Materials Literature
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This paper reviews selected types of structurally well defined assemblies of porphyrins and phthalocyanines with strong electronic coupling. Face-to-face, head-to-tail, slipped cofacial, and non-parallel dimeric motifs constructed by covalent and non-covalent bonds are compared in the earlier sections. Their molecular…
We investigated initial cell adhesion on self-assembled monolayers (SAMs) of alkanethiols carrying different functional groups including methyl (CH3), hydroxyl (OH), carboxylic acid (COOH), and amine (NH2). The combination of a surface plasmon resonance (SPR) instrument and a total internal reflection fluorescence mic…
Abaca fibre reinforced PP composites were fabricated with different fibre loadings Flax and jute fibre reinforced PP composites were also fabricated with 30 wt% fibre loading. The mechanical properties, odour emission and structure properties were investigated for those composites. Tensile, flexural and Charpy impact…
Polyelectrolyte microcapsules have been loaded with a pH-sensitive, high molecular weight SNARF-1-dextran conjugate. SNARF-1 exhibits a significant pH-dependent emission shift from green to red fluorescence under acidic and basic conditions, respectively. The unique spectral properties of the dye were maintained after…
Titanium may be considered a relatively new engineering material. It was discovered much later than the other commonly used metals, its commercial application starting in the late 1940s. Its usage as an implant material began in the 1960s, despite the fact that titanium exhibits superior corrosion resistance and tissu…
In this paper we address several key aspects to the formation mechanism of self-organized oxide nanotube layers grown by anodization of valve metals and their alloys in fluoride ion containing electrolytes. We suggest that ( i ) the self-organized structure is produced as a result of an autocatalytic reaction, in whic…
Based on physical models, distributed circuit models are presented for single-walled carbon nanotubes (SWCNs) and SWCN bundles that are valid for all voltages and lengths. These models can be used for circuit simulations and compact modeling. It is demonstrated that by customizing SWCN interconnects at the local, semi…
A wide range of biomedical devices is applied clinically in contact with blood. Tailoring the surface properties of the involved biomaterials is a common approach to enhance performance and to limit adverse reactions. This review summarizes current trends in coating technologies developed for that purpose. Inorganic c…
With an ever-increasing need for thin, flexible and functional materials in electrochemical systems, the layer-by-layer (LbL) technique provides a simple and affordable route in creating new, active electrodes and electrolytes. The LbL technique, which is based upon the alternate adsorption of oppositely charged speci…
The vaporization of chromium species from chromia scales limits the applicability of chromia-forming steels at high temperatures and is one of the major reasons for degradation in the development of planar solid oxide fuel cells (SOFCs). vaporized from the interconnector is reduced at the cathode and deposits in the f…
The effect of hydrogen sulfide on the performance of nickel/yttria-stabilized zirconia (YSZ) cermet anode for solid oxide fuel cells has been studied under various operating conditions. In all cases, a small amount of (ppm level) causes a sharp drop in cell performance within the first few minutes of exposure, followe…
Photonic metamaterials could provide optical nonlinearities far exceeding those of natural substances due to the combined action of (magnetic) resonances and local-field enhancements. Here, we present our experiments on second- and third-harmonic generation from magnetic metamaterials composed of nanoscale gold split-…
A new class of monodisperse water-soluble magnetite nanoparticles was prepared by a simple and inexpensive method based on a polyol process, and their potential as MRI contrast agents was investigated.
International audience
Chemical bath deposition (CBD) has been used to deposit films of metal sulfides, selenides and oxides, together with some miscellaneous compounds, beginning nearly 140 years ago. While it is a well-known technique in a few specific areas (notably photoconductive lead salt detectors, photoelectrodes and more recently,…
For the first time, fully exfoliated graphite oxide nanoplatelets have been fabricated successfully in a polar organic solvent N,N-dimethylformamide from graphite oxide without any assistance of chemical treatment. The graphite oxide was prepared from expandable graphite by using Hummer’s method.
Super-hydrophilic polymer brushes were prepared by surface-initiated atom transfer radical polymerization of 2-methacryloyloxyethyl phosphorylcholine (MPC) on initiator-immobilized silicon wafers. The graft density was estimated to be 0.22 chains nm based on the linear relationship between and the layer thickness. The…
Materials displaying high oxide-ion conductivity have attracted considerable interest due to technological applications in solid oxide fuel cells (SOFCs), oxygen sensors and separation membranes. This has driven research into the identification of new classes of oxide-ion conductors, and in this review, work on the re…
Nanotechnology has applications across most economic sectors and allows the development of new enabling science. The ability to see materials down to nanoscale dimensions and to control how materials are constructed at the nanoscale is providing the opportunity to develop new materials and products in previously unima…
Biodegradable polymeric blends are expected to be widely used by industry due to their environmental friendliness and comparable mechanical and thermal properties. Poly (lactic acid) (PLA) and poly (butylene succinate) (PBS) are such biodegradable polymers which aim to replace commodity polymers in future applications…