Materials Literature
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Multiple photosynthetic reaction centers have successfully been constructed using a supramolecular complex of zinc porphyrin dendrimer [D(ZnP) 16 ] with pyridylnaphthalenediimide (PyNIm) in benzonitrile. The apparent formation constant determined from the fluorescence quenching of the singlet excited state of porphyri…
Hybrid nanocomposites were successfully prepared by the incorporation of polyethersulfone (PES) and organoclay into epoxy resin. They had higher fracture toughness than the prepared PES/epoxy blend and organoclay/epoxy nanocomposites. The microstructures of the hybrid nanocomposites were studied. They were comprised o…
The database system for thermophysical property data, which has been developed by the National Metrology Institute of Japan (NMIJ), is evolved to store comprehensive information on thin films. Since a thin film is identified by not only its constituent elements, phases, or compositions but also its method of synthesis…
The temperature dependence of the charge transport in TiO2 films was investigated to establish the correlation between the Nb content and electrical properties. It was identified that temperature-dependent conductivity of the films is dominated by a phonon-assisted small polaron hopping model in the non-adiabatic regi…
The present study is deals with the influence of nanoparticles on the growth of heterocyst-forming cyanobacterium Anabaena ambigua Rao [A100]. The nano molybdenum and iron particles have been synthesized respectively from molybdenum trioxide (MoO3) and iron chloride (FeCl3) employing sodium borohydride (NaBH4) as a re…
It is demonstrated that the diameter distribution of catalyst nanoparticles in arc discharge can be controlled by a magnetic field. The magnetic field affects the arc shape, shortens the diffusing time of the catalyst nanoparticles through the nucleation zone, and consequentially reduces the average diameters of nanop…
Abstract The effect of temperature and moisture on mechanical behavior of flax fiber/starch based composites was investigated experimentally. Elastic modulus, the nonlinear tensile loading curves, and failure strain were analyzed. Neat matrix and composites with 20 and 40% weight content of fibers were tested. It was…
An electrospun polysulfone (PSU) was prepared as a barrier membrane for guided bone regeneration. The membrane was in nanoscale to prevent fibrous tissue infiltration and highly porous to allow permeation of oxygen and nutrients. The morphology and attachment, viability and proliferation, and differentiation and miner…
Abstract The effect of organoclay on phase morphology development of PA6/SEBS alloys had been investigated. PA6/SEBS blends of various compositions, with and without the presence of exfoliated organoclay in the PA6 phase, were prepared and the morphology and thermal expansion of these blends were examined. The results…
Blends of natural rubber (NR) containing 10—30 phr mechanically disintegrated cellulose fibres — in form of processed scrap paper (CP) or cotton mat (CB) — were transformed into vulcanizates. The obtained elastomers were examined for mechanical and thermomechanical properties under dynamic conditions (DMTA), abrasion…
Poly(o-methoxyaniline)/Pt-M (POMA/Pt-M, M=Ru, Au, Pd) composite catalysts have been successfully fabricated by a two-step electrodeposition and used for the methanol electrooxidation. As-prepared composite catalysts are characterized by SEM and electrochemical analysis. The results of the catalytic activity for the me…
Bulk isotropic and anisotropic Nd-Fe-B magnets were synthesized by hot pressing and subsequent hot deforming melt-spun ribbons with addition of Ce using spark plasma sintering (SPS). It was found that Ce addition had a prominent effect on the bulk magnets by changing the structures of the matrix and boundary phase. Wi…
In this paper, the effect of weaving machine settings on weavability limits of air-jet looms was investigated by weaving plain weave fabrics with polyester warp and weft yarns. For this purpose, firstly, weavability limits were determined for 16.7 tex weft by setting back-rest height, total warp tension, frontshed ang…
The induced modifications of the optical properties in UV-irradiated Makrofol-E with different wavelengths were investigated. Makrofol-E samples were irradiated by UV of wavelengths 254, 302, and 365 nm for different durations. It was found that Makrofol-E shows substantial modifications in its optical characteristics…
This review presents the synthetic aspects and photophysical properties of trimeric systems constructed with a first unit consisting of a cofacial porphyrin and then of another porphyrin attached as a side arm. Two scenarios are dealt with. The first one is the case where the three chromophores are different, called d…
Abstract CaS formed during the retorting process of oil shale has a hazardous influence on surface water quality. Interaction of retorted oil shale with water generates highly alkaline leachate with a high content of sulfur due to the CaS component. A theoretical model describing the behavior of solid calcium sulfide…
A next generation ion source suitable for both high resolution focused ion beam milling and imaging applications is currently being developed. The new ion source relies on a method of which positively charged ions are extracted from a miniaturized gas chamber where neutral gas atoms become ionized by direct electron i…
Previously unreported octaisopropyltetraphenylporphyrin (OiPTPP) was prepared from 3,4-diisopropylpyrrole, an unstable previously unisolated heterocyclic compound. Purification of the free-base 18π porphyrin required conversion to its 18π zinc(II) complex, chromatographic separation, and acid mediated demetalation. Ox…
The stacking structure of tubular halloysite, which is easily damaged by electron-beam radiation, has been investigated by high-resolution transmission electron microscopy (HRTEM) using a new TEM with a computer-assisted minimal-dose system. The new TEM is equipped with a high-speed beam blanker by which the specimen…
In the present paper, we study the effects of functionalization of graphene with simple organic molecules OH, and NH 2 , focusing on the stability and band gaps of the structures. We have performed DFT calculations for graphene supercells with various numbers of the attached molecules. We have determined adsorption en…