Materials Literature
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Abstract The title complex was synthesized by the reaction of copper(I) iodide and tetrakis(ethylthio)tetrathiafulvalene (TTC2-TTF) in acetonitrile under argon atmosphere. The new compound, [(CuI)2TTC2-TTF], crystallizes in the monoclinic system, space group P21/m with unit-cell dimensions a = 9.843(2), b = 12.946(2),…
Abstract Electroactive 2,2′: 6,2″‐terpyridinyl ligands ( 3, 5, 6 ) and their iron(II) ( 7a–9a ) and ruthenium(II) complexes ( 7b–9b ) were synthesized. Bis[3‐(aminophenyl)‐2,2′ :6,2″‐terpyridinyl]metal(II) complexes ( 7a, 7b ) and bis[2‐(hydroxyphenyl)‐2,2′ :6,2″‐terpyridinyl]metal(II) complexes ( 8a, 8b ) were electr…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTConducting Polymers from Polybutadiene: Molecular Configuration Effects on the Iodine-Induced Conjugation ReactionsLiming Dai, Albert W. H. Mau, Hans J. Griesser, and David A. WinklerCite this: Macromolecules 1994, 27, 23, 6728–6735Publication Date (Print):November 1, 1994Pu…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTFormation of a Flexible Graphite Film from Poly(acrylonitrile) Using a Layered Clay Film as TemplateTakashi Kyotani, Toshiki Mori, and Akira TomitaCite this: Chem. Mater. 1994, 6, 11, 2138–2142Publication Date (Print):November 1, 1994Publication History Published online1 May…
Amorphous carbon (a-C) structures over a wide range of densities are generated using tight-binding molecular-dynamics simulations. The a-C networks obtained by quenching low-density liquids consist of mostly threefold coordinated atoms. These a-C structures correspond to those obtained experimentally by evaporation of…
An interference effect on angular correlation patterns due to the exchange of Auger and photoelectrons of the same energy is discussed. The detection in coincidence of Auger and photoelectrons may reveal a striking angular correlation pattern when a synchrotron light source is tuned so that the Auger and photoelectron…
We observed the spontaneous electric polarization reversal induced by the magnetic field of 100 kOe at 78 K in single crystal samples of orthorhombic β'-phases of Tb2(MoO4)3 and TbGd(MoO4)3. We explained this effect by magnetoelastic coupling between the magnetic and electric subsystems in a crystal. This explanation…
A new class of amorphous and icosahedral phases has been obtained in rapidly solidified Zn-Mg-Rare-Earth Metal (RE) ternary alloys. The rapidly solidified alloy structure exhibits the amorphous phase when it contains the RE elements of La, Ce, Pr or Eu with large atomic size. On the other hand, it exhibits the icosahe…
We used electron-energy-loss spectrometry to measure the intensities of the Cu white lines found at the onsets of the ${\mathit{L}}_{2}$ and ${\mathit{L}}_{3}$ absorption edges of rapidly quenched CuZr, CuTi, CuPd, CuPt, and CuAu. Enhancements of the white lines in the alloys as compared to elemental Cu were correlate…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPhotoinduced Reduction of Viologens on Size-Separated CdS NanocrystalsHajime Matsumoto, Hiroyuki Uchida, Takahiro Matsunaga, Koji Tanaka, Takao Sakata, Hirotaro Mori, and Hiroshi YoneyamaCite this: J. Phys. Chem. 1994, 98, 44, 11549–11556Publication Date (Print):November 1,…
Orientationally disordered crystals possess translational order while retaining rotational and conformational degrees of freedom. Because these materials exhibit a glasslike transition, they are of great theoretical and experimental interest as model systems for structural glasses. We present detailed measurements of…
Abstract Conjugated dimeric TTFs linked with an ethenylene or ethynylene spacer were prepared as novel electron donors and preferentially formed 1:1 complexes with TCNQF4 and with DDQ, which were more conductive than those of monomeric TTFs.
This study focused on the chemistry of soil water samples (SWS) obtained by tension-free lysimetry from serpentinitic, i.e., Cr- and Ni-rich, Dystric Eutrochrepts. Soil water samples from undisturbed soil profiles had total elemental concentrations (μnmol/L) of O.1–3.2 Cr, O.2–3.1 Ni, 3–154 Fe, and 55–401 Mg; however,…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTChemistry and Structure of Al(OH)/Organic Precipitates. A Small-Angle X-ray Scattering Study. 3. Depolymerization of the Al13 Polycation by Organic LigandsA. Masion, F. Thomas, D. Tchoubar, J. Y. Bottero, and P. TekelyCite this: Langmuir 1994, 10, 11, 4353–4356Publication Da…
We present a detailed analysis of the nature of electronic eigenfunctions in one-dimensional quasiperiodic chains based on a clustering idea recently introduced by us [Sil et al., Phys. Rev. B 48, 4192 (1993)], within the framework of the real-space renormalization-group approach. It is shown that even in the absence…
A hybrid medial tissue composed of a type I collagen gel, into which smooth muscle cells (SMCs) derived from bovine aortic media were 3-dimensionally (3D) embedded, was constructed around an elastomeric silicone tube (outer diameter: 8 mm). Subsequently, hybrid tissues thus prepared were subjected to three modes of me…
This paper describes the study of the effects of radiation damage on the quality of data collected from a protein crystal at 100 K. It is shown that radiation damage causes measurable effects in the diffraction pattern. This implies that, even at liquid nitrogen temperatures, there is a limit to the size of a crystal…
There is a need to improve the selectivity of photodynamic therapy and for better targeting of tumor cells within specific tumor compartments. Selective in vitro phototoxicity of a human bladder carcinoma cell line 647V has been achieved by targeting sulfonated aluminum phthalocyanines (AlSPc) with monoclonal antibodi…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMagnetic Exchange in Dinuclear Chromium(II) Complexes: Effect of Bridging Chlorides and Bridging Hydrides in Antiferromagnetic CouplingMichael D. Fryzuk, Daniel B. Leznoff, Steven J. Rettig, and Robert C. ThompsonCite this: Inorg. Chem. 1994, 33, 24, 5528–5534Publication Dat…
Glutaconate coenzyme A-transferase (Gct) from Acidaminococcus fermentans consists of two subunits (GctA, 35725 Da and GctB, 29168 Da). The N-termini sequences of both subunits were determined. DNA sequencing of a subgenomic fragment of A. fermentans revealed that the genes encoding glutaconate CoA-transferase (gctAB)…