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A time-dependent density functional theory (TDDFT) interpretation of the optical spectra of zinc phthalocyanine π-cation and π-anion radicals

Angela Rosa、Giampaolo Ricciardi2009-07-01Canadian Journal of Chemistry

The UV–visible and near-IR spectra of the zinc phthalocyanine π-cation and π-anion radicals, [ZnPc(–1)] •+ and [ZnPc(–3)] •– , are investigated by time-dependent density functional theory (TDDFT) calculations using the pure, asymptotically correct, statistical average of (model) orbital potentials (SAOP) functional. T…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesMetal-Catalyzed Oxygenation Mechanisms

Effective hydrogen generator testing for on-site small engine

Praitoon Chaiwongsa、N. Pornsuwancharoen、P.P. Yupapin2009-07-01Physics Procedia

We propose a new concept of hydrogen generator testing for on-site small engine. In general, there is a trade-off between simpler vehicle design and infrastructure issues, for instance, liquid fuels such as gasoline and methanol for small engine use. In this article we compare the hydrogen gases combination the gasoli…

Fuel Cells and Related MaterialsHydrogen Storage and MaterialsHybrid Renewable Energy Systems

Interaction between dislocation and divalent impurity in KBr single crystals

T. Ohgaku、Takuya Matsunaga2009-07-01IOP Conference Series Materials Science and Engineering

Interaction between dislocation and divalent impurity has been investigated in KBr single crystals doped with various impurities by strain rate cycling tests under ultrasonic oscillation. The interaction energy between dislocation and impurity-vacancy dipole (I-V dipole) has been obtained by fitting Barnett model to e…

Metal and Thin Film MechanicsIntermetallics and Advanced Alloy PropertiesNuclear Materials and Properties

Polyelectrolyte multilayer films promote human cord blood stem cells differentiation into mature endothelial cells exhibiting a stable phenotype

Nicolas Salmon、Estelle Paternotte、Véronique Decot 等 6 位作者2009-07-01Bio-Medical Materials and Engineering

BACKGROUND: recent studies in bio-engineering have showed the influence of Polyelectrolyte Multilayer (PEM) films on endothelial cells (ECs), especially poly(sodium-4-styrene-sulfonate) (PSS) and poly(allylamine hydrochloride) (PAH). They were tested either with human mature ECs or rabbit immature endothelial progenit…

Hydrogels: synthesis, properties, applicationsElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

Intense Ultraviolet-Blue Photoluminescence from SiO2 Embedded Ge Nanocrystals Prepared by Different Techniques

P. K. Giri、S. Bhattacharyya、R. Kesavamoorthy 等 5 位作者2009-07-01Journal of Nanoscience and Nanotechnology

We have made systematic studies on the ultraviolet-blue photoluminescence (PL) from Ge nanocrystals (NCs) grown embedded in SiO2 matrix. Embedded Ge NCs are grown by two different methods, namely, radio-frequency magnetron sputtering (SPT) and ion implantation (IMP). For comparison, Ar implanted SiO2 layer was process…

Quantum Dots Synthesis And PropertiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Experimental and Numerical Investigation of the Thermal Performance of the Gas-Cooled Divertor Plate Concept

E. Gayton、L. Crosatti、D. L. Sadowski 等 6 位作者2009-07-01Fusion Science & Technology

The helium-cooled plate-type divertor concept proposed by Malang was designed to accommodate a surface heat load of ˜10 MW/m2. This design can potentially reduce the number of modules needed for the divertor by over two orders of magnitude compared with other concepts, thereby significantly reducing coolant delivery s…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Engineering Thermal-Hydraulics

Influence of silica nanoparticle surface treatments on the water treeing characteristics of low density polyethylene

Xingyi Huang、Zhisen Ma、Pingkai Jiang 等 7 位作者2009-07-01OpenAlex

Premature failure of XLPE cables can occur due to water trees increased the susceptibility of polyethylene insulation to breakdown, and extensive studies have been made to improve the resistance of polyethylene to water treeing in the past. In this study, we investigated the influence of the incorporation of silica na…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationDielectric materials and actuators

Multidisciplinary modeling and simulation of a fuel cell/gas turbine hybrid power system

Atideh Abbasi、Zhenhua Jiang2009-07-01OpenAlex

The fuel cell/gas-turbine hybrid power systems can utilize exhaust fuel and waste heat from fuel cells to increase the system efficiency. This paper considers an internally reforming solid oxide fuel cell/gas turbine (SOFC/GT) hybrid system, where the anode exhaust, which contains the remainder of the fuel, is mixed w…

Advancements in Solid Oxide Fuel CellsFuel Cells and Related MaterialsCatalysis and Oxidation Reactions

Stable Dispersions of Metal Oxide Nanowires and Nanoparticles in Water, Dimethylformamide and Toluene

Sandeep Ghosh、A. Gomathi、C.N.R. Rao2009-07-01Journal of Nanoscience and Nanotechnology

In view of the important need to generate well-dispersed inorganic nanostructures in various solvents, we have explored the dispersion of nanostructures of metal oxides such as TiO2, Fe3O4 and ZnO in solvents of differing polarity in the presence of several surfactants. The solvents used are water, dimethylformamide (…

Dendrimers and Hyperbranched Polymers

First-principles computational discovery of materials for hydrogen storage

Vidvuds Ozoliņš、Alireza Akbarzadeh、Hakan Günaydin 等 6 位作者2009-07-01Journal of Physics Conference Series

Hydrogen-fuelled vehicles require a cost-effective, lightweight material with precisely targeted thermodynamics and fast kinetics of hydrogen release. Since none of the conventional metal hydrides satisfy the multitude of requirements for a practical H 2 storage system, recent research efforts have turned to advanced…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsCarbon dioxide utilization in catalysis

Modelling plastic deformation of metals over a wide range of strain rates using irreversible thermodynamics

Mingxin Huang、Pedro E.J. Rivera-Díaz-del-Castillo、Olivier Bouaziz 等 4 位作者2009-07-01IOP Conference Series Materials Science and Engineering

Based on the theory of irreversible thermodynamics, the present work proposes a dislocation-based model to describe the plastic deformation of FCC metals over wide ranges of strain rates. The stress-strain behaviour and the evolution of the average dislocation density are derived. It is found that there is a transitio…

Microstructure and mechanical propertiesHigh-pressure geophysics and materialsHigh-Velocity Impact and Material Behavior

Do pyrotechnics contain radium?

Georg Steinhäuser、Andreas Musilek2009-07-01Environmental Research Letters

Many pyrotechnic devices contain barium nitrate which is used as an oxidizer and colouring agent primarily for green-coloured fireworks.Similarly, strontium nitrate is used for red-coloured pyrotechnic effects.Due to their chemical similarities to radium, barium and strontium ores can accumulate radium, causing a rema…

Radioactivity and Radon MeasurementsGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies

Structural modifications induced by electron irradiation in SiO 2 glass: Local densification measurements

Gianpiero Buscarino、S. Agnello、F. M. Gelardi2009-07-01Europhysics Letters (EPL)

We report a study on the structural modifications induced in amorphous silicon dioxide ( a -SiO 2 ) by electron irradiation in the dose range from 1.2·10 3 to 5·10 6 kGy. This study has been performed by investigating the properties of the 29 Si hyperfine structure of the E ' γ center by electron paramagnetic resonanc…

Glass properties and applicationsThin-Film Transistor TechnologiesIon-surface interactions and analysis

The Shell Features ofCornu aspersum(SynonymHelix aspersa) andHelix pomatia: Characteristics and Comparison

Maciej Ligaszewski、Krzysztof Surówka、Julia Stekla2009-07-01American Malacological Bulletin

We examine the morphometric, chemical, and physical properties of adult shells from breeding populations of Cornu aspersum maxima (Taylor, 1883), Cornu aspersum aspersum (Müller, 1774), and Helix pomatia (Linnaeus, 1758). The higher thermal requirements of the African subspecies C. aspersum maxima were confirmed by th…

Parasite Biology and Host InteractionsCalcium Carbonate Crystallization and InhibitionMollusks and Parasites Studies

MICROSCOPIC OBSERVATIONS OF LEATHER LOOSENESS AND ITS EFFECTS ON MECHANICAL PROPERTIES

Cheng‐Kung Liu、Nicholas P. Latona、Joseph J. Lee 等 4 位作者2009-07-01Journal of the American Leather Chemists Association

Looseness is a very troublesome issue regarding the structure of leather as well as the final leather product. It is a great concern to tanners who will go to great lengths to address it by adding different chemicals. However, its fine structure and effects on the mechanical properties are not fully understood. This i…

Mechanical Behavior of CompositesTextile materials and evaluationsCollagen: Extraction and Characterization

Cetyl trimethylammonium bromide as corrosion inhibitor for mild steel in acidic medium

Mukta Sharma、Jyoti Chawla、Gurmeet Singh2009-07-01Indian Journal of Chemical Technology

The inhibitive effect of cetyl trimethylammonium bromide (CTAB) on acid corrosion of mild steel in sulphuric acid at different temperatures has been investigated. Galvanostatic and potentiostatic studies were performed to determine the corrosion current, inhibition efficiency, passivation current and passivation poten…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

External search coil as a means of measuring rotor speed of an induction motor

Hayri Ertan、Ozan Keysan2009-07-01OpenAlex

The study in this paper investigates whether the air gap harmonics can be identified by using an external search coil placed on the frame of an induction motor. For this purpose the study focuses on the prediction of rotor speed of an induction motor from external search coil emf, using spectral analysis techniques. I…

Electric Motor Design and AnalysisMagnetic Properties and ApplicationsNon-Destructive Testing Techniques

Suppression of packet-like space charge formation in LDPE by the addition of magnesia nanofillers

Yoshimichi Ohki、Kazuyuki Ishimoto、Etsu Kanegae 等 7 位作者2009-07-01OpenAlex

Space charge distributions were investigated in two-layer dielectric films consisting of certain combinations of low-density polyethylene (LDPE) and its nanocomposite with magnesia nanofillers at DC electric fields of 25 kV/mm and 100 kV/mm at room temperature. Space charge is formed at the interface of two different…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationDielectric materials and actuators

Atomistic simulation of He bubble in Fe as obstacle to dislocation

Seyed Masood Hafez Haghighat、G. Lucas、R. Schäublin2009-07-01IOP Conference Series Materials Science and Engineering

Degradation of mechanical properties due to nanometric irradiation induced defects is one of the challenging issues in designing materials for future fusion reactors. Various types of defects such as voids and He bubbles may be produced due to high dose of neutron irradiation due to fusion reaction. We study the influ…

Microstructure and mechanical propertiesFusion materials and technologiesNuclear Materials and Properties

Kondo universality, energy scales, and intermediate valence in plutonium

E. S. Clementyev、A. Mirmelstein2009-07-01Journal of Experimental and Theoretical Physics

On the basis of the concepts of an intermediate-valence (IV) regime, an analysis is carried out of macroscopic properties of the α and δ phases of plutonium, as well as of several model systems based on rare earth elements. Within a single-site approximation (SSA), the characteristic Kondo interaction energy, the f-el…

Rare-earth and actinide compoundsNuclear Materials and PropertiesThermodynamic and Structural Properties of Metals and Alloys