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Photophysical Properties of TlGaS2 Layered Single Crystals

I.M. Ashraf2004-07-01The Journal of Physical Chemistry B

The photoconductivity (PC) of TlGaS 2 layered single crystals was investigated in the 77−300 K temperature, 1000−2500 lx excitation intensity, 10−25 V applied voltage, and 415−535 nm wavelength ranges. Both the alternating current photoconductivity (ac-PC) and the spectral distribution of the photocurrent were studied…

Crystal Structures and PropertiesNonlinear Optical Materials ResearchSolid-state spectroscopy and crystallography

Photoemission study of the translational energy induced oxidation processes on Cu(111)

Kousuke Moritani、Michio Okada、Seiichi Sato 等 7 位作者2004-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

The oxidation processes of Cu(111) with a hyperthermal O2 molecular beam (HOMB) were studied using high-resolution x-ray photoemission spectroscopy in conjunction with a synchrotron radiation source. The O-uptake curves were precisely measured at ∼300 K when irradiating with 2.3 and 0.6 eV HOMB on a Cu(111) surface. A…

Catalytic Processes in Materials ScienceCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Simplified Versus Detailed Solid Oxide Fuel Cell Reactor Models and Influence on the Simulation of the Design Point Performance of Hybrid Systems

Loredana Magistri、R. Bozzo、Paola Costamagna 等 4 位作者2004-07-01Journal of Engineering for Gas Turbines and Power

High-efficiency hybrid systems (HS) based on the coupling of solid oxide fuel cells (SOFCs) and gas turbines (GT) are analyzed in this paper through the use of two different approaches: simplified and detailed SOFC models. The simplified model, already presented by the authors, is very useful for HS design and off-des…

Advancements in Solid Oxide Fuel CellsChemical Looping and Thermochemical ProcessesCatalysis and Oxidation Reactions

Suitability of alternative fatty food simulants to study the effect of thermal and microwave heating on overall migration of plastic packaging

María José Galotto、Abél Guarda2004-07-01Packaging Technology and Science

Abstract The suitability of alternative fatty food simulants on overall migration determination under thermal treatment and microwave heating were analysed for different plastic materials commonly used for packs subjected to thermal treatment or microwave heating. Elevated temperature and microwave heating increased o…

Postharvest Quality and Shelf Life ManagementNanocomposite Films for Food PackagingFood Waste Reduction and Sustainability

Laser-etched silicon pillars and their porosification

David Mills、Kurt W. Kołasiński2004-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Mesoscale silicon pillars are formed when silicon wafers are irradiated by a nanosecond excimer laser operating at 308 nm and incident fluence of ∼3 J cm−2. The morphology of the pillars responds to the chemical composition of the gas phase above the Si surface. Postprocessing can also be used to change the structure…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Solid-solution hardening by point-like obstacles of different kinds

Masato Hiratani、Vasily V. Bulatov2004-07-01Philosophical Magazine Letters

The critical resolved shear stress (CRSS) for a dislocation percolating through penetrable obstacles with different pinning strength is derived analytically. The stability of dislocation–obstacle configurations is determined by evaluating the configurational entropy. The analytical results imply a superposition law fo…

Microstructure and mechanical propertiesMicrostructure and Mechanical Properties of SteelsFusion materials and technologies

SURFACE MODIFICATIONS AND ADHESION OF VULCANIZED SBR RUBBER TREATED WITH RF PLASMAS OF DIFFERENT GASES

Ana B. Ortíz‐Magán、M. Mercedes Pastor‐Blas、José Miguel Martín‐Martínez2004-07-01The Journal of Adhesion

The surface modifications produced by treatment of a synthetic vulcanized styrene-butadiene rubber (R1) with oxidizing (oxygen, air, carbon dioxide) and nonoxidizing (nitrogen, argon) RF plasmas have been assessed by ATR-IR and XPS spectroscopy, SEM, and contact angle measurements. The effectiveness of the treatment d…

Surface Modification and SuperhydrophobicityHigh voltage insulation and dielectric phenomenaSilicone and Siloxane Chemistry

Drug Delivery Systems Using Immobilized Intact Liposomes: A Comparative and Critical Review

Heïdi Brochu、Ange Polidori、Bernard Pucci 等 4 位作者2004-07-01Current Drug Delivery

Liposomes sustain considerable interest to develop ways to fabricate drug delivery systems that would provide a good release without inducing any systemic reactions into the host. However, in many cases, liposomes injected into the blood stream are rapidly cleared from the system and only a fraction reaches the target…

Nanoparticle-Based Drug DeliveryLipid Membrane Structure and BehaviorAdvanced Drug Delivery Systems

Subcritical Crack Growth in Lead Zirconate Titanate

William S. Oates、Christopher S. Lynch、Doru C. Lupascu 等 6 位作者2004-07-01Journal of the American Ceramic Society

Subcritical crack growth in terms of velocity–stress intensity factor ( v – K ) curves in lead zirconate titanate (PZT) were experimentally characterized on poled and unpoled compact tension specimens. The poled specimens were tested under open‐ and short‐circuit electrical boundary conditions, which resulted in an in…

Advanced ceramic materials synthesisRock Mechanics and ModelingNumerical methods in engineering

Preparation and Structural Characterization of RuS2 Nanoislands on Au(111)

Tanhong Cai、Zhen Song、José A. Rodríguez 等 4 位作者2004-07-01Journal of the American Chemical Society

Among all the transition metal sulfides, ruthenium sulfide (RuS2) has been shown to be the most active catalyst for the hydrodesulfuriztion processes. Using X-ray photoemission spectroscopy (XPS) and scanning tunneling microscopy (STM), we have found a novel approach for the preparation of RuS2 nanoislands on an Au(11…

Electrocatalysts for Energy ConversionCopper-based nanomaterials and applicationsSurface and Thin Film Phenomena

One-electron singular branch lines of the Hubbard chain

J. M. P. Carmelo、Karlo Penc、L. M. Martelo 等 8 位作者2004-07-01Europhysics Letters (EPL)

The momentum and energy dependence of the weight distribution in the vicinity of the one-electron spectral-function singular branch lines of the 1D Hubbard model is studied for all values of the electronic density and on-site repulsion U . To achieve this goal, we use the recently introduced pseudofermion dynamical th…

Physics of Superconductivity and MagnetismMagnetism in coordination complexesOrganic and Molecular Conductors Research

Highly transparent and conductive ZnO:Al thin films prepared by vacuum arc plasma evaporation

Toshihiro Miyata、Youhei Minamino、Satoshi Ida 等 4 位作者2004-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

A vacuum arc plasma evaporation (VAPE) method using both oxide fragments and gas sources as the source materials is demonstrated to be very effective for the preparation of multicomponent oxide thin films. Highly transparent and conductive Al-doped ZnO (AZO) thin films were prepared by the VAPE method using a ZnO frag…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

MONSTER: inferring non-covalent interactions in macromolecular structures from atomic coordinate data

William Salerno、S. M.D. Seaver、Brian Armstrong 等 4 位作者2004-07-01Nucleic Acids Research

A web application for inferring potentially stabilizing non-bonding interactions in macromolecular structures from input atomic coordinate data is described. The core software, called Monster, comprises a PERL wrapper that takes advantage of scripts developed in-house as well as established software in the public doma…

Protein Structure and DynamicsComputational Drug Discovery MethodsEnzyme Structure and Function

Recent Developments in Studies of Electronic Excited States by Means of Electron Paramagnetic Resonance Spectroscopy

