Materials Literature
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A series of metal amidoboranes LiNH(2)BH(3) (LAB), NaNH(2)BH(3) (SAB), LiNH(Me)BH(3) (LMAB), NaNH(Me)BH(3) (SMAB), KNH(Me)BH(3) (PMAB), and KNH((t)Bu)BH(3) (PBAB) were synthesized by solution phase methods, and the thermal release of H(2) in the solid state was studied. The mechanism of hydrogen release from metal ami…
Disassembling a supramolecular assembly and releasing the contents of the assembly in response to a stimulus are important goals of supramolecular chemistry. When proteins are used as the stimulus, the biological relevance of the supramolecular event dramatically increases. Although there have been efforts in which su…
Silica nanospheres with varied morphologies and pore structures, including mesoporous nanospheres, nanospheres with hierarchical pores (from 2 to 100 nm), and hollow nanospheres of mesoporous shell, were fabricated at room temperature simply by regulating the ethanol/ethyl ether volume ratio in the starting solution.…
The correlated electronic structure of the submonolayer surface systems Sn/Si(111) and Sn/Ge(111) is investigated by density-functional theory (DFT) and its combination with explicit many-body methods. Namely, the dynamical mean-field theory and the slave-boson mean-field theory are utilized for the study of the intri…
Oxide ionic conductors typically operate at high temperatures, which limits their usefulness. Colossal room-temperature ionic conductivity was recently discovered in multilayers of yttria-stabilized zirconia (YSZ) and SrTiO3. Here we report density-functional calculations that trace the origin of the effect to a combi…
We present an experimental study of the tunability of the silver nanoparticle localized plasmon resonance in close proximity to a gold film. Broad-band tuning of the silver particle plasmon resonance from blue wavelengths into the near-IR region can be achieved due to strong electromagnetic coupling between the nanopa…
Exposure of highly oriented pyrolytic graphite to bromine vapor gives rise to in-plane charge conductivities which increase monotonically with intercalation time toward values (for $\ensuremath{\sim}6\text{ }\text{at}\text{ }\mathrm{%}$ Br) that are significantly higher than Cu at temperatures down to 5 K. Magnetotran…
UNLABELLED: Silver ion migration and antimicrobial activity of PLA (polylactic acid-polylactide)/silver zeolite composites were investigated. Films prepared by solution-casting/solvent evaporation, or by melt-mixing/compression molding were compared. Silver migration to food simulants and TSB (tryptone soy broth) was…
Abstract Despite extensive use of type I collagen for research and medical applications, its fibril‐forming or polymerization potential has yet to be fully defined and exploited. Here, we describe a type I collagen formulation that is acid solubilized from porcine skin collagen (PSC), quality controlled based upon pol…
With an MBE technique, a Si/Ge heterostructures are prepared containing layers of nanostructured Ge with quantum dots of size of several nanometers. The effective conductivity of the layers is determined by a quasioptical terahertz-subterahertz coherent source BWO spectroscopy. The conductivity is found to be strongly…
Recent nanotoxicity studies revealed that the physico-chemical characteristics of engineered nanomaterials play an important role in the interactions with living cells. Here, we report on the toxicity and uptake of cerium and iron oxide sub-10-nm nanoparticles by NIH/3T3 mouse fibroblasts. Coating strategies include l…
A new calorimeter for measurements of the AC heat capacity and magnetocaloric effect of small samples in pulsed magnetic fields is discussed for the exploration of thermal and thermodynamic properties at temperatures down to 2 K. We tested the method up to μ0H = 50 Tesla, but it could be extended to higher fields. For…
We report that 30-inch scale multiple roll-to-roll transfer and wet chemical doping considerably enhance the electrical properties of the graphene films grown on roll-type Cu substrates by chemical vapor deposition. The resulting graphene films shows a sheet resistance as low as ~30 Ohm/sq at ~90 % transparency which…
The paper concerns the dependence of thermomechanical properties of three-dimensional solid nanoclusters on the cluster size as well as on its shape. Investigations are restricted to the class of so-called homogeneous thermodynamic processes with kinematics based on affine group and referred to the one whole body, not…
Using first-principles calculations, we show that the formation of carbohydrate directly from carbon and water is energetically favored when graphene membrane is subjected to aqueous environment with difference in chemical potential across the two sides. The resultant carbohydrate is two-dimensional, where the hydroge…
We present results on all-MgB2 tunnel junctions, where the tunnel barrier is deposited MgO or native-oxide of base electrode. For the junctions with MgO, the hysteretic I-V curve resembles a conventional underdamped Josephson junction characteristic with critical current-resistance product nearly independent of the ju…
Based on ab initio calculations we identify possible scenarios for the Kondo effect due to Co adatoms on graphene. General symmetry arguments show that for magnetic atoms in high-symmetry positions, the Kondo effect in graphene is controlled not only by the spin but also by the orbital degree of freedom. For a Co atom…
The trans-cis photoisomerization of azobenzene-containing materials is key to a number of photomechanical applications, but the actual conversion mechanism in condensed phases is still largely unknown. Herein, we study the n, pi* isomerization in a vacuum and in various solvents via a modified molecular dynamics simul…
The electron-phonon interaction in monolayer graphene is investigated using density-functional perturbation theory. The results indicate that the electron-phonon interaction strength is of comparable magnitude for all four in-plane phonon branches and must be considered simultaneously. Moreover, the calculated scatter…
Multifunctional superparamagnetic nanoparticles have been developed for a wide range of applications in nanomedicine, such as serving as tumor-targeted drug carriers and molecular imaging agents. To function in vivo, the development of these novel materials must overcome several challenging requirements including bioc…