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Mechanical relaxations in heat‐aged polycarbonate. Part I: Comparison between two molecular weights

Pearl Lee‐Sullivan、Donna Dykeman、Qing Shao2003-02-01Polymer Engineering and Science

Abstract As part of a wider research program related to polycarbonate embrittlement, the effects of heat‐aging on mechanical relaxation behavior have been studied by examining the relationship between secondary transitions and stress relaxation behavior. In this Part I, the differences in response between two molecula…

Polymer crystallization and propertiesMaterial Dynamics and PropertiesPolymer Nanocomposites and Properties

Cyprinid fishes as samplers of benthic diatom communities in freshwater streams of varying water quality

Ted C Rosati、Jeffrey R. Johansen、Miles M. Coburn2003-02-01Canadian Journal of Fisheries and Aquatic Sciences

The diatom composition of natural substrates in streams of different water qualities was compared among samples collected by researchers and samples collected from the intestine contents of three species of Cyprinid fishes: Campostoma anomalum, Pimephales notatus, and Semotilus atromaculatus. Campostoma and Pimephales…

Aquatic Ecosystems and Phytoplankton DynamicsFreshwater macroinvertebrate diversity and ecologyDiatoms and Algae Research

Performance of Alumina Membranes from New Nanosynthesis in Ultrafiltration and Nanofiltration

Andreas Krell、Hongwei Ma2003-02-01Journal of the American Ceramic Society

Starting from simple inorganic or organic raw materials in aqueous or alcoholic solvents, a synthesis process has been developed for (i) the preparation of sol–gel‐derived alumina (Al 2 O 3 ) membranes or (ii) the manufacture of membranes by the deposition of precalcined nanocorundum (α‐Al 2 O 3 ) powders. Because of…

Mesoporous Materials and CatalysisCatalysis and Hydrodesulfurization StudiesNanomaterials for catalytic reactions

Toroidal varied-line space (TVLS) gratings

Roger J. Thomas2003-02-01Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

It is a particular challenge to develop a stigmatic spectrograph for EUV wavelengths since the very low normal-incidence reflectance of standard materials most often requires that the design be restricted to a single optical element which must simultaneously provide both re-imaging and spectral dispersion. This proble…

Adaptive optics and wavefront sensingOptical Coatings and Gratingssolar cell performance optimization

Synthesis of new singly metal-metal-bonded heterobinuclear complexes involving a porphyrin and a corrole: X-ray structure of the rhodium tetraphenylporphyrin-tin(2,3,7,13,17,18-hexamethyl-8,12-diethylcorrole) complex

Jean‐Michel Barbe、G. Morata、Enrique Espinosa 等 4 位作者2003-02-01Journal of Porphyrins and Phthalocyanines

The nucleophilic attack of a rhodium(I) porphyrin on a chlorotin(IV) corrole yields the heterobinuclear rhodium porphyrin-tin corrole complex where the two metals are bound via a single metal-metal bond. The X-ray structure of the rhodium tetraphenylporphyrin-tin(2,3,7,13,17,18-hexamethyl-8,12-diethylcorrole) complex…

Metal complexes synthesis and propertiesPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Model Reduction in Emulsion Polymerization Using Hybrid First‐Principles/Artificial Neural Network Models

Alicia d’Anjou、Francisco Torrealdea、José R. Leiza 等 5 位作者2003-02-01Macromolecular Theory and Simulations

Abstract A first‐principles mathematical model for emulsion polymerization was reduced by using a hybrid mathematical model composed by artificial neural networks (ANN) and material balances. The goal was to have an accurate model that may be integrated fast enough to be used for online optimization purposes. In the r…

Advanced Polymer Synthesis and CharacterizationSpectroscopy and Chemometric AnalysesMachine Learning in Materials Science

Novel Technology for 3D Nonwovens

Hugh Gong、Zhibao Dong、I. Porat2003-02-01Textile Research Journal

Nonwovens are widely used in technical applications and for composite preforms. The current technology of forming 3D shapes from flat webs is inefficient and results in uneven final products due to joints. The technology presented in this paper enables the production of 3D preforms directly from fibers, thus eliminati…

