Materials Literature
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Abstract Over‐oxidation of poly(pyrrole) films has been shown to result in permselective films favoring cation transport and excluding anions. The exclusion principal depends on both the size of the analyte and electrostatic interactions between the analyte and the polymer film. The size of the polymer dopant anion an…
Persistent spectral hole burning in the $f\ensuremath{\rightarrow}f$ transition and changes in the $f\ensuremath{\rightarrow}d$ transition spectra upon laser irradiation were investigated in ${\mathrm{Sm}}^{2+}$-doped ${\mathrm{Al}}_{2}{\mathrm{O}}_{3}{\ensuremath{-}\mathrm{S}\mathrm{i}\mathrm{O}}_{2}$ glasses prepare…
The effect of Nd content in Al films on hillock formation was investigated for applications of interconnections for thin film transistor liquid crystal displays. It was found that the hillock density of Al–Nd alloy films was strongly dependent on the Nd content, and the hillocks were completely suppressed in Al–2.0–6.…
Static and dynamic low-angle light-scattering experiments carried out on semidilute and moderately concentrated solutions of polystyrene in toluene provide evidence for the existence of heterogeneities in the entanglement network with correlation lengths of several hundred nanometers. The slow mode showing up in the c…
Recent results on the composition, structural characterization and mechanical properties of amorphous hydrogenated carbon-nitrogen films (a-C(N):H) deposited by plasma enhanced chemical vapor deposition (PECVD) have been discussed. The use of different nitrogen-containing gases, ammonia, methylamine or nitrogen itself…
In this study two solubility-parameter models have been compared using as dependent variables the logarithm of the mole fraction solubility, lnX2e, and ln(alpha)/U (originally used in the extended Hansen method), where alpha is the activity coefficient and U is a function of the molar volume of the solute and the volu…
Luminescence studies have been performed on phosphorous-doped diamond films deposited by hot-filament chemical vapor deposition. A broad luminescence band, centered around 1.9 eV is revealed, in the cathodo luminescence spectra of homoepitaxial and polycrystalline films, whereas the blue band-A luminescence, which is…
The low-temperature specific heat ${C}_{p}$ of vitreous B${}_{2}$O${}_{3}$ has been measured between 1.5 K and 25 K, for several B${}_{2}$O${}_{3}$ glasses with different thermal histories and water contents. A noticeable variation of the specific heat from glass to glass is found in the temperature range around the b…
The monopersulfate oxidation of 4-isopropylbenzoic acid performed in H(2)(18)O and catalyzed by a water-soluble metalloporphyrin indicated that half of the oxygen atoms incorporated in 4-(1-hydroxy-1-methylethyl)benzoic acid, the primary hydroxylation product, came from water. A redox tautomerism of the active high-va…
Pt/(Ba, Sr)TiO 3 /Pt capacitors were fabricated on TiN/Ti/ Poly –Si/SiO 2 /Si substrate by sputtering technique and effects of post-annealing conditions on the current vs. voltage ( I–V ) characteristics of the capacitors were investigated. It was found that leakage currents of Pt/BST/Pt capacitors were greatly depend…
The effects of concentration and modification of fibre surface in oil palm fibre-reinforced rubber composites have been studied. Modification of the fibre surface increased the physical properties of the rubber composites. Increasing concentration of oil palm fibre in the rubber matrix resulted in reduction of tensile…
Six different behavioral models for ferroelectric capacitors are surveyed with an emphasis on their usefulness in the transient circuit simulation of integrated nonvolatile memories. These models can be broadly classified into two categories, namely, those that rely on the hysteresis loop and those that rely on the sw…
Oxynitride films with continuous variations of the optical index with thickness were grown by electron cyclotron resonance plasma-enhanced chemical vapor deposition using silane as a silicon precursor and oxygen and nitrogen as plasma gases. Specific linear and parabolic index profiles were fabricated by computerized-…
A detailed surface chemistry model is presented for the reactions of N 2, O2, NO, N, and O on a silica surface. The model distinguishes adsorption, desorption, and recombination reactions according to the Eley‐ Rideal and Langmuir ‐ Hinshelwood mechanisms as well as dissociative adsorption reactions of the molecular s…
Abstract One of the challenges in building reaction mechanisms using algorithms for automated model construction is to describe the essential chemistry and enable prediction of experimental data over wide ranges of reaction conditions while maintaining a manageable model size. Two complementary methodologies for build…
Birefringence can be induced in Se films photocrystallized by linearly polarized light at \ensuremath{\sim}350 K. The birefringence reaches \ensuremath{\sim}0.1, which is approximately 1/10 of that in the hexagonal Se. X-ray-diffraction investigations suggest that the photothermally induced birefringence is caused by…
Multilayered composites consisting of LaPO 4 (La‐monazite) layers alternating with various ZrO 2 ‐based materials were fabricated to investigate whether LaPO 4 provides a weakly bonded interface suitable for promoting toughening, as previously observed in the system LaPO 4 /Al 2 O 3 . The following ZrO 2 ‐based materi…
A new heterotrinuclear complex of formula [Cu(2)Zn(Hdmg)(2)(dmg)(2)(H(2)O)].0.5H(2)dmg.H(2)O (C(18)H(34)Cu(2)N(9)O(11)Zn, 1) (H(2)dmg = dimethylglyoxime) has been synthesized and its crystal structure determined by single-crystal X-ray diffraction. It crystallizes in the triclinic system, space group P&onemacr;, with…
The oxidation and reduction behavior of complexes [(mpz)M(CN) 5 ] 2 - between the group 8 pentacyanometalates(II) and the N -methylpyrazinium ion mpz + was studied using spectroelectrochemical techniques (UV/vis/NIR, IR, EPR) in nonaqueous and, in part, aqueous media. As a further source of information on the electron…
We describe a relatively simple, reliable, and fast approach for quantitative surface analyses by x-ray photoelectron spectroscopy (XPS) and Auger electron spectroscopy (AES) that significantly improves the accuracy of analyses of polycrystalline solids. The common formalism of XPS and AES is based on the assumption,…