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The First Molecular Level Monitoring of Carbohydrate Conversion to 5‐Hydroxymethylfurfural in Ionic Liquids. B2O3—An Efficient Dual‐Function Metal‐Free Promoter for Environmentally Benign Applications

Е. А. Хохлова、Вадим В. Качала、Valentine P. Ananikov2012-02-22ChemSusChem

The mechanistic nature of the conversion of carbohydrates to the sustainable platform chemical 5-hydroxymethylfurfural (5-HMF) was revealed at the molecular level. A detailed study of the key sugar units involved in the biomass conversion process has shown that the simple dissolution of fructose in the ionic liquid 1-…

Supercapacitor Materials and FabricationMesoporous Materials and CatalysisCatalysis for Biomass Conversion

An Extended Photoelectrothermal Theory for LED Systems: A Tutorial From Device Characteristic to System Design for General Lighting

S.Y.R. Hui、Huanting Chen、Xuehui Tao2012-02-22IEEE Transactions on Power Electronics

LED technology is a multidisciplinary subject that involves semiconductor physics, photometry, electric power, heat, and chromaticity. It has been demonstrated that operating the LED load at its rated power does not necessarily guarantee optimal luminous performance unless the LED system is properly designed. This pap…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGas Sensing Nanomaterials and Sensors

Tetrachlorinated Tetraazaperopyrenes (TAPPs): Highly Fluorescent Dyes and Semiconductors for Air‐Stable Organic n‐Channel Transistors and Complementary Circuits

Susanne C. Martens、Ute Zschieschang、Hubert Wadepohl 等 5 位作者2012-02-22Chemistry - A European Journal

A range of 2,9-perfluoroalkyl-substituted tetraazaperopyrene (TAPP) derivatives (1-5) was synthesised by reacting 4,9-diamino-3,10-perylenequinone diimine (DPDI) with the corresponding carboxylic acid chloride or anhydride in the presence of a base. The reaction of compounds 1-4 with dichloroisocyanuric acid (DIC) in…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

Phase Separation and Molecular Intermixing in Polymer–Fullerene Bulk Heterojunction Thin Films

Matthias A. Ruderer、Robert J. Meier、Lionel Porcar 等 5 位作者2012-02-22The Journal of Physical Chemistry Letters

The phase separation and molecular intermixing in poly(3-hexylthiophene) (P3HT)/[6,6]-phenyl-C61 butyric acid methyl ester (PCBM) bulk heterojunction thin films are investigated as a function of the overall PCBM content. The structural length scales, phase sizes, and molecular miscibility ratio in bulk heterojunction…

Organic Electronics and PhotovoltaicsThin-Film Transistor TechnologiesThermal properties of materials

Determining the Bulk Viscosity of Rigid Water Models

George S. Fanourgakis、J. S. Medina、Rita Prosmiti2012-02-22The Journal of Physical Chemistry A

We use equilibrium molecular dynamics methods to compute the shear and bulk viscosities of the pairwise additive and rigid SPC/E, TIP4P, and TIP4P/2005 water models. For the latter model it was found in a recent study (J. Chem. Phys. 2009, 131, 246101) an excellent agreement with experiment in the prediction of the sh…

Material Dynamics and PropertiesTheoretical and Computational PhysicsSpectroscopy and Quantum Chemical Studies

Analytic design method for optimal imaging: coupling three ray sets using two free-form lens profiles

Fabian Duerr、Pablo Benı́tez、Juan C. Miñano 等 5 位作者2012-02-22Optics Express

In this work, a new two-dimensional optics design method is proposed that enables the coupling of three ray sets with two lens surfaces. The method is especially important for optical systems designed for wide field of view and with clearly separated optical surfaces. Fermat's principle is used to deduce a set of func…

Semiconductor Lasers and Optical DevicesAdvanced optical system designOptical Coatings and Gratings

Texture‐etched ZnO as a versatile base for optical back reflectors with well‐designed surface morphologies for application in thin film solar cells

W. Böttler、Vladimir Smirnov、J. Hüpkes 等 4 位作者2012-02-22physica status solidi (a)

Abstract ZnO layers with a wide range of surface morphologies were studied for applications in thin film silicon solar cells. The texture of ZnO layers, achieved by chemical etching, was measured by atomic force microscopy (AFM) and statistically analyzed in terms of the roughness, the crater depth, the crater diamete…

Thin-Film Transistor TechnologiesOptical Coatings and GratingsSurface Roughness and Optical Measurements

Tuning the Tricritical Point with Spin-Orbit Coupling in Polarized Fermionic Condensates

Renyuan Liao、Yu Yi-Xiang、Wu‐Ming Liu2012-02-22Physical Review Letters

We investigate a two-component atomic Fermi gas with population imbalance in the presence of Rashba-type spin-orbit coupling (SOC). As a competition between SOC and population imbalance, the finite-temperature phase diagram reveals a large variety of new features, including the expanding of the superfluid state regime…

Cold Atom Physics and Bose-Einstein CondensatesMagnetic and transport properties of perovskites and related materialsAtomic and Subatomic Physics Research

Domain wall propagation in micrometric wires: Limits of single domain wall regime

V. Zhukova、J.M. Blanco、Valeria Rodionova 等 5 位作者2012-02-22Journal of Applied Physics

We measured magnetic domain propagation and local domain wall(DW) nucleation in Fe-Co-rich amorphous microwires with metallic nucleus diameters from 2.8 to 18 μm. We found that manipulation of magnetoelastic energy through application of applied stresses, changing of magnetostriction constant, and variation of interna…

Magnetic properties of thin filmsMetallic Glasses and Amorphous AlloysMagnetic Properties and Applications

Can orbital-free density functional theory simulate molecules?

Junchao Xia、Chen Huang、Ilgyou Shin 等 4 位作者2012-02-22The Journal of Chemical Physics

Orbital-free density functional theory (OFDFT), with its attractive linearly scaling computation cost and low prefactor, is one of the most powerful first principles methods for simulating large systems (~10(4)-10(6) atoms). However, approximating the electron kinetic energy with density functionals limits the accurac…

Advanced Chemical Physics StudiesMachine Learning in Materials ScienceInorganic Chemistry and Materials

Elastic Moduli Inheritance and the Weakest Link in Bulk Metallic Glasses

Dong Ma、A. D. Stoica、Xun‐Li Wang 等 6 位作者2012-02-22Physical Review Letters

We show that a variety of bulk metallic glasses (BMGs) inherit their Young's modulus and shear modulus from the solvent components. This is attributed to preferential straining of locally solvent-rich configurations among tightly bonded atomic clusters, which constitute the weakest link in an amorphous structure. This…

Material Dynamics and PropertiesMetallic Glasses and Amorphous AlloysPhase-change materials and chalcogenides

Preparation of Calcium Alginate Nanoparticles Using Water-in-Oil (W/O) Nanoemulsions

Alexandra H.E. Machado、Dan Lundberg、António J. Ribeiro 等 7 位作者2012-02-22Langmuir

A procedure for the preparation of calcium alginate nanoparticles in the aqueous phase of water-in-oil (W/O) nanoemulsions was developed. The emulsions were produced from mixtures of the nonionic surfactant tetraethylene glycol monododecyl ether (C(12)E(4)), decane, and aqueous solutions of up to 2 wt % sodium alginat…

Proteins in Food SystemsSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Soot Emissions of Various Oxygenated Biofuels in Conventional Diesel Combustion and Low-Temperature Combustion Conditions

Hai Feng Liu、Xiaojie Bi、Ming Huo 等 5 位作者2012-02-22Energy & Fuels

To investigate the effects of oxygenated biofuels on soot formation, oxidation, and distribution, a detailed comparative study using the forward illumination light extinction method was conducted in an optical constant volume combustion chamber. Various ambient temperatures (800 and 1000 K) and ambient oxygen concentr…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceBiodiesel Production and Applications

Massign: An Assignment Strategy for Maximizing Information from the Mass Spectra of Heterogeneous Protein Assemblies

Nina Morgner、Carol V. Robinson2012-02-22Analytical Chemistry

Electrospray ionization mass spectrometry (ESI-MS) has evolved into a powerful adjunct for structural biology, helping to unravel the quaternary structure of protein complexes. Increasing interest has led to the study of ever larger multicomponent systems. Investigating these large complexes with ESI has meant that pr…

Protein Structure and DynamicsMass Spectrometry Techniques and ApplicationsEnzyme Structure and Function

Human Adult Dental Pulp Stem Cells Enhance Poststroke Functional Recovery Through Non-Neural Replacement Mechanisms

Wai Khay Leong、Tanya L. Henshall、Agnes Arthur 等 13 位作者2012-02-22Stem Cells Translational Medicine

Human adult dental pulp stem cells (DPSCs), derived from third molar teeth, are multipotent and have the capacity to differentiate into neurons under inductive conditions both in vitro and following transplantation into the avian embryo. In this study, we demonstrate that the intracerebral transplantation of human DPS…

Mesenchymal stem cell researchElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Dissecting Contact Mechanics from Quantum Interference in Single-Molecule Junctions of Stilbene Derivatives

Sriharsha V. Aradhya、Jeffrey Meisner、Markrete Krikorian 等 8 位作者2012-02-22Nano Letters

Electronic factors in molecules such as quantum interference and cross-conjugation can lead to dramatic modulation and suppression of conductance in single-molecule junctions. Probing such effects at the single-molecule level requires simultaneous measurements of independent junction properties, as conductance alone c…

Graphene research and applicationsMolecular Junctions and NanostructuresForce Microscopy Techniques and Applications

Lewis Acido-Basic Interactions between CO 2 and MgO Surface: DFT and DRIFT Approaches

Damien Cornu、Hazar Guesmi、Jean‐Marc Krafft 等 4 位作者2012-02-22The Journal of Physical Chemistry C

Combined experimental infrared (IR) and theoretical approaches have been carried out in an attempt to specify the actual structure of the CO 2 species adsorbed on the magnesium oxide surface. The interaction of CO 2 with regular sites of the MgO(100), (111), and (110) surfaces as well as MgO(100) defect sites (steps,…

Catalytic Processes in Materials ScienceZeolite Catalysis and SynthesisCatalysis and Oxidation Reactions

Food Industrial Processes - Methods and Equipment

Benjamín Valdez2012-02-22InTech eBooks

The global food industry has the largest number of demanding and knowledgeable consumers: the world population of seven billion inhabitants, since every person eats! This population requires food products that fulfill the high quality standards established by the food industry organizations. Food shortages threaten hu…

Nanoparticles: synthesis and applicationsElectrochemical sensors and biosensorsAgricultural and Food Sciences

Concise Review: The Clinical Application of Mesenchymal Stem Cells for Musculoskeletal Regeneration: Current Status and Perspectives

Andre F. Steinert、Lars Rackwitz、Fabian Gilbert 等 5 位作者2012-02-22Stem Cells Translational Medicine

Regenerative therapies in the musculoskeletal system are based on the suitable application of cells, biomaterials, and/or factors. For an effective approach, numerous aspects have to be taken into consideration, including age, disease, target tissue, and several environmental factors. Significant research efforts have…

Mesenchymal stem cell researchElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

From Electromagnetically Induced Transparency to Superscattering with a Single Structure: A Coupled-Mode Theory for Doubly Resonant Structures

Lieven Verslegers、Zongfu Yu、Zhichao Ruan 等 5 位作者2012-02-22Physical Review Letters

We observe from simulations that a doubly resonant structure can exhibit spectral behavior analogous to electromagnetically induced transparency, as well as superscattering, depending on the excitation. We develop a coupled-mode theory that explains this behavior in terms of the orthogonality of the radiation patterns…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications