Materials Literature
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Soft templated mesoporous carbon films (ca. 60 nm thick) are fabricated by the cooperative assembly of poly(styrene- block -ethylene oxide) (PS- b -PEO) with phenolic resin, where the pore sizes are tuned by the addition of polystyrene oligomers (hPS) to this self-assembling system. Significant differences in the morp…
We predict a large spin-filtering effect in graphene zigzag nanoribbons in the presence of Rashba spin-orbit coupling. The spin polarization of the transmitted current reaches a maximum when the incoming electrons occupy only one subband and the outgoing electrons occupy two subbands (spin is not taken into account).…
Electronic structures of a charge-density wave (CDW) system CeTe${}_{2\ensuremath{-}x}$Sb${}_{x}$ ($x=0$, 0.05) have been investigated by employing angle-resolved photoemission spectroscopy (ARPES) and the first-principles electronic and phonon band-structure methods. The observed Fermi surface (FS) agrees very well w…
Ab initio methods are used to predict the diffusion coefficient of As dopants in ZnO as a function of Fermi level. Contributions to As diffusion from interstitial, simple substitutional, and cluster diffusion are considered. Formation and migration energies for Zn vacancies (V${}_{\mathrm{Zn}}$), As substituting on Zn…
The selected-control preparation of uniform core-shell and yolk-shell architectures, which combine the multiple functions of a superparamagnetic iron oxide (SPIO) core and europium-doped yttrium oxide (Y(2)O(3):Eu) shell in a single material with tunable fluorescence and magnetic properties, has been successfully achi…
The support of epitaxial films frequently determines their crystallographic orientation, which is of crucial importance for their properties. We report a novel way to alter the film orientation without changing the substrate. We show for the growth of CoO on the Ir(100) surface that, while the oxide grows in (111) ori…
In small structures the phonon mean free path due to phonon-phonon interactions and defect scattering may exceed the sample dimensions. The thermal conductivity then becomes dependent on the size and shape of the sample. In this article we present calculations of the conductivity under these conditions for several dif…
Kinetic models for nucleation, denucleation, Ostwald ripening (OR), and nanoparticle (NP) aggregation are presented and discussed from a physicochemical standpoint, in terms of their role in current NP preparations. Each of the four solid-state mechanisms discussed predict a distinct time dependence for the evolution…
A new aging calculation method for three-phase three-leg power transformers under (un)balanced and (non)sinusoidal operating conditions is proposed where the impacts of magnetic saturation, couplings, and hysteresis are accurately included. The aging estimation is carried out through a recently developed and validated…
Antagonistic shape memory actuators use opposing shape memory alloy (SMA) elements to create devices capable of producing differential motion paths and two-way mechanical work in a very efficient manner. There is no requirement for additional bias elements to 're-arm' the actuators and allow repetitive actuation. The…
In this Article, we focus on the in situ observation of photochemical reactions on individual nanoobjects of solid catalysts using single-molecule, single-particle fluorescence spectroscopy. The use of high-resolution imaging techniques with suitable fluorogenic probes enables us to determine the location of the catal…
A nanoforest structure for surface-enhanced Raman scattering (SERS) active substrates is fabricated and analyzed. The detailed morphology of the resulting structure can be easily controlled by modifying the process parameters such as initial gold layer thickness and etching time. The applicability of the nanoforest su…
Abstract Visible transparency is one of the attributes pursued in the advancement of display devices. Such a transparency can be realized in a plasma display device simply by applying Y(V,P)O4:Eu red‐, Y(V,P)O4:Tm blue‐, and LaPO4:Ce,Tb green‐emitting nanophosphors with a controlled particle size and reasonable lumine…
The objective of this work was the synthesis of serum albumin targeted, Gd(III)-based magnetic resonance imaging (MRI) contrast agents exhibiting a strong pH-dependent relaxivity. Two new complexes (Gd-glu and Gd-bbu) were synthesized based on the DO3A macrocycle modified with three carboxyalkyl substituents α to the…
The subloading surface model is based on the simple and natural postulate that the plastic strain rate develops as the stress approaches the yield surface. It therefore always describes the continuous variation of the tangent modulus. It requires no incorporation of an algorithm for the judgment of yielding, i.e., a j…
The synthesis of two novel bithiophenesilane-based dendronized polymers by a chain growth Kumada polymerization, their molecular properties in dilute solutions and thermal properties in the bulk are described and compared with those of bithiophenesilane dendrimers. GPC equipped with a dual light scattering detector ha…
A transverse-magnetic-pass (TM-pass) optical polarizer based on Cu complementary metal-oxide-semiconductor technology platform is proposed and analyzed using the 2-D method-of-lines numerical model. In designing the optimum configuration for the polarizer, it was found that the metal-insulator-metal (MIM) polarizer st…
Abstract Hydrodynamic cavitation reactors are known to intensify diverse physical and chemical processes. In this article, flow regime maps have been proposed that give an overview of the operation of hydrodynamic cavitation reactor for different combinations of design and process parameters. These maps are based on s…
The 1,3-dipolar cycloaddition reaction of 2-methyl-N-confused porphyrin with 2,6-dichlorobenzonitrile oxide yielded four isomeric monoadducts of carbachlorin type and one diadduct of carbabacteriochlorin type. Two major carbachlorin products, constituting 82% of the monoadducts, were shown to be structural precursors…
This study investigates the use of a short ultrasonic burst at the beginning of a cooling crystallization to achieve a growth dominated process and produce crystals with regular habit without the requirement of inoculation of seeds. The results of conventionally seeded crystallization experiments were compared with un…