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Acetate/Di-2-pyridyl Ketone Oximate “Blend” as a Source of High-Nuclearity Nickel(II) Clusters: Dependence of the Nuclearity on the Nature of the Inorganic Anion Present

Theocharis C. Stamatatos、Eleanna Diamantopoulou、Catherine P. Raptopoulou 等 6 位作者2007-03-01Inorganic Chemistry

The use of di-2-pyridyl ketone oxime [(py)2CNOH] in reactions with Ni(O2CMe)2.4H2O, in the presence or absence of extra inorganic anions (N3- and SCN-) has led to Ni4, Ni5, and Ni7 clusters; the magnetic study of the heptanuclear nickel(II) complex reveals an S = 3 ground state.

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

POROSITY DETERMINATION OF JERSEY STRUCTURE

Sofien Benltoufa、Faten Fayala、Morched Cheikhrouhou 等 4 位作者2007-03-01Autex Research Journal

Abstract In our paper, we attempt to investigate methods of determining jersey porosity which is this fabric’s principal physical characteristic. In fact, end use, liquid absorbency, thermal comfort and resistance are closely related to pore size and distribution. So it is important to study porosity, in order to clas…

Thermoregulation and physiological responsesDyeing and Modifying Textile FibersTextile materials and evaluations

Emerging nanomedicine opportunities with perfluorocarbon nanoparticles

Patrick M. Winter、Kejia Cai、Shelton D. Caruthers 等 5 位作者2007-03-01Expert Review of Medical Devices

Perfluorocarbon (PFC) nanoparticles can serve as a platform technology for molecular imaging and targeted drug-delivery applications. These nanoparticles are approximately 250 nm in diameter and are encapsulated in a phospholipid shell, which provides an ideal surface for the incorporation of targeting ligands, imagin…

Nanoparticle-Based Drug DeliveryAdvancements in Transdermal Drug DeliveryAdvanced Drug Delivery Systems

Galvanic replacement reaction: A simple and powerful route to hollow and porous metal nanostructures

Xianmao Lu、Jingyi Chen、Sara E. Skrabalak 等 4 位作者2007-03-01Proceedings of the Institution of Mechanical Engineers Part N Journal of Nanoengineering and Nanosystems

Galvanic replacement reaction provides a remarkably simple and versatile route to metal nanostructures with controllable hollow interiors and porous walls. The key step of this process involves the replacement reaction between a suspension of nanoscale metal templates and a salt precursor containing a relatively less…

Gold and Silver Nanoparticles Synthesis and ApplicationsAnodic Oxide Films and NanostructuresNanoporous metals and alloys

Schottky-Barrier Carbon Nanotube Field-Effect Transistor Modeling

Arash Hazeghi、Tejas Krishnamohan、H.‐S. Philip Wong2007-03-01IEEE Transactions on Electron Devices

The theoretical performance of carbon nanotube field-effect transistors (CNFETs) with Schottky barriers (SBs) is examined by means of a general ballistic model. A novel approach is used to treat the SBs at the metal-nanotube contacts as mesoscopic scatterers by modifying the distribution functions for carriers in the…

Carbon Nanotubes in CompositesGraphene research and applicationsAdvancements in Semiconductor Devices and Circuit Design

Comparative Theoretical Study of Heterocyclic Conducting Oligomers: Neutral and Oxidized Forms

Jordi Casanovas、Carlos Alemán2007-03-01The Journal of Physical Chemistry C

The structural and electronic properties of pyrrole-, thiophene-, phosphole-, 3,4-ethylenedioxythiophene-, and 3,4-ethylenedithiafurane-containing oligomers have been studied using density functional theory with the B3PW91 functional and the 6-31+G(d, p) basis set. Calculations were performed on systems containing two…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsOrganic and Molecular Conductors Research

Structure and Stability of Al-Doped Boron Clusters by the Density-Functional Theory

Xiaojuan Feng、You-Hua Luo2007-03-01The Journal of Physical Chemistry A

The geometries, stabilities, and electronic properties of Bn and AlBn clusters, up to n=12, have been systematically investigated by using the density-functional approach. The results of Bn clusters are in good agreement with previous conclusions. When the Al atom is doped in Bn clusters, the lowest-energy structures…

