Materials Literature
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Thirty one layer TiO2/SiO2 optical filters with graded refractive index profiles were fabricated by helicon plasma sputtering at room temperature. Multilayer films were deposited on glass (BK7) and Si (100) substrates simultaneously and sequentially. The measured transmittance spectrum exhibited a reflectance of 99.8%…
We report the molecular beam epitaxy (MBE) growth of the manganese(II) phthalocyanine thin films with unique crystal structure and the measurement of their magnetic properties. The epitaxial films were grown on hydrogen-terminated Si(111) substrates. Reflection high energy electron diffraction observations showed that…
Electrothermal poling of soft glasses (soda lime and borosilicate glass) at relatively high currents led to the creation of a second-order optical nonlinearity. The second-harmonic generation efficiency decays in time, and the decay rate can be accelerated by exposure to intense infrared radiation.
Characteristic features in photocurrent (PC) and electron paramagnetic resonance (EPR) spectra are discussed and attributed to main defects in the gap of optical-quality chemical vapor deposited diamond. A shoulder in the PC spectra with an onset at about 2.2 eV is attributed to the single-substitutional nitrogen defe…
Author: Gratz, R. et al.; Genre: Journal Article; Finally published : 1998; Title: Monazite xenotime thermometry. III. Experimental calibration of the partitioning of Gadolinium between monazite and xenotime
The elastic strain field of a dislocation is highly affected by nearby dislocations. The effects of dislocation-dislocation interactions on elastic energy and core structure are analyzed using a new and self-consistent method to apply periodic boundary conditions on unit cells containing dislocations. Local density fu…
A system is glassy when the observation time is much smaller than the equilibration time. A unifying thermodynamic picture of the glassy state is presented. Slow configurational modes are in quasiequilibrium at an effective temperature. It enters thermodynamic relations with the configurational entropy as a conjugate…
We present results on the normal-collective current conversion processes and associated deformation profile for a charge density wave in the sliding state. High resolution x-ray measurements of the satellite positional shift have been performed on ${\mathrm{NbSe}}_{3}$ at 90 K. The shift $q$ has been determined in the…
A study of the liquid crystalline phase transitions in a system of hard-sphere chains is presented. The chains comprise m=7 tangentially bonded hard-sphere segments in a linear conformation (LHSC). The isothermal–isobaric Monte Carlo simulation technique is used to obtain the equation of state of the system both by co…
In the static field limit, the vibrational hyperpolarizability consists of two contributions due to: (1) the shift in the equilibrium geometry (known as nuclear relaxation), and (2) the change in the shape of the potential energy surface (known as curvature). Simple finite field methods have previously been developed…
Drastic enhancements of the interdiffusion were observed in Cu-Ni diffusion couples when samples were heated under high hydrogen pressures $(\ensuremath{\sim}5\mathrm{GPa})$. Interdiffusion coefficients measured between $600--800\ifmmode^\circ\else\textdegree\fi{}\mathrm{C}$ were increased by $\ensuremath{\sim}{10}^{4…
We report on a study of phonons in diamond using a new instrument for high resolution inelastic x-ray scattering at the Advanced Photon Source. We have paid particular attention to possible overbending of the most energetic branches, i.e., LO along both $\ensuremath{\Gamma}\ensuremath{-}X$ ( $\ensuremath{\equiv}\ensur…
Asymmetric polarization switching of Pb(Zr,Ti)O3 (PZT) thin films with different electrode configuration has been studied in (La,Sr)CoO3/Pb(Zr,Ti)O3/(La,Sr)CoO3 (LSCO) heterostructures in which the conducting oxide (La,Sr)CoO3 and/or LaCoO3 (LCO) have been used as an electrode. Polarization-voltage (P-V) hysteresis lo…
Compact expressions, complete through second order in electrical and/or mechanical anharmonicity, are given for the dynamic dipole vibrational polarizability and dynamic first and second vibrational hyperpolarizabilities. Certain contributions not previously formulated are now included.
Zero-order metal diffraction gratings may give remarkably strong absorption of radiation. This absorption is due to the excitation of standing wave coupled surface plasmons in the narrow grating grooves. Theoretical modeling shows that a family of resonances exists, as the grating grooves are deepened, corresponding t…
Fluorinated amorphous carbon (a-CFx) films were studied by high-resolution x-ray absorption, emission, and photoelectron spectroscopy. The composition and local bonding information were obtained and correlated with substrate temperature during deposition. The data suggest that the structure of the a-CFx is mostly of c…
Spectroscopic ellipsometry (SE) has been used to determine the complex pseudo dielectric functions, ε1(E)+iε2(E), of ZnO films on (0001) Al2O3 substrates over the spectral range of 1.33 and 4.96 eV at room temperature. The SE measurements are carried out with E⊥c at angles of incidence of 60° and 65° with respect to t…
We study hysteresis for a two-dimensional, spin-1/2, nearest-neighbor, kinetic Ising ferromagnet in an oscillating field, using Monte Carlo simulations. The period-averaged magnetization is the order parameter for a proposed dynamic phase transition (DPT). To quantify the nature of this transition, we present the firs…
We report intercalation of charged polyiodide chains into the interstitial channels in a single-wall carbon nanotube (SWNT) rope lattice, suggesting a new carbon chemistry for nanotubes, distinctly different from that of graphite and ${\mathrm{C}}_{60}$. This structural model is supported by results from Raman spectro…
Rope-like bundles of single-walled carbon nanotubes (SWNTs) similar to those obtained by laser vaporization and electric-arc techniques were synthesized on a relatively large scale and at low cost by the catalytic decomposition of hydrocarbons at a temperature of about 1200 °C using an improved floating catalyst metho…