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Using 5,10,15,20-tetra(4-nitrophenyl)porphyrin as a fluorescent chemosensor to determine Ru3+

Tienkul Kangwanwong、Wanchai Pluempanupat、Waraporn Parasuk 等 5 位作者2012-01-01ScienceAsia

porphyrin (TNPP) has been synthesized using the reaction of pyrrole and 4-nitrobenzaldehyde in the presence of propionic acid. The TNPP was used as a new fluorescent chemosensor to determine Ru 3+ with higher selectivity than other ions such as Hg 2+ , CH3Hg + , Ag + , Co 2+ , Cd 2+ , Ni 2+ , Cr 3+ , Fe 3+ , Cu 2+ , o…

Electrochemical sensors and biosensorsMolecular Sensors and Ion DetectionPorphyrin and Phthalocyanine Chemistry

Synthetic osteogenic extracellular matrix formed by coated silicon dioxide nanosprings

Jamie Hass、Erin Garrison、Sarah A. Wicher 等 7 位作者2012-01-01Journal of Nanobiotechnology

BACKGROUND: The design of biomimetic materials that parallel the morphology and biology of extracellular matrixes is key to the ability to grow functional tissues in vitro and to enhance the integration of biomaterial implants into existing tissues in vivo. Special attention has been put into mimicking the nanostructu…

Bone Tissue Engineering MaterialsNanoparticles: synthesis and applicationsGraphene and Nanomaterials Applications

Casting Routes for Porous Metals Production

Petr Lichý、V. Bednářová、T. Elbel2012-01-01Archives of Foundry Engineering

Casting Routes for Porous Metals Production The last decade has seen growing interest in professional public about applications of porous metallic materials. Porous metals represent a new type of materials with low densities, large specific surface, and novel physical and mechanical properties, characterized by low de…

Cellular and Composite StructuresMaterials Engineering and ProcessingMetallurgy and Material Science

Crystallization of l-alanine in the presence of additives on a circular PMMA platform designed for metal-assisted and microwave-accelerated evaporative crystallization

Anginelle M. Alabanza、Muzaffer Mohammed、Kadir Aslan2012-01-01CrystEngComm

Crystallization of l-alanine in the presence of l-valine and l-tryptophan additives on a circular poly(methyl) methacrylate (PMMA) platform designed for Metal-Assisted and Microwave-Accelerated Evaporative Crystallization (MA-MAEC) technique was investigated. Theoretical simulations predicted homogeneous temperature a…

Analytical Chemistry and ChromatographyProtein purification and stabilityCrystallization and Solubility Studies

Exfoliated Graphite Reinforced PMMA Composite: A Study on Nanoindentation and Scratch Behavior

Himel Chakraborty、Arijit Sinha、Nillohit Mukherjee 等 4 位作者2012-01-01Journal of Nanotechnology

The present work aims to compare the scratch hardness ( H s ) with the indentation hardness ( H IT ) obtained from nanoindentation measurements of exfoliated graphite/poly (methyl methacrylate) (EG/PMMA) composites. EG/PMMA composites with thickness 50 μm each were produced by in situ melt mixing method. Scratch hardn…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchTribology and Wear Analysis

Structural flexibility of DNA-like conformers of canonical 2′-deoxyribonucleosides

Tymofii Yu. Nikolaienko、Л. А. Булавін、Dmytro М. Hovorun2012-01-01Physical Chemistry Chemical Physics

Relaxed force constants (RFC) and vibrational root-mean-square (VRMS) deviations are used for comparative characterization of mechanical properties of canonical 2'-deoxyribonucleosides (2DRs) and 1,2-dideoxyribose molecule, their model sugar residue. It has been shown that RFC and VRMS should be preferred over traditi…

DNA and Nucleic Acid ChemistryCrystallography and molecular interactionsEnzyme Structure and Function

Valence Band Offset at a-B:H and a-BP:H/Si Interfaces

Sean W. King、Marc French、Milt Jaehnig 等 5 位作者2012-01-01ECS Journal of Solid State Science and Technology

In order to understand the fundamental charge transport in amorphous boron heterostructure devices, we have utilized X-ray photoelectron spectroscopy to determine the valence band offset present at interfaces formed by plasma enhanced chemical vapor deposition of a-B:H and a-BP:H on Si (100) substrates. For both cases…

Semiconductor materials and devicesSilicon Nanostructures and PhotoluminescenceSemiconductor materials and interfaces

Nonlinear capacitors for ESD protection

Hongyu Li、Victor Khilkevich、Tianqi Li 等 6 位作者2012-01-01IEEE Electromagnetic Compatibility Magazine

In order to protect electronic products from Electrostatic Discharge (ESD) damage, multi-layer ceramic capacitors (MLCC) are often used to bypass the transient ESD energy. Most dielectric materials used in MLCC are nonlinear, since the dielectric constant decreases with increasing voltage, reducing the capacitance val…

Semiconductor materials and devicesCopper Interconnects and ReliabilityElectrostatic Discharge in Electronics

2-(2,3,4,5,6-Pentafluorophenyl)-1H-benzo[d]imidazole, a fluorine-rich building block for the preparation of conjugated polymer donors for organic solar cell applications

Marios Neophytou、H. A. Ioannidou、Theodosia A. Ioannou 等 8 位作者2012-01-01Polymer Chemistry

We have introduced the pentafluorophenyl substituted benzimidazole as a building block of conjugated polymers for optoelectronic applications. We present the synthesis of a copolymer bearing fluorene as the comonomer. A detailed characterization of the novel material including structural, electrochemical and optical (…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Electron Moiré method

Satoshi Kishimoto2012-01-01Theoretical and Applied Mechanics Letters

It is very important to measure local deformations for an in-depth understanding of mechanical properties and fracture mechanism of structural and functional materials. In this paper, different types of model grid fabrication methods and many types of electron Moiré methods using an electron beam drawing system, a sca…

Advanced Surface Polishing TechniquesAdvancements in Photolithography TechniquesOptical Coatings and Gratings

A new non-uniform blast load model for SDOF method of one-way reinforced concrete slab

Wei Wang、D. Zhang、F. Lu 等 5 位作者2012-01-01EPJ Web of Conferences

A new effective model for calculation of the equivalent uniform blast load for non-uniform blast load such as close-in explosion of a one-way square and rectangle reinforced concrete slab is proposed in this paper. The model is then validated using single degree of freedom (SDOF) system with the experiments and blast…

High-Velocity Impact and Material BehaviorStructural Response to Dynamic LoadsTransportation Safety and Impact Analysis

Challenges in intermetallics: synthesis, structural characterization, and transitions

Robin T. Macaluso、Benjamin K. Greve2012-01-01Dalton Transactions

Intermetallics that contain rare-earth elements are particularly interesting because of their temperature- and pressure-dependent structural and physical transitions that make them potential candidates for magnetic applications. This article highlights synthetic routes and structural characterization advancements used…

Rare-earth and actinide compoundsIron-based superconductors researchHeusler alloys: electronic and magnetic properties

Culture of Mouse Olfactory Sensory Neurons

Qizhi Gong2012-01-01Current Protocols in Neuroscience

Olfactory sensory neurons, located in the nasal epithelium, detect and transmit odorant information to the central nervous system. This requires that these neurons form specific neuronal connections within the olfactory bulb and express receptors and signaling molecules specific for these functions. This protocol desc…

Neurobiology and Insect Physiology ResearchOlfactory and Sensory Function StudiesPhotochromic and Fluorescence Chemistry

FATIGUE CHARACTERISTICS OF LASER WELDED ZIRCALOY THIN SHEET

Donghee Jeong、Jae Hoon Kim、Joon Kyoo Park 等 6 位作者2012-01-01International Journal of Modern Physics Conference Series

The spacer grid is one of the main structural components in a fuel assembly. It supports fuel rods, guides cooling water and maintains geometry from external impact load and cyclic stress by the vibration of nuclear fuel rod, it is necessary to have sufficient strength against dynamic external load and fatigue strengt…

Fatigue and fracture mechanicsNuclear Materials and PropertiesNuclear and radioactivity studies

Elastic Modulus Determination of Al‐Cu Film Alloys Prepared by Thermal Diffusion

Enrique Otero Huerta、A.I. Oliva、F. Avilés 等 5 位作者2012-01-01Journal of Nanomaterials

Elastic moduli of 50–250 nm thick Al‐50 at % Cu film alloys deposited by thermal evaporation on Kapton substrates and postformed by thermal diffusion are investigated. Formation of the Al2Cu alloy phase was confirmed by X‐ray photoelectron spectroscopy (XPS). Surface morphology was examined by atomic force microscopy…

Metal and Thin Film MechanicsAluminum Alloy Microstructure PropertiesCopper Interconnects and Reliability

Novel metal–organic frameworks based on 5-bromonicotinic acid: Multifunctional materials with H 2 purification capabilities

Antonio J. Calahorro、Marta E. López-Viseras、Alfonso Salinas‐Castillo 等 7 位作者2012-01-01CrystEngComm

Two new metal–organic frameworks based on 5-bromonicotinic acid complexes have been synthesized by hydrothermal reaction with Cd and Co metallic( ii ) salts in the presence of water.

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Improvement of the retention-formation relationship using three-component retention aid systems

Anna Svedberg、Tom Lindström2012-01-01Nordic Pulp & Paper Research Journal

Abstract The effects of retention on formation and drainage by using three-component retention aid systems were examined using a pilot web former. The purpose was to examine whether the relationship between retention and formation could be improved by using systems based on cationic polyacrylamide, structurally differ…

Asphalt Pavement Performance EvaluationCorrosion Behavior and InhibitionAdvanced Cellulose Research Studies

An Electronic Model for Solar Cells Including Active Interfaces and Energy Resolved Defect Densities

Annegret Glitzky2012-01-01SIAM Journal on Mathematical Analysis

We introduce an electronic model for solar cells taking into account heterostructures with active interfaces and energy resolved volume and interface trap densities. The model consists of continuity equations for electrons and holes with thermionic emission transfer conditions at the interface and of ODEs for the trap…

Material Dynamics and PropertiesAdvanced Thermodynamics and Statistical MechanicsOptical properties and cooling technologies in crystalline materials

Oligo(ω-pentadecalactone) decorated magnetic nanoparticles

Muhammad Yasar Razzaq、Marc Behl、Ute Frank 等 6 位作者2012-01-01Journal of Materials Chemistry

Hybrid magnetic nanoparticles (mgNP) with a magnetite core diameter of 10 ± 1 nm surface functionalized with oligo(ω-pentadecalactone) (OPDL) oligomers with Mn between 1300 and 3300 g mol−1 could be successfully prepared having OPDL grafted from 200 mg g−1 to 2170 mg g−1. The particles are dispersible in chloroform re…

Nanoparticle-Based Drug DeliveryIron oxide chemistry and applicationsLayered Double Hydroxides Synthesis and Applications

Development of a Novel Biosensor Using Cationic Antimicrobial Peptide and Nickel Phthalocyanine Ultrathin Films for Electrochemical Detection of Dopamine

Maysa F. Zampa、Inês Maria de Sousa Araújo、José Ribeiro dos Santos Júnior 等 6 位作者2012-01-01International Journal of Analytical Chemistry

The antimicrobial peptide dermaseptin 01 (DS 01), from the skin secretion of Phyllomedusa hypochondrialis frogs, was immobilized in nanostructured layered films in conjunction with nickel tetrasulfonated phthalocyanines (NiTsPc), widely used in electronic devices, using layer-by-layer technique. The films were used as…

Advanced biosensing and bioanalysis techniquesElectrochemical sensors and biosensorsConducting polymers and applications