Materials Literature
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New pentacyano complexes of tri- and tetravalent platinum were obtained in aqueous solution and characterized by multinuclear NMR ((195)Pt, (13)C) supported by Raman spectroscopy. The complexes form as products of redox decomposition of metal-metal bonded platinum-thallium compounds. The trimetallic [(NC)(5)Pt-Tl-Pt(C…
Abstract The populations of four aliphatic polyester-degrading microorganisms at 50 °C were demonstrated in vitro. The percentage of degraders to total microorganisms were: 5-86%, PHB; 3-49%, PCL; 0-87.5%, PBS; and 0-4.5%, PLA.
An overview of contemporary methods of crystal structure solution from powder diffraction data is given.Methods are compared with respect to their advantages and disadvantages.A choice of an appropriate method is discussed in the light of understanding the structural problem to be solved.The need of the variety of met…
Transparent and crack-free SrTiO3 thin films were prepared on fused silica substrates by a sol–gel technique. Strontium acetate and titanium tetra-n-butoxide were used as starting materials. The structural properties of the thin films were studied by X-ray diffraction. The films annealed at 700 °C have good crystallin…
We study the use of shape memory alloys for the purpose of passive vibration damping in a one degree of freedom oscillator. We assume that the pseudoelastic behavior of the shape memory material is due to a stress-induced phase transformation which is governed by a kinetic relation. We consider both impulsively initia…
Structure of poly(3-hydroxybutyrate-co-3-hydroxyvalerate) fibers prepared by drawing and annealing processes has been analyzed through wide-angle X-ray diffraction (WAXD), density, infrared dichroism, and birefringence measurements. There are three different types of crystalline structure in these fibers: two of these…
Zone-center TO phonon frequencies and eigenvectors of cubic ${\mathrm{SrHfO}}_{3}$ are determinated, by calculating atomic forces, in the framework of the local density approximation to density functional theory to sense the presence of possible lattice instabilities. The results are compared with parallel calculation…
SmFe 2 crystals were grown by the self-flux method using Sm as a flux, and the crystallographic and magnetic properties of the crystal were studied for the first time. SmFe 2 crystallizes in a cubic MgCu 2 -type structure (space group of Fd3m ) with lattice constants of a =0.7425 nm. Saturation magnetization M S at 5…
By taking into account the effects of domain structures and X-ray absorption, the superstructure of PbZrO 3 , lead zirconate, has been determined at room temperature. The space group is Pbam with a unit cell of a = 5.8884 (19), b = 11.771 (4) and c = 8.226 (3) Å, with Z = 8. The intensity data were collected using sho…
It has been demonstrated that Fourier transform infrared (FT-IR) microspectroscopy can be used to study different types of spherulites of poly(vinylidene fluoride) formed by different crystal modifications. Because of selective IR bands of the α and the γ modification, respectively, it is possible to map the crystalli…
The hydrolysis behaviour of lactic acid based poly(ester-urethane)s has been studied in a buffer solution of pH 7·00 at 37 and 55°C. Samples were prepared using a straight two step lactic acid polymerization process. The lactic acid was first polymerized by condensation with a low molecular weight by hydroxyl terminat…
Abstract The microtextural changes in the kaolinization of primary phyllosilicates including biotite, sericite, clinochlore and muscovite were investigated by scanning electron microscopy (SEM) and microchemical analysis of thin sections of weathered anorthosite. Kaolinization began at grain edges and propagated towar…
L'inhibition de la corrosion de l'alliage Cu-Zn (70/30) en milieu H2SO4 0.1 M par des composés organiques de type “tétrazole" a été étudiée en utilisant les méthodes gravimétrique et électrochimique. Les résultats obtenus montrent que le 1-phényl-5-mercapto-1,2,3,4-tétrazole (PMT) est le meilleur inhibiteur de la séri…
The process of phase separation for quenched, three-dimensional binary alloy systems with coupled elastic fields was investigated with Langevin simulations. The elastic effects are the result of a dilational misfit introduced via inhomogeneities in the elastic constants of the system. A selection criterion for the sha…
Modified sol‐gel processes have been developed for the preparation of lead zirconate titanate (PZT) (52/48) powders. These processes use different starting sources to introduce the titanium and zirconium components, namely tetraethyl orthotitanate, titanium isopropoxide, or titanium diisopropoxide bis(2,4‐pentanediona…
Grafting of polyethylene glycol chains onto cellulosic membrane can be expected to reduce the interaction between blood (plasma protein and cells) and the membrane surface. Alkylether carboxylic acid (PEG acid) grafted high flux cellulosic membranes for hemodialysis, in which the polyethylene glycol chain bears an alk…
The influence of water, formamide, and n -dodecane on the liquid crystalline properties of several rodlike 4,4‘‘-bis(decyloxy)- p -terphenyl derivatives incorporating nonionic hydrophilic groups in a central position was investigated by polarizing microscopy and X-ray scattering. Up to three different rectangular colu…
In colossal magnetoresistance materials, ferromagnetic double exchange presumably coexists with a direct nearest-neighbor antiferromagnetic interaction. We construct a single-site mean-field theory that explicitly takes into account the different nature of carrier-mediated ferromagnetism vs Heisenberg-like superexchan…
Principles of solid-state structure and bonding that relate metal-halide and metal-chalcogenide materials are described through a comparison of binary AX n salts. Structural variation is rationalized by a comparison of the size and charge of the respective ions, the d-electron count of the cations, and the type of A−X…
This paper studies the dye-sensitized photooxidation of tyrosine (tyr) and tyr di- and tripeptides (tyr-tyr and tyr-tyr-tyr) mediated by singlet molecular oxygen (O2[1 delta g]) in alkaline media. Photooxidation quantum efficiencies (phi r) were obtained by determining the overall and reactive rate constants of intera…