Rare-earth and actinide compoundsBoron and Carbon Nanomaterials ResearchSuperconductivity in MgB2 and Alloys

Ballistic Performance of Alumina/S‐2 Glass‐reinforced Polymer‐matrix Composite Hybrid Lightweight Armor Against Armor Piercing (ap) and Non‐AP Projectiles

M. Grujičić、B. Pandurangan、U. Zecevic 等 5 位作者2007-03-01Multidiscipline Modeling in Materials and Structures

The ability of light‐weight all fiber‐reinforced polymer‐matrix composite armor and hybrid composite‐based armor hard‐faced with ceramic tiles to withstand the impact of a non‐Armor‐ Piercing (non‐AP) and AP projectiles is investigated using a transient non‐linear dynamics computational analysis. The results obtained…

Advanced ceramic materials synthesisEnergetic Materials and CombustionHigh-Velocity Impact and Material Behavior

Whitlockite solid solutions Ca9−x M x R(PO4)7 (x = 1, 1.5; M = Mg, Zn, Cd; R = Ln, Y) with antiferroelectric properties

A. V. Teterskii、S. Yu. Stefanovich、Bogdan I. Lazoryak 等 4 位作者2007-03-01Russian Journal of Inorganic Chemistry

Whitlockite solid solutions Ca9−x M x R(PO4)7 (M = Mg, Zn, Cd; R = Ln, Y) were synthesized as powders and ceramics using solid-phase synthesis. Dielectric investigations and second harmonic generation (SHG) tests showed that ferroelectric (FE) phase transitions existing in samples with x = 0 change to antiferro-electr…

Crystal Structures and PropertiesSolid-state spectroscopy and crystallographyMicrowave Dielectric Ceramics Synthesis

Minimum-Fuel Powered Descent for Mars Pinpoint Landing

Ufuk Topcu、Jordi Casoliva、Kenneth D. Mease2007-03-01Journal of Spacecraft and Rockets

Covers advancements in spacecraft and tactical and strategic missile systems, including subsystem design and application, mission design and analysis, materials and structures, developments in space sciences, space processing and manufacturing, space operations, and applications of space technologies to other fields.

Spacecraft and Cryogenic TechnologiesGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies

Gamma Radiation‐Induced Crosslinked PVA/Chitosan Blends for Wound Dressing

Kariman M. El Salmawi2007-03-01Journal of Macromolecular Science Part A

Crosslinked polyvinyl alcohol (PVA) and chitosan polymer blends have been prepared by using gamma irradiation. Chitosan was used in the blends to prevent microbiological growth, such as bacteria and fungi on the polymer. The physical properties of the blend, such as gelation, water absorption, and mechanical propertie…

Nanocomposite Films for Food PackagingElectrospun Nanofibers in Biomedical ApplicationsWound Healing and Treatments

Failure Model for Silver Electrochemical Migration

Shuang Yang、Aristos Christou2007-03-01IEEE Transactions on Device and Materials Reliability

A new model for silver electrochemical migration is presented, which includes the insulation resistance degradation prior to dendritic growth. This failure model reported is based on the calculation of the ion accumulation rate. Failure occurs when the accumulated ion concentration exceeds the threshold. Experimental…

Electrocatalysts for Energy ConversionSemiconductor materials and devicesCopper Interconnects and Reliability

Nano-mesoscopic structure control in 9Cr–ODS ferritic steels

Shigeharu Ukai、Satoshi Ohtsuka2007-03-01Energy Materials

The development status of 9Cr–oxide dispersion strengthened (ODS) ferritic steels was reviewed, focusing on the authors' activities. This material is the most prospective cladding of the advanced high burn-up fuel elements for Japanese prototype fast breeder reactor MONJU and international Generation IV advanced fast…

Fusion materials and technologiesHigh Temperature Alloys and CreepNuclear Materials and Properties

