Materials Literature
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The objective of this work was the synthesis of serum albumin targeted, Gd(III)-based magnetic resonance imaging (MRI) contrast agents exhibiting a strong pH-dependent relaxivity. Two new complexes (Gd-glu and Gd-bbu) were synthesized based on the DO3A macrocycle modified with three carboxyalkyl substituents α to the…
The subloading surface model is based on the simple and natural postulate that the plastic strain rate develops as the stress approaches the yield surface. It therefore always describes the continuous variation of the tangent modulus. It requires no incorporation of an algorithm for the judgment of yielding, i.e., a j…
The synthesis of two novel bithiophenesilane-based dendronized polymers by a chain growth Kumada polymerization, their molecular properties in dilute solutions and thermal properties in the bulk are described and compared with those of bithiophenesilane dendrimers. GPC equipped with a dual light scattering detector ha…
A transverse-magnetic-pass (TM-pass) optical polarizer based on Cu complementary metal-oxide-semiconductor technology platform is proposed and analyzed using the 2-D method-of-lines numerical model. In designing the optimum configuration for the polarizer, it was found that the metal-insulator-metal (MIM) polarizer st…
Abstract Hydrodynamic cavitation reactors are known to intensify diverse physical and chemical processes. In this article, flow regime maps have been proposed that give an overview of the operation of hydrodynamic cavitation reactor for different combinations of design and process parameters. These maps are based on s…
The 1,3-dipolar cycloaddition reaction of 2-methyl-N-confused porphyrin with 2,6-dichlorobenzonitrile oxide yielded four isomeric monoadducts of carbachlorin type and one diadduct of carbabacteriochlorin type. Two major carbachlorin products, constituting 82% of the monoadducts, were shown to be structural precursors…
This study investigates the use of a short ultrasonic burst at the beginning of a cooling crystallization to achieve a growth dominated process and produce crystals with regular habit without the requirement of inoculation of seeds. The results of conventionally seeded crystallization experiments were compared with un…
The physiological properties of polymer brush-afforded silica particles prepared by surface-initiated living radical polymerization were investigated in terms of the circulation lifetime in the blood and distribution in tissues. Hydrophilic polymers consisting mainly of poly(poly(ethylene glycol) methyl ether methacry…
We report on coherent manipulation of electron spins in an antiferromagnetically coupled spin triangle ${{\mathrm{Cu}}_{3}\mathrm{\text{\ensuremath{-}}}X}$ ($X=\mathrm{As}$, Sb) impregnated in freestanding nanoporous silicon (NS) by using 240 GHz microwave pulses. Rabi oscillations are observed and the spin coherence…
The modular nature of repeat proteins makes them a versatile platform for the design of smart materials with predetermined properties. Here, we present a general strategy for combining protein modules with specified stability and function into arrays for the assembly of stimuli-responsive gels. We have designed tetrat…
It is demonstrated that the presence of the metal on the walls of dielectric grating slits opens new possibilities for tailoring optical properties of metal–dielectric plasmonic gratings. In particular, a new kind of metal-thickness-sensitive resonances appear due to the excitation of the Fabry–Perot plasmonic modes i…
In this work, we study how film thickness and chain packing density affect the protein-resistant properties of polymer brushes in complex media. Polymer brushes based on dual-functional poly(carboxybetaine acrylamide) (pCB) were prepared via surface-initiated photoiniferter-mediated polymerization. By adjusting UV rad…
Fluorophores have been extensively used as the signal mediator in biosensing and bioimaging for a long time. Enhancement of fluorescence can amplify the signal, thus improving the sensitivity, enabling earlier and accurate disease detection and diagnosis. Some metal nanoparticles, such as gold and silver, can generate…
The local charge carrier density of graphene can exhibit significant and highly localized variations that arise from the interaction between graphene and the local environment, such as adsorbed water, or a supporting substrate. However, it has been difficult to correlate such spatial variations with individual impurit…
We simulate from first principles the energetic, structural, and electronic properties of ferroelectric (FE) ultrathin PbTiO3 nanotubes. The nanotube possesses spontaneous polarization despite their sidewalls being thinner than the critical thickness at which the thin films lose ferroelectricity; this indicates the ab…
It has been proved that zeolite MFI coatings synthesized by in situ hydrothermal synthesis is corrosion-resistant. Pure silica zeolite MFI (silicalite-1) coatings on aluminum alloy 1060 plates seeded by brush-coating a seed paste and leveling the seed layer with fingers have been synthesized by the seeded growth metho…
A Derjaguin-Broekhoff-de Boer analysis of adsorption and desorption in SBA-15 mesoporous silica is presented, using realistic geometrical models that account for the pore corrugation in these materials. The model parameters are derived from independent electron tomography and small-angle scattering characterization. A…
Electrochemical dealloying of a single-phase Al 2 Au alloy in sodium chloride solutions has been investigated considering influence of potential and electrolyte concentration. Both open-circuit potentials and corrosion potentials of Al 2 Au decrease with increasing electrolyte concentration and temperature. The overpo…
The fabrication of tissue engineering scaffolds is a well-established field that has gained recent prominence for the in vivo repair of a variety of tissue types. Recently, increasing levels of sophistication have been engineered into adjuvant scaffolds facilitating the concomitant presentation of a variety of stimuli…
ZnO tetrapods (ZnO-Ts) were synthesized in a vertical flow reactor by gas phase oxidation of Zn vapor in an air atmosphere. The morphology of the product was varied from nearly spherical nanoparticles to ZnO-Ts, together with the partial pressure of Zn and reaction temperature. MgO introduced during synthesis, increas…