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Mechanisms of Single-Walled Carbon Nanotube Nucleation, Growth, and Healing Determined Using QM/MD Methods

Alister J. Page、Yasuhito Ohta、Stephan Irle 等 4 位作者2010-07-27Accounts of Chemical Research

Since their discovery in the early 1990s, single-walled carbon nanotubes (SWNTs) have spawned previously unimaginable commercial and industrial technologies. Their versatility stems from their unique electronic, physical/chemical, and mechanical properties, which set them apart from traditional materials. Many researc…

Fullerene Chemistry and ApplicationsGraphene research and applicationsCarbon Nanotubes in Composites

Difference of the Crystal Structure of Cellulose in Wood after Hydrothermal and Aging Degradation: A NIR Spectroscopy and XRD Study

Tetsuya Inagaki、Heinz W. Siesler、Katsuya Mitsui 等 4 位作者2010-07-27Biomacromolecules

The change of crystalline structure in hydrothermally treated hinoki wood was investigated by means of Fourier-transform near-infrared spectroscopy in combination with a deuterium exchange method and X-ray diffraction. The results were compared with analogous data of dry-exposed archeological wood taken from an old wo…

Advanced Cellulose Research StudiesLignin and Wood ChemistryWood Treatment and Properties

Anisotropy and boundary scattering in the lattice thermal conductivity of silicon nanomembranes

Zlatan Akšamija、I. Knežević2010-07-27Physical Review B

We present a calculation of the full thermal conductivity tensor for (001), (111), and (011) surface orientations of the silicon-on-insulator (SOI) nanomembrane, based on solving the Boltzmann transport equation in the relaxation-time approximation with the full phonon dispersions, a momentum-dependent model for bound…

Thermal Radiation and Cooling TechnologiesAdvanced Thermoelectric Materials and DevicesThermal properties of materials

Terahertz Kerr and Reflectivity Measurements on the Topological Insulator Bi2Se3

G. S. Jenkins、A. B. Sushkov、D. C. Schmadel 等 7 位作者2010-07-27arXiv

We report the first terahertz Kerr measurements on bulk crystals of the topological insulator Bi2Se3. At T=10K and fields up to 8T, the real and imaginary Kerr angle and reflectance measurements utilizing both linearly and circularly polarized incident radiation were measured at a frequency of 5.24meV. A single fluid…

Strongly Correlated ElectronsMaterials Science

The search for strong topological insulators

M. Klintenberg2010-07-27arXiv

Topological insulators [1-6] is a new quantum phase of matter with exotic properties such as dissipationless transport and protection against Anderson localization [7]. These new states of quantum matter could be one of the missing links for the realization of quantum computing [8,9] and will probably result in new sp…

Materials Science

Highly Active Magnesium Initiators for Ring-Opening Polymerization of rac-Lactide

Liying Wang、Haiyan Ma2010-07-27Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTHighly Active Magnesium Initiators for Ring-Opening Polymerization of rac-LactideLiying Wang and Haiyan Ma*View Author Information Laboratory of Organometallic Chemistry, East China University of Science and Technology, 130 Meilong…

biodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Effect of Moisture on Electrospun Nanofiber Composites of Poly(vinyl alcohol) and Cellulose Nanocrystals

María Soledad Peresin、Youssef Habibi、Arja‐Helena Vesterinen 等 6 位作者2010-07-27Biomacromolecules

The effect of humidity on the morphological and thermomechanical properties of electrospun poly(vinyl alcohol) (PVA) fiber mats reinforced with cellulose nanocrystals (CNs) was investigated. Scanning electron microscopy (SEM) images revealed that the incorporation of CNs improved the morphological stability of the com…

Advanced Cellulose Research StudiesElectrospun Nanofibers in Biomedical ApplicationsAdvanced Sensor and Energy Harvesting Materials

Brittle–ductile transitions in polycrystalline tungsten

A. Giannattasio、Zhongwen Yao、Edmund Tarleton 等 4 位作者2010-07-27The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

The strain rate dependence of the brittle-to-ductile transition (BDT) temperature was investigated in notched and un-notched miniature bars made of high-purity polycrystalline tungsten and in notched bars of less-pure sintered material. The activation energy, E BDT, for the process controlling the BDT in pure tungsten…

High-Velocity Impact and Material BehaviorMicrostructure and mechanical propertiesFusion materials and technologies

Non-spherical bubble dynamics in a compressible liquid. Part 1. Travelling acoustic wave

Qianxi Wang、J. R. Blake2010-07-27Journal of Fluid Mechanics

Micro-cavitation bubbles generated by ultrasound have wide and important applications in medical ultrasonics and sonochemistry. An approximate theory is developed for nonlinear and non-spherical bubbles in a compressible liquid by using the method of matched asymptotic expansions. The perturbation is performed to the…

Ultrasound and Hyperthermia ApplicationsUltrasound and Cavitation Phenomena

New Insight on Initiation of Cavitation in Semicrystalline Polymers: In-Situ SAXS Measurements

Séverine Humbert、Olivier Lame、Jean‐Marc Chenal 等 5 位作者2010-07-27Macromolecules

The phenomenon of cavitation generally appears close to yielding in the high-density polyethylene. It can affect the yield stress and the properties at large strains. The influence of the microstructural and molecular parameters on cavitation is not well established; it is not even clear whether the cavitation is a ca…

Mechanical Behavior of CompositesPolymer crystallization and propertiesCorrosion Behavior and Inhibition

White Light Emission from NaCaPO 4 :Dy 3+ Phosphor for Ultraviolet‐Based White Light‐Emitting Diodes

B.V. Ratnam、M. Jayasimhadri、Kiwan Jang 等 6 位作者2010-07-27Journal of the American Ceramic Society

Trivalent dysprosium (Dy 3+ )‐doped NaCaPO 4 phosphors were synthesized by using a conventional solid‐state reaction technique. The phase and the structure of the as‐prepared powders were characterized by using X‐ray diffraction analysis and revealed that the pure NaCaPO 4 formed with orthorhombic structure. The photo…

Radiation Detection and Scintillator TechnologiesLuminescence Properties of Advanced MaterialsAdvanced Photocatalysis Techniques

Structure of Dealloyed PtCu3 Thin Films and Catalytic Activity for Oxygen Reduction

Ruizhi Yang、Jennifer Leisch、Peter Strasser 等 4 位作者2010-07-27Chemistry of Materials

The detailed structure and composition (surface and bulk) as well as catalytic activity for oxygen reduction of electrochemically dealloyed PtCu 3 thin films have been investigated. Synchrotron-based anomalous X-ray diffraction (AXRD) reveals that a Pt enriched surface region (∼1.0 nm thick) and a Cu depleted interior…

Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationNanoporous metals and alloys

The Morphology of Poly(3,4-Ethylenedioxythiophene)

David C. Martin、Jinghang Wu、Charles M. Shaw 等 8 位作者2010-07-27Journal of macromolecular science. Part C, Reviews in macromolecular chemistry and physics/Journal of macromolecular science. Reviews in macromolecular chemistry and physics

Poly(3,4-ethylene dioxythiophene) (PEDOT) is a chemically stable, conjugated polymer that is of considerable interest for a variety of applications including coatings for interfacing electronic biomedical devices with living tissue. Here, we describe recent work from our laboratory and elsewhere to investigate the mor…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAdvanced Sensor and Energy Harvesting Materials

Supramolecular Control of Stiffness and Strength in Lightweight High‐Performance Nacre‐Mimetic Paper with Fire‐Shielding Properties

Andreas Walther、Ingela Bjurhager、Jani‐Markus Malho 等 6 位作者2010-07-27Angewandte Chemie International Edition

Taking the heat: Hard/soft core/shell colloidal building blocks allow large-scale self-assembly to form nacre-mimetic paper. The strength and stiffness of this material can be tailored by supramolecular ionic bonds. These lightweight biomimetic materials show excellent and tunable mechanical properties and heat and fi…

Bone Tissue Engineering MaterialsCalcium Carbonate Crystallization and InhibitionPaleontology and Stratigraphy of Fossils

Layer-by-Layer Doping of Few-Layer Graphene Film

Fethullah Güneş、Hyeon‐Jin Shin、Chandan Biswas 等 8 位作者2010-07-27OpenAlex

We propose a new method of layer-by-layer (LbL) doping of thin graphene films. Large area monolayer graphene was synthesized on Cu foil by using the chemical vapor deposition method. Each layer was transferred on a polyethylene terephthalate substrate followed by a salt-solution casting, where the whole process was re…

ZnO doping and propertiesGraphene research and applicationsPlasmonic and Surface Plasmon Research

Resonant Scattering by Realistic Impurities in Graphene

Tim O. Wehling、Shengjun Yuan、A. I. Lichtenstein 等 5 位作者2010-07-27arXiv

We develop a first-principles theory of resonant impurities in graphene and show that a broad range of typical realistic impurities leads to the characteristic sublinear dependence of the conductivity on the carrier concentration. By means of density functional calculations various organic groups as well as adatoms su…

Carbon Nanotubes in CompositesSurface and Thin Film PhenomenaGraphene research and applications

Light Concentration at the Nanometer Scale

Ramón A. Álvarez‐Puebla、Luis M. Liz‐Marzán、F. Javier Garcı́a de Abajo2010-07-27OpenAlex

Visible and near-infrared optical excitations are common currency in the biological world, and consequently, they are routinely used to investigate microscopic phenomena taking place in living organisms and their environment. However, the wavelength of light within that energy region is above hundreds of nanometers, t…

Spectroscopy Techniques in Biomedical and Chemical ResearchGold and Silver Nanoparticles Synthesis and ApplicationsNonlinear Optical Materials Studies

Formation of a crystal nucleus from liquid

Takeshi Kawasaki、Hajime Tanaka2010-07-27OpenAlex

Crystallization is one of the most fundamental nonequilibrium phenomena universal to a variety of materials. It has so far been assumed that a supercooled liquid is in a "homogeneous disordered state" before crystallization. Contrary to this common belief, we reveal that a supercooled colloidal liquid is actually not…

nanoparticles nucleation surface interactionsTheoretical and Computational PhysicsMaterial Dynamics and Properties

Seed-Mediated Synthesis of Ag Nanocubes with Controllable Edge Lengths in the Range of 30−200 nm and Comparison of Their Optical Properties

Qiang Zhang、Weiyang Li、Christine H. Moran 等 7 位作者2010-07-27OpenAlex

Silver nanocubes with edge lengths controllable in the range of 30-200 nm were synthesized using an approach based on seeded growth. The keys to the success of this synthesis are the use of single-crystal Ag seeds to direct the growth and the use of AgNO(3) as a precursor to elemental Ag, where the byproduct HNO(3) ca…

Quantum Dots Synthesis And PropertiesCopper-based nanomaterials and applicationsGold and Silver Nanoparticles Synthesis and Applications

Silver Coordination Polymers for Prevention of Implant Infection: Thiol Interaction, Impact on Respiratory Chain Enzymes, and Hydroxyl Radical Induction

Oliver Gordon、Tünde Vig Slenters、Priscilla S. Brunetto 等 8 位作者2010-07-27OpenAlex

Prosthetic joint replacements are used increasingly to alleviate pain and improve mobility of the progressively older and more obese population. Implant infection occurs in about 5% of patients and entails significant morbidity and high social costs. It is most often caused by staphylococci, which are introduced perio…

Trace Elements in HealthNanoparticles: synthesis and applicationsOrthopaedic implants and arthroplasty