Multiferroic BiFeO3 thin films deposited on SrRuO3 buffer layer by rf sputtering

Rongyan Zheng、Xingsen Gao、Z. H. Zhou 等 4 位作者2007-03-01Journal of Applied Physics

Sr Ru O 3 (SRO) acts as an effective buffer layer for growth of multiferroic BiFeO3 (BFO) thin films deposited on Pt∕TiO2∕SiO2∕Si substrates by radio frequency sputtering. Phase identification by using x-ray diffraction and texture studies by using atomic force microscopy show that the SRO buffer layer promotes crysta…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Grain-Size Effect on Electrical Properties of (Bi1/2K1/2)TiO3 Ceramics

Yuji Hiruma、Hajime Nagata、Tadashi Takenaka2007-03-01Japanese Journal of Applied Physics

In this study, Bi 2 O 3 -doped bismuth potassium titanate, (Bi 1/2 K 1/2 )TiO 3 , (abbreviated to BKT-Bi x ; x =0, 0.1, 0.2, 0.4, and 0.6 wt %) ceramics were fabricated by hot-pressing method, and its electrical properties were investigated in detail. Moreover, BKT-Bi0.6 was annealed at 1040 °C for 4–20 h to develop g…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Influence of fluoride concentration and pH on corrosion behavior of Ti‐6Al‐4V and Ti‐23Ta alloys in artificial saliva

A. Robin、J. P. Meirelis2007-03-01Materials and Corrosion

Abstract Titanium alloys exhibit an excellent corrosion resistance in most aqueous media due to the formation of a stable oxide film and some of these alloys (particularly Ti‐6Al‐4V) were chosen for surgical and odontological implants for this resistance and their biocompatibility. Treatments with fluorides (F − ) are…

Bone Tissue Engineering MaterialsDental materials and restorationsTitanium Alloys Microstructure and Properties

Carbon Nanotubes from Camphor: An Environment-Friendly Nanotechnology

Mukul Kumar、Yoshinori ANDO2007-03-01Journal of Physics Conference Series

High-purity carbon nanotubes (CNTs) are produced by chemical vapour deposition of camphor, an environment-friendly hydrocarbon. In a small CVD reactor (1-m long and 26- mm wide), CVD of 3 g camphor at 650°C for 1 hour yields ∼1.62 g MWNTs of diameter ∼10 nm with an as-grown purity over 88%; that is, camphor-to-CNT pro…

Carbon Nanotubes in CompositesGraphene research and applicationsNanotechnology research and applications

Deposition of epitaxial Ti2AlC thin films by pulsed cathodic arc

Johanna Rosén、L. Ryves、Per O. Å. Persson 等 4 位作者2007-03-01Journal of Applied Physics

A multicathode high current pulsed cathodic arc has been used to deposit Ti2AlC thin films belonging to the group of nanolaminate ternary compounds of composition Mn+1AXn. The required stoichiometry was achieved by means of alternating plasma pulses from three independent cathodes. We present x-ray diffraction and tra…

Metal and Thin Film MechanicsAluminum Alloys Composites PropertiesMXene and MAX Phase Materials

Nanofibrous Poly(ε-Caprolactone)/Poly(Vinyl Alcohol)/Chitosan Hybrid Scaffolds for Bone Tissue Engineering using Mesenchymal Stem Cells

Yousef Mohammadi、Milad Soleimani、Mohammad Fallahi‐Sichani 等 10 位作者2007-03-01The International Journal of Artificial Organs

In the present study, based on a biomimetic approach, novel 3D nanofibrous hybrid scaffolds consisting of poly(epsilon-caprolactone), poly(vinyl alcohol), and chitosan were developed via a multi-jet electrospinning method. The influence of chemical, physical, and structural properties of the scaffolds on the different…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsGraphene and Nanomaterials Applications

Fabrication and Characterization of Tubular Solid Oxide Fuel Cells

Nigel M. Sammes、Yanhai Du2007-03-01International Journal of Applied Ceramic Technology

Processes to fabricate tubular solid oxide fuel cells (SOFCs) using various electrolyte and electrode materials have been investigated. Single‐phase perovskite strontium‐ and magnesium‐doped lanthanum gallate (LSGM) was synthesized. Mechanical and thermal properties, and the cell performance of LSGM electrolyte fuel c…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides