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Dynamic structural changes of pentacopper(ii) chains supported by N6-donor ligands

Yukie Takemura、Takayuki Nakajima、Tomoaki Tanase 等 7 位作者2009-01-01Chemical Communications

Elastic pentacopper molecular chains, [Cu5(panapy)4X2] (X=Cl (), Br ()) and [Cu5(panapy)4]X'2 (X'=BF4 (), PF6 ()), were prepared using a naphthyridine-modulated N6-donor ligand, panapy2-, and showed magnetically coupled, dynamic rearrangement of five Cu(II) ions switched by the presence/absence of halide termination.

Organometallic Complex Synthesis and CatalysisMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Novel sesquiterpene and coumarin constituents from the whole herbs of Crossostephium chinense

Qi Wu、Lei Zou、Xiu‐Wei Yang 等 4 位作者2009-01-01Journal of Asian Natural Products Research

Novel sesquiterpene, named crossostephin (1), and coumarin, named biscopoletin (2), together with four known compounds, artesin, tanacetin, scopoletin, and scopolin, were isolated from the 70% ethanolic extract of the whole herbs of Crossostephium chinense (L.) Makino. Their structures were determined by spectroscopic…

Natural product bioactivities and synthesisSesquiterpenes and Asteraceae StudiesPhytochemistry and Bioactive Compounds

Wear Resistance of AISI316L Steel Modified by Pre-FPP Treated DLC Coating

Hiroshi Nanbu、Shoichi Kikuchi、Yutaka Kameyama 等 4 位作者2009-01-01Journal of Solid Mechanics and Materials Engineering

In order to improve the adhesion strength of the DLC coating, Fine Particle Peening (FPP) treatment was employed as pretreatment for DLC coatings. FPP treatment was performed using SiC shot particles, and then the AISI316L steel was DLC-coated. The FPP treatment increased the surface roughness of the specimen, and a S…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchTribology and Wear Analysis

Synthesis of superparamagnetic iron(iii) oxide nanowires in double-walled carbon nanotubes

Carmen-Mihaela Tîlmaciu、Brigitte Soula、Anne-Marie Galibert 等 11 位作者2009-01-01Chemical Communications

The synthesis and characterization of superparamagnetic iron(iii) oxide nanowires confined within double-walled carbon nanotubes by capillary filling with a melted precursor (iron iodide) followed by thermal treatment is reported for the first time.

Carbon Nanotubes in CompositesSupercapacitor Materials and FabricationIron oxide chemistry and applications

Nanocrystallization and structural correlation in quasicrystalline and crystalline phases during mechanical milling

R. S. Tiwari、Thakur Prasad Yadav、N.K. Mukhopadhyay 等 5 位作者2009-01-01Zeitschrift für Kristallographie - Crystalline Materials

Abstract The main objective of the proposed work is to investigate the formation of nanoquasicrystalline and related nanocrystalline phases in Al—Cu—Fe system during mechanical milling at the initial stage of milling. The mechanical milling of a quasicrystalline Al 65 Cu 20 Fe 15 alloy was performed in a high-energy b…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesQuasicrystal Structures and Properties

Morphological control of vertically self-aligned nanosheets formed on magnesium alloy by surfactant-free hydrothermal synthesis

Takahiro Ishizaki、Sung-Pyo Cho、Naobumi Saito2009-01-01CrystEngComm

Crystalline nanosheets were successfully formed on magnesium alloy AZ31 by a facile surfactant-free hydrothermal treatment using aqueous solution. The crystal structures and shapes of the nanosheets changed with the treatment temperature. On treatment at 120 °C, rosette-like structures made from curved nanosheets of c…

Magnesium Alloys: Properties and ApplicationsLayered Double Hydroxides Synthesis and ApplicationsMagnesium Oxide Properties and Applications

Functionalized Electrolytic Manganese Dioxide Nanostructure Prepared at Fixed pH for Electrochemical Supercapacitor

