Materials Literature
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Previous work has shown that polymethacrylates with highly tapered side groups, such as poly{2-{2-[2-(2-methacryloyloxyethoxy)-ethoxy]ethoxy}ethyl-3,4,5-tris-(p-dodecyloxy-benzyloxy)benzoate} (H12-ABG-4EO-PMA), form columnar hexagonal (Colh, previously designated φh) liquid crystalline structures. The small angle X-ra…
Sodium 4-nitrophenolate 4-nitrophenol dihydrate is a new nonlinear optical crystal of C2 monoclinic symmetry composed of two distinct organic chromophores of respective calculated molecular hyperpolarisabilities β xxx =18.2×10 –30 and 5.2×10 –30 esu. The chromophores are organised in herringbone motifs along inorganic…
The DC and AC conductivity of composites with epoxy resin and nickel particles was investigated for various content of nickel powder from ambient to 120 °C. AC conductivity was measured in the frequency range 10 Hz to 13 MHz. An enhancement of conductivity was evidenced increasing conductive filler content and tempera…
System design of cold weather protective clothing is a critical process, as it involvesconsideration of the effects of a number of external and internal parameters like environmental factors and physical, physico-mechanical and psychological parameters. The bulk and weightof the textile materials used in protective cl…
The effect of oxide shape on magnetic properties of semiprocessed nonoriented electrical steel sheets produced by single reduction cold rolling process was studied. When oxides in steel sheets were elongated inclusions which were prescribed as B type by JIS, the oxides inhibited grain growth during consumer annealing…
Acid-mediated cleavage and rearrangement of (c-C6H11)6Si6O9 1 by triflic acid (TfOH) and methanesulfonic acid (MsOH) produces good yields of C2-[(c-C6H11)6Si6O8X2] (4a, X = OTf; 4b, X = MsO), which reacts with water, LiNMe2 and LiCCPh to afford C2-[(c-C6H11)6Si6O8(OH)2] 5, C2-[(c-C6H11)6Si6O8(NMe2)2] 8 and C2-[(c-C6H1…
Ultrathin fluoropolymer films were deposited by a plasma-enhanced chemical vapor deposition process, from mixtures of hexafluoropropylene (C3F6) and octafluoropropane (C3F8) precursors. Different monomer feed compositions result in different rates of deposition. The C3F6 is the primary polymerizing species and C3F8 ac…
Shear bands (SBs) in cold-rolled austenitic stainless steel 310S have been investigated by using transmission electron microscopy (TEM). Shear Bands appear in the region of twin-matrix lamellae which have already developed at moderate strain. Inside the shear band, fine grains are observed, and the shape of each grain…
Structural investigations of the compounds in the series Ba 0.27 Sr 0.73 Zr y Ti 1- y O 3 have been carried out. The crystal structure goes to lower symmetry with increasing Zr content and the tolerance factor decreases. The variation of V a / V b is linear with the tolerance factor. The tilt system is a - a - c 0 for…
The results of an investigation of the electronic structure of lithium tetraborate crystals using experimental (x-ray photoelectron spectroscopy) and theoretical (quantum-chemical modeling) methods are reported. The experimental spectrum of the valence-band states of the crystal lies 2–15 eV below the Fermi level and…
To predict phase selection in a ternary eutectic system, approximate growth models of eutectic cells are proposed. Two models are proposed. The first assumes that the growth adjustment should be governed by elimination and branching of the two solid phases and assumes the extreme condition and uses the Burden-Hunt mod…
The objective of this research is to experimentally characterize the spatial distribution of an additive across the thickness of a single-layer polymer film. Concentration-distribution data are then used to quantify the amount of additive that diffuses from the bulk of the film to the film surfaces as a function of ti…
The dinucleating phenolate-hinged ligand 4-tert-butyl-2,6-bis[bis(2-pyridylmethyl)aminomethyl]phenolate (bpbp–) has been used to prepare a series of FeIIIMII complexes containing independent species at the exogenous binding sites. These sites are occupied by fluoride and water ligands and show the general formulation…
Collagen, as a fibrous protein constituting approximately one third of the total protein in the body is synthesized by fibroblasts and is a major component of extracellular matrix in many tissues such as vessels, heart, kidney, liver, skin, tendons, bone and cartilage. The collagen molecule consists of three polypepti…
A cylindrical coordinate separation-of-variables solution is developed for the determination of the internal and the near-surface electromagnetic fields for the arrangement of a focused beam incident upon a homogeneous infinite circular cylinder. The angle of incidence and the focal point location of the beam, as well…
This paper reports initial results in the application of shape memory polymer (SMP) technology to the active disassembly of electronic products. The smart material SMP of polyurethane (PU) composition was employed. Created for these experiments were novel SMP releasable fasteners, with which it is possible to effectiv…
Reaction of an alkene with aqueous hydrogen peroxide and a catalytic quantity of a heteropolyacid adsorbed onto magnesium, aluminium or zinc oxide leads to complete, rapid cleavage of the alkene to give carbonyl compounds.
This paper presents the science and technology developments in the field of high performance aromatic polyimides and their composites in relation to space applications as follows; 1) Development of polyimides as an high performance materials 2) High perfonnance polyimide film like materials for spacecraft applications…
Rotational molding is one of the most important methods for the manufacture of hollow plastic products. However, there are several unsolved problems that confound the overall success of this technique. Part warpage caused by inappropriate mold design and processing conditions is one of them. An experimental study is r…
A new approach for calculating the temperature coefficients of magnetic parameters is proposed in order to more accurately describe high temperature characteristics of magnetic materials. Using this new approach, the "true" (or instantaneous) temperature coefficient of any magnetic parameter at a specific temperature…