Dyeing and Modifying Textile FibersTextile materials and evaluationsColor Science and Applications

In situ polymerisation of monomers in layered double hydroxides

El Mostafa Moujahid、Fabrice Leroux、Marc Dubois 等 4 位作者2003-02-01Comptes Rendus Chimie

Vinyl or amino-benzene sulfonates (VBS and ABS) are polymerised in situ after a soft thermal treatment ( T = 473 K) between the sheets of layered double hydroxides (LDH). The reaction of polymerisation is studied either by 13 C CP- MAS NMR or ESR spectroscopies. The resonance peak associated to the vinyl group disappe…

Polyoxometalates: Synthesis and ApplicationsLayered Double Hydroxides Synthesis and ApplicationsSynthesis and properties of polymers

Viscoelastic properties of threads before and after sewing

Isao Ajiki、Ron Postle2003-02-01International Journal of Clothing Science and Technology

The viscoelastic properties of the sewing thread before and after loading in the sewing process were investigated. Sewing threads are subjected to dynamic tension and friction in the sewing process. In order to compare polyester, cotton and silk sewing threads, the fineness of the threads were selected to be almost eq…

Mechanical Behavior of CompositesOptical measurement and interference techniquesTextile materials and evaluations

Effect of nylon66 addition on the mechanical properties and fracture morphology of poly(phenylene sulfide)/glass fiber composites

Bo Sun Lee、Byoung Chul Chun2003-02-01Polymer Composites

Abstract In this study, the toughening effect of nylon66 on the PPS/glass fiber composite at various nylon66 contents and testing temperatures was analyzed using tensile and notched Izod impact test. Also, the corresponding fracture surface morphology was observed and analyzed. Mechanical properties such as strain at…

Mechanical Behavior of CompositesPolymer crystallization and propertiesFiber-reinforced polymer composites

Characterization of modulus and glass transition phenomena in poly(L‐lactide)/hydroxyapatite composites

Luca Fambri、Kemal Kesenci、Claudio Migliaresi2003-02-01Polymer Composites

Abstract In order to study the dynamic‐mechanical properties of Poly(L‐lactide)/Hydroxyapatite (PLLA/HA) composites, two different molecular weight (inherent viscosity (η inh ): 4.0 (dL/g), and 7.8 (dL/g)) poly(L‐lactide) (PLLA) were synthesized by bulk polymerization and filled with 10%, 30%, and 50% (w/w) with medic…

Bone Tissue Engineering MaterialsDental materials and restorationsbiodegradable polymer synthesis and properties

Development of a new off-line test procedure for low voltage rotating machines fed by adjustable speed drives (ASD)

Pierre Bidan、Thierry Lebey、C. Neacsu2003-02-01IEEE Transactions on Dielectrics and Electrical Insulation

Using adjustable speed drives employing fast switching components to supply low voltage asynchronous motors may be detrimental to their reliability in some cases. The premature failures of the insulating materials are often attributed to the existence of partial discharges (PD) in the windings. Nevertheless, a clear e…

High voltage insulation and dielectric phenomenaElectromagnetic Compatibility and Noise SuppressionElectrostatic Discharge in Electronics

Synthesis and studies of some 4-substituted phenyl-4′-azopyridine-containing hydrogen-bonded supramolecular mesogens

V. Ajay Mallia、P. K. Sudhadevi Antharjanam、Suresh Das2003-02-01Liquid Crystals

Novel azopyridine-containing supramolecular liquid crystalline (LC) materials built via 1 : 1-heterointermolecular hydrogen bonding between some 4-substituted phenyl-4′-azopyridines and 4-n-alkyloxybenzoic acids are reported. These hydrogen-bonded LC complexes exhibit well defined nematic, smectic A and smectic C phas…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Volatile by‐products during heat polymerization of soybean oil

Sevim Z. Erhan、Quan Z. Sheng、Hong‐Sik Hwang2003-02-01Journal of the American Oil Chemists Society