Seigo Yamauchi2004-07-01Bulletin of the Chemical Society of Japan

Abstract New trends of electron paramagnetic resonance (EPR) are reviewed in studies of the electronic excited states conducted during this decade. The studies include EPR of excited triplet states in fluid solution and excited multiplet states in a triplet–radical pair system. Together with these new areas, advanced…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesElectron Spin Resonance Studies

Impact Response and Analysis of Several Silicon Carbides

M. J. Normandia2004-07-01International Journal of Applied Ceramic Technology

Several hot‐pressed and sintered SiC variants were impacted with tungsten‐carbide (WC) spheres at velocities up to 1700 m/s. Ballistic response curves of areal density penetrated as a function of impact velocity were generated to compare ceramics for ballistic applications. Observed response curve features are shown t…

Advanced ceramic materials synthesisHigh-pressure geophysics and materialsHigh-Velocity Impact and Material Behavior

α-Aminoadipate aminotransferase from an extremely thermophilic bacterium, Thermus thermophilus

Takashi Miyazaki、Junichi Miyazaki、Hisakazu Yamane 等 4 位作者2004-07-01Microbiology

The extremely thermophilic bacterium Thermus thermophilus HB27 synthesizes lysine through alpha-aminoadipate (AAA). In this study, a T. thermophilus gene encoding the enzyme that catalyses transamination of AAA was cloned as a mammalian kynurenine/AAA aminotransferase (Kat2) gene homologue. A T. thermophilus mutant wi…

Enzyme Structure and FunctionAmino Acid Enzymes and MetabolismBiochemical and Molecular Research

Aqueous Cholesteric Liquid Crystals Using Uncharged Rodlike Polypeptides

Enrico G. Bellomo、Patrick Davidson、Marianne Impéror‐Clerc 等 4 位作者2004-07-01Journal of the American Chemical Society

The aqueous, lyotropic liquid-crystalline phase behavior of the alpha-helical polypeptide, poly(N(epsilon)-2-[2-(2-methoxyethoxy)ethoxy]acetyl-lysine) (1), has been studied using optical microscopy and X-ray scattering. Solutions of optically pure 1 were found to form cholesteric liquid crystals at volume fractions th…

Liquid Crystal Research AdvancementsSupramolecular Self-Assembly in MaterialsAdvanced Materials and Mechanics

Investigation of Energy Transfer between CdTe Nanocrystals on Polystyrene Beads and Dye Molecules for FRET-SNOM Applications

Felix Müller、Stephan Götzinger、Nikolai Gaponik 等 6 位作者2004-07-01The Journal of Physical Chemistry B

We report results on the observation of energy transfer between CdTe nanocrystals and AlexaFluor dye molecules. The nanocrystals were attached to the surface of polystyrene latex beads of 450 nm in diameter by means of the layer-by-layer technique. Energy transfer was observed as signal enhancement in confocal imaging…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNear-Field Optical Microscopy

Effects of oxygen contents on the electrical and optical properties of indium molybdenum oxide films fabricated by high density plasma evaporation

Shi-Yao Sun、Jow-Lay Huang、Ding‐Fwu Lii2004-07-01Journal of Vacuum Science & Technology A Vacuum Surfaces and Films

Indium molybdenum oxide (IMO) films were made from an oxidized target with In2O3 and MoO3 in a weight proportion of 99:1 by using a high density plasma evaporation with the substrate maintained at room temperature. Effects of the oxygen contents of 1%–28.6% on the structural and optoelectronic properties of the IMO fi…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Comparison of the electronic structures of hydrated and unhydrated NaxCoO2:The effect of H2O

M. D. Johannes、Deobrat Singh2004-07-01Physical Review B

We report electronic structure calculations within density functional theory for the hydrated superconductor and compare the results with the parent compound . We find that the intercalation of water into the parent compound has little effect on the Fermi surface outside of the predictable effects of expansion, in par…

Physics of Superconductivity and MagnetismAdvanced Thermoelectric Materials and DevicesMagnetic and transport properties of perovskites and related materials