H. Adelkhani2009-01-01Journal of The Electrochemical Society

MnO 2 samples are synthesized by an electrodeposition technique at a fixed pH and are tested as active electrode material for an electrochemical supercapacitor. The physicochemical properties of electrolytic manganese dioxide, including average Mn oxidation state, amount of incorporated water, porosity, crystal struct…

Supercapacitor Materials and FabricationGas Sensing Nanomaterials and SensorsLaser-Ablation Synthesis of Nanoparticles

First Principles Calculations of Vacancy Formation Energies in &Sigma;13 Pyramidal Twin Grain Boundary of &alpha;-Al<SUB>2</SUB>O<SUB>3</SUB>

Nobuaki Takahashi、Teruyasu Mizoguchi、Tetsuya Tohei 等 8 位作者2009-01-01MATERIALS TRANSACTIONS

Defect energetics in Σ13 pyramidal twin grain boundary (GB) of Al2O3 was investigated by a first principles projector-augmented wave method. It was found that the vacancy formation energy depends on the atomic site and the defect energetics at the GB is similar to that in the bulk Al2O3, namely the oxygen vacancy show…

Advanced ceramic materials synthesisMicrostructure and mechanical propertiesSemiconductor materials and interfaces

Injection Molding of Wood–Fiber/Plastic Composite Foams

Jae D. Yoon、Takashi Kuboki、P.U. Jung 等 5 位作者2009-01-01Composite Interfaces

This paper investigates the feasibility of injection-molded wood–fiber/high-density polyethylene (HDPE) composite foams that can replace injection-molded HDPE solids in industrial applications. The study applies injection foam molding technology using a physical blowing agent to a wood–fiber/HDPE composite, and examin…

Natural Fiber Reinforced CompositesInjection Molding Process and PropertiesPolymer Foaming and Composites

Facile synthesis of dicyanovinyl-di(meso-aryl)dipyrromethenes via a dipyrromethene–DDQ adduct

Ji‐Young Shin、Brian O. Patrick、David Dolphin2009-01-01Organic & Biomolecular Chemistry

The dicyano-substituted vinyl dipyrromethene and compound are near-planar and were prepared from a simple meso-aryl dipyrromethane via the DDQ adduct ; the unique structures of , and were confirmed by X-ray diffraction analysis.

Organic Electronics and PhotovoltaicsPorphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent Materials

Effects of the S∕Zn Ratio on the Photoluminescence Properties of Color-Tunable ZnS:Mn Nanophosphors

Ying-Chien Fang、Sheng‐Yuan Chu、Hung-Cheng Chen 等 6 位作者2009-01-01Journal of The Electrochemical Society

Effects of the S ∕ Zn Ratio on the Photoluminescence Properties of Color-Tunable ZnS:Mn Nanophosphors, Fang, Ying-Chien, Chu, Sheng-Yuan, Chen, Hung-Cheng, Kao, Po-Ching, Chen, In-Gann, Hwang, Chii-Shyang

Advanced biosensing and bioanalysis techniquesPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Energy distributions and effective temperatures in the packing of elastic sheets

S. Deboeuf、Mokhtar Adda-Bedia、Arezki Boudaoud2009-01-01Europhysics Letters (EPL)

The packing of elastic sheets is investigated in a quasi two-dimensional experimental setup: a sheet is pulled through a rigid hole acting as a container, so that its configuration is mostly prescribed by the cross-section of the sheet in the plane of the hole. The characterisation of the packed configuration is made…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesGranular flow and fluidized beds

Soret emission from water-soluble porphyrin thin films: effect on the electroluminescence response

Marta Pérez-Morales、Gustavo de Miguel、Henk J. Bolink 等 5 位作者2009-01-01Journal of Materials Chemistry

The emission properties of TSPP [tetrakis(4-sulfonatophenyl) porphyrin] and TMPyP [tetrakis(4-methylpyridyl) porphyrin] in thin films, prepared both by the Langmuir–Blodgett technique and the spin-coating method, have been investigated. Surprisingly, in most of the samples analyzed, the emission spectra do not show th…