Abstract Volatile by‐products during heat polymerization of soybean oil at 330°C were analyzed using GC‐MS and NMR. Color and viscosity changes were monitored for the heat‐polymerized soybean oil and the by‐products. About 90% (w/w) of the by‐products were decanoic, palmitic, linoleic, oleic, and stearic acids and cis…

Advanced Polymer Synthesis and CharacterizationPolymer composites and self-healingCultural Heritage Materials Analysis

Reverse Turn Induced π-Facial Selectivity during Polyaniline-Supported Cobalt(II) Salen Catalyzed Aerobic Epoxidation ofN-Cinnamoyll-Proline Derived Peptides

Jyoti Prokosh Nandy、Erode N. Prabhakaran、Sarvesh Kumar 等 5 位作者2003-02-01The Journal of Organic Chemistry

A novel chemo- and diastereoselective aerobic epoxidation of the N-cinnamoyl peptides catalyzed by polyaniline-supported cobalt(II) salen (PASCOS) is described. The N-cinnamoyl proline derived peptides 1 show a high pi-facial selectivity during these epoxidations. The origin of this diastereoselectivity in 1 has been…

Porphyrin and Phthalocyanine ChemistryPolyoxometalates: Synthesis and ApplicationsPhotochromic and Fluorescence Chemistry

A Genetic Algorithm for Searching Weaving Parameters for Woven Fabrics

Jeng-Jong Lin2003-02-01Textile Research Journal

In this study, an intelligent R&D design system is used to obtain the best combination of weaving parameters for woven fabric designs. The searching mechanism, developed in the Turbo C programming environment, and the theory, based on a genetic algorithm, can find several desired solutions of weaving parameters to…

Textile materials and evaluationsIndustrial Vision Systems and Defect Detection

Loss of K-Bearing Clay Minerals in Flood-Irrigated, Rice-Growing Soils in Jiangxi Province, China

Zhongpei Li、B. Velde、Chao Li2003-02-01Clays and Clay Minerals

Abstract The loss of K-bearing clay minerals has been observed over an 80 y cultivation period in Chinese rice paddies despite the use of NKP fertilizers. Clay mineral determinations were made in flood-irrigated paddies cultivated for 3, 10, 15, 30 and 80 y in clayey (45 wt.%), red soils derived from red Quaternary se…

Soil and Unsaturated FlowClay minerals and soil interactionsAluminum toxicity and tolerance in plants and animals

Inhibition of Bromide-Pitting Corrosion of Type 904L Stainless Steel

E. A. Abd El Meguid、N. A. Mahmoud2003-02-01CORROSION

Pitting corrosion of Type 904L (UNS N08904) stainless steel was investigated using the potentiodynamic polarization technique in different bromide concentrations, as well as in 0.6 M sodium bromide (NaBr) in the presence of some inorganic compounds at elevated temperatures. The critical pitting potential (Epit) of the…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsNuclear Physics and Applications

Toughness Optimization of SBR Elastomers – Use of Fracture Mechanics Methods for Characterization

K. Reincke、Wolfgang Grellmann、Ralf Lach 等 4 位作者2003-02-01Macromolecular Materials and Engineering

Abstract Elastomer materials are used in a wide application range and subjected to different loading from which failure of the material results. Because this failure is caused by initiation and propagation of cracks, the application of fracture mechanics methods for the assessment of the material is obvious. A short s…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesThermal and Kinetic Analysis

Study on composition and characteristics of maleated ethylene‐octene copolymer prepared by reactive extrusion on the morphology and properties of polyamide 6/ethylene‐octene copolymer blends

K. Premphet‐Sirisinha、S. Chalearmthitipa2003-02-01Polymer Engineering and Science

Abstract Blends of polyamide 6 (PA6) and elastomeric ethylene‐octene copolymer (EOR), with and without maleated EOR (EOR‐MA) were studied. EOR‐MA with various amounts of grafted MA and gel content were prepared by reactive extrusion. The effects of EOR‐MA characteristics and composition on the morphology, thermal and…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties