Materials Literature
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Abstract A new type of membrane polymer, containing a photosensitive moiety, was synthesized. The photochemically induced functionalization and crosslinking of poly [acrylonitrile‐co‐butadiene‐co‐styrene‐co‐2‐(4‐ethenyl) phenyl‐5‐phenyl‐2H‐tetrazole], ABSV, has been studied. A variety of dipolarophiles and phenolic co…
Modulated-beam mass spectrometry and x-ray photoelectron spectroscopy (XPS) have been used to investigate the interaction of CH4, C2H4, C5H10, and H2 with carburized and uncarburized tungsten. It is shown that significant evaporation of C1, C2, and C3 occurs for carburized tungsten at temperatures above 1900 °C. The t…
This work presents the anisotropic pseudorotation (APR) model, which is a new dynamic model for the interpretation of experimental nuclear spin-lattice relaxation times in paramagnetic (S=1) complexes of low symmetry. It comprises two dynamic processes active in modulating the zero-field splitting interaction (ZFS). R…
Noble gas (He,Ar,Xe) and reactive gas (O2,N2) plasma treatments of polymethylmethacrylate (PMMA) and polyethyleneterephthalate (PET) surfaces were performed in an electron-cyclotron-resonance plasma. In situ surface analysis by x-ray photoelectron spectroscopy reveals well-defined surface compositions. From these meas…
Abstract Microphase separation in block copolymer systems forms well-defined, periodic structure on the sub-micron length scale. This structure arises from the system striving to satisfy the delicate balance of minimizing the area of contact between incompatible chain segments and maximizing the conformational entropy…
The resistance Rf of Pt and Ni films has been measured during deposition (by ion-beam sputtering) for different deposition rates r and substrate temperatures TS (300≤TS≤575 K). At the onset of deposition (the nucleation stage) Rf varies only slowly with deposition time T and oscillations occur in Rf vs T which are dam…
Abstract Significant advances in knowledge of lamellae and their organization in meltcrystallized polymers have stemmed from the ability to examine internal morphologies systematically with the transmission electron microscope. Spherulites form because the first-forming (dominant) lamellae branch repetitively, often a…
The electronic properties of amorphous carbon structures with varying microscopic mass densities, ranging from 2.0 to 3.52 g/${\mathrm{cm}}^{3}$, are analyzed. Using a semiempirical density-functional approach the model structures were generated by molecular dynamics performing a simulated cooling of liquid carbon clu…
The energetics and electronic structure of a series of neutral and charged oxygen and magnesium vacancy defects (F, ${\mathit{F}}^{+}$, ${\mathit{F}}^{2+}$, V, ${\mathit{V}}^{\mathrm{\ensuremath{-}}}$, ${\mathit{V}}^{2\mathrm{\ensuremath{-}}}$, and P centers) in MgO have been computed using the stationary total-energy…
Using a simple three-dimensional lattice copolymer model and Monte Carlo dynamics, we study the collapse and folding of proteinlike heteropolymers. The polymers are 27 monomers long and consist of two monomer types. Although these chains are too long for exhaustive enumeration of all conformations, it is possible to e…
Abstract To improve the wettability and adhesion, graft polymerization of acrylamide (AAm) and glycidyl methacrylate (GMA) was performed onto the surface of ultra‐high modulus polyethylene (UHMPE) fiber pretreated with Ar plasma. Following the plasma treatment and the subsequent exposure to air to introduce peroxides…
A 1 mm x 1 mm nematic liquid-crystal three-terminal device for optical beam forming (focusing/spoiling) is fabricated. A thin-film-resistor network on the device substrate layer is used to control the voltages on the 98 internal lens electrodes by use of only one variable external driver. By using a high-resistance th…
Three different size distributions of Ge quantum dots (≳200, 110, and 60 Å) have been synthesized via the ultrasonic mediated reduction of mixtures of chlorogermanes and organochlorogermanes (or organochlorosilanes) by a colloidal sodium/potassium alloy in heptane, followed by annealing in a sealed pressure vessel at…
The following paper presents the results of a theoretical study that probed the chemistry of water at structural defects on the MgO (001) surface. The computational technique used was periodic Hartree–Fock (PHF) theory with density functional based correlation corrections. The adsorption energies for water adsorbed on…
The electronic properties of shallow band-edge surface traps in nanometer-size CdSe quantum dots are probed using fluorescence-line-narrowing spectroscopy. We find large changes in electron-hole-pair radiative lifetimes and couplings to LO phonons as the temperature is changed from 1.75 to 10 K. We attribute these cha…
Using Brillouin scattering the three independent elastic stiffness constants cij of single-crystal cubic boron nitride have been measured: c11=820, c12=190, and c44=480 GPa. The resulting bulk modulus, 400 GPa, is in reasonable agreement with two independent determinations obtained from x-ray measurements in a diamond…
We present calculated 3 d , 3 p and 3 s resonant photoemission (RPE) spectra in the transition metal (TM) compounds CuO, NiO, CoO, FeO, MnO and TiO 2 at TM 2 p core threshold on the basis of a cluster model. Our model includes the intraatomic multipole electron-electron interactions and the hybridization between trans…
It is demonstrated that the reflective properties and bistability of cholesteric liquid crystals can be controlled by proper surface treatment and dispersed polymers. Dispersing a polymer in the liquid crystal or using a cell with an inhomogeneous surface anchoring creates permanent defects which result in long-term b…
Seaweed has been used since the 1800s in the treatment of wounds. Sorbsan is an alginate dressing designed to absorb large amounts of exudate. Sorbsan is removed by irrigation without causing damage to newly forming tissue. Sorbsan is a relatively painless dressing to remove.
Fine tip structures are required for many applications in different technologies, for example in scanning probe microscopy or vacuum microelectronic devices. Tips can be produced with nanometre precision by the electron-beam-induced deposition technique. The deposition process, however, is still not really understood.…