Porphyrin and Phthalocyanine ChemistryMolecular Junctions and NanostructuresPhotochemistry and Electron Transfer Studies

Layering transitions in colloidal crystal thin films between 1 and 4 monolayers

Fernando Ramiro‐Manzano、E. Bonet、Isabelle Rodríguez 等 4 位作者2009-01-01Soft Matter

This paper investigates the sequence of morphological transitions in a nearly hard particle arrangement of colloidal crystals confined in a wedge cell. Earlier studies have shown intermediate particle arrangements (such as the buckling, rhombic, prismatic, and hcp like phases) to account for the drastic changes in the…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Fabrication and characteristics of mesh band-pass filters

M. A. Tarasov、V. D. Gromov、Г. Д. Богомолов 等 5 位作者2009-01-01Instruments and Experimental Techniques

Mesh band-pass filters for 300-, 450-, 600-, and 750-GHz central frequencies are designed and manufactured. Copper and aluminum foil and foil-clad Teflon filters were made by chemical and ionic etching methods, and an aluminum film evaporated on a kapton film was formed by the lift-off lithography method. A gold layer…

Photonic and Optical DevicesPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Electrodeposition of Nanocrystalline CeO[sub 2] on Si(001)

V. Fernandes、J. J. Klein、W. H. Schreiner 等 5 位作者2009-01-01Journal of The Electrochemical Society

We report the cathodic electrodeposition of cerium oxide thin films from cerium-chloride aqueous solutions on p-type Si(001) substrates under illumination. Transmission electron microscopy coupled with electron diffraction analyses show that the deposits exhibited a nanocrystalline structure with a significant amorpho…

Electrocatalysts for Energy ConversionCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Electrochromic Properties of MnO[sub 2]-Based Layered Polymer Nanocomposite

Masaharu Nakayama、Yoshinori Kashiwa、Kazushi Suzuki2009-01-01Journal of The Electrochemical Society

This paper presents electrochromic properties of manganese oxide-based multilayered nanocomposite that was grown electrochemically on a transparent indium-tin oxide (ITO)-coated glass slide in a thin-film form. The composite film consists of negatively charged manganese oxide nanolayers and the intercalated cationic p…

Supercapacitor Materials and FabricationConducting polymers and applicationsTransition Metal Oxide Nanomaterials

Growth and Characterisation of Nonlinear Optical Single Crystals of L-Alaninium Oxalate

K. Arun、S. Jayalekshmi2009-01-01Journal of Minerals and Materials Characterization and Engineering

A potential organic nonlinear optical (NLO) single crystal based on amino acid, L alaninium oxalate (LAO) is grown using the simple chiral amino acid L alanine and oxalic acid by slow evaporation method. Grown crystals have an optimum dimension of 40 x15 x 8 mm 3 with good optical quality and are characterized by powd…

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchPhotochemistry and Electron Transfer Studies

Cellular Magnetic Resonance Imaging Using Superparamagnetic Anionic Iron Oxide Nanoparticles: Applications to In Vivo Trafficking of Lymphocytes and Cell-Based Anticancer Therapy

П. В. Смирнов2009-01-01Methods in molecular biology

In current cancer research, the application of cytotoxic T lymphocytes with specificity to tumor antigens is regarded as a real therapeutic hope. The objective of imaging is to provide a follow-up of these killer cells in real time, in order to gain a better understanding of the mechanisms and action modes of lymphocy…

Nanoparticle-Based Drug DeliveryImmunotherapy and Immune ResponsesMolecular Communication and Nanonetworks

Natural Pollution Test of Composite and Porcelain Insulators Under AC and DC Stress

Yuanxiang Zhou2009-01-01Gao dianya jishu

A natural pollution was tested to study the pollution and self cleaning characteristics of composite insulators and porcelain insulators (type: XP-70,XWP-70) energized with AC and DC voltage. Under the station’s condition,pollution differences between different insulators and different stresses mainly appeared on the…

High voltage insulation and dielectric phenomena