independently of their chirality, superior material for hydrogen storage, and have strong nonlinear optical coefficients. Nevertheless, only a single experime…
This paper introduces a new technique to the study of diamonds: mapping the luminescence lifetime of optical centres. The understanding of luminescence lifetimes in diamond is briefly reviewed. Since lifetime mapping involves extended measuring times with focused laser excitation, the stability of the H3 optical centr…
The kinetics of the recovery of radiation damage in type Ia diamond has been investigated using isothermal annealing at 600 °C. In diamonds having a reasonably homogeneous distribution of nitrogen the decay of the vacancy concentration with time can be approximately described by a single exponential. Previous investig…
We report on electrical measurements of the effective density of states in the ferromagnetic semiconductor material (Ga,Mn)As. By analyzing the conductivity correction to an enhanced electron-electron interaction the electrical diffusion constant was extracted for (Ga,Mn)As samples of different dimensionality. Using t…
The chiral Swiss roll metamaterial is a resonant, magnetic medium that exhibits a negative refractive band for one-wave polarization. Its unique structure facilitates huge chiral effects: a plane polarized wave propagating through this system can change its polarization by 90° in less than a wavelength. Such chirality…
Abstract A novel fabrication method is developed for the preparation of superhydrophobic surfaces. The procedure uses focal conic structures of semi‐fluorinated smectic liquid crystals (LCs) whose periodic toric focal conic domains (TFCDs) are prepared on a surface modified substrate. Reactive ion etching (RIE) on the…
A straightforward synthetic approach to the preparation of disulfide linked hyperbranched polymers with peripheral pyridyl disulfide functionalities is described. The hyperbranched polymers were obtained by the condensation of novel AB 2 macromonomers bearing α-dithobenzoate and ω-double pyridyl disulfide end-groups.…
Approaches for enhancing the strength and toughness of single-crystal diamond produced by chemical vapor deposition (CVD) at high growth rates are described. CVD processes used to grow single-crystal diamond in high density plasmas were modified to incorporate boron and nitrogen. Semi-quantitative studies of mechanica…