Materials Literature
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Abstract This highlight concerns the birth, development, and present status of unique polyurethanes consisting of polyisobutylene soft segments and conventional hard segments (PIB‐based PUs) exhibiting unprecedented combinations of mechanical properties and oxidative/hydrolytic/biological stability. Impetus for develo…
We extend designs of perfect lenses to the focusing of surface plasmon polaritons (SPPs) propagating at the interface between two anisotropic media of opposite permittivity sign. We identify the role played by the components of anisotropic and heterogeneous tensors of permittivity and permeability, deduced from a coor…
Colour centres in diamond are promising candidates as a platform for quantum technologies and biomedical imaging based on spins and/or photons. Controlling the emission properties of colour centres in diamond is a key requirement for the development of efficient single-photon sources having high collection efficiency.…
Abstract The vibrational contribution to static and dynamic (hyper)polarizabilities for the zigzag ( n ,0) family of BN nanotubes, with n ranging from (6,0) to (36,0), has been obtained. Calculations were done by the finite field nuclear relaxation (FF‐NR) method for periodic systems, newly implemented in the CRYSTAL…
SBA-15 exhibits a biporous character consisting of primary mesopores and intrawall pores ranging from micropore to mesopore size. We successfully demonstrated the removal of the intrawall porosity upon addition of NaI. The characteristic mesopore size, wall thickness, particle size, and morphology were maintained.
Abstract The effects of strain rate and water absorption properties can be used to evaluate the environmental degradation of sisal fiber reinforced polymer–matrix composites. Composites of vinylester and epoxy resin, reinforced by sisal fiber, were manufactured using the RTM method. To examine how the mechanical prope…
Abstract The rheological properties of sisal fiber (SF)/polylactic acid (PLA) composites of different SF content and initial fiber length were evaluated using a torque rheometer. Since the SF configuration directly affected the rheological properties of the composites, the length and width of SFs in the final composit…
A new family of low thermal expansion niobate ceramics was discovered that sinter to form unusual high permeability microstructures. The coefficient of thermal expansion ( CTE ) can be tailored from −4 × 10 −7 /°C to +40 × 10 −7 /°C by control of composition and firing temperature. The inherent vapor‐phase transport s…
A recent gold nanotechnology-driven approach opens up a new possibility for the destruction of cancer cells through photothermal therapy. Ultimately, photothermal therapy may enter into clinical therapy and, as a result, there is an urgent need for techniques to monitor the tumor response to therapy. Driven by this ne…
To utilize a new conformation-dependent backbone-geometry library (CDL) in protein refinements at atomic resolution, a script was written that creates a restraint file for the SHELXL refinement program. It was found that the use of this library allows models to be created that have a substantially better fit to main-c…
The success of nanoparticle-based devices will need reliable fabrication methods for well-defined, defect-free self-assembled structures of nanoparticles (NPs). NP self-assembly is a process governed by an interplay between many inter-particle interactions, such as core-core van der Waals and dipolar attractions, as w…
The electrical resistivity, crystalline structure, and electronic properties calculated from the experimentally measured atomic positions of the compound SmFeAsO${}_{0.81}$F${}_{0.19}$ have been studied up to pressures \ensuremath{\sim}20 GPa. The correlation between the pressure dependence of the superconducting tran…
Abstract A series of efficient zinc catalysts supported by sterically bulky benzotriazole phenoxide ( BTP ) ligands are synthesized and structurally characterized. The reactions of diethyl zinc (ZnEt 2 ) with CMe2Ph BTP ‐H, t‐Bu BTP ‐H, and TMCl BTP ‐H yield monoadduct [(μ‐ BTP )ZnEt] 2 ( 1 – 3 ), respectively. Bisadd…
Two distinct morphologies of hexylselenophene-hexylthiophene rod-rod block copolymer films can be prepared depending on the molecular weight of the sample (see picture: left M(n) =12.9, right M(n) =3.9 kg mol(-1)). These polymers can be used to organize spherical CdSe nanocrystals (yellow) into either dispersed or ali…
A nanocomposite composed of NbTi nanowires uniformly embedded in NiTi matrices was fabricated, which exhibits an ultrahigh mechanical-damping capability. The absorption energy measured under an applied 8% strain is up to 54 MJ/m3, which is over three times higher than that (∼16 MJ/m3) found in the well-known Ni-Ti all…
We study inelastic energy relaxation in graphene for low energies to find out how electrons scatter with acoustic phonons and other electrons. By coupling the graphene to superconductors, we create a strong dependence of the measured signal, i.e., critical Josephson current, on the electron population on different ene…
Shape memory alloys (SMAs) are well known for their unique shape memory effect (SME) and superelasticity (SE) behavior. The SME and SE have been extensively investigated in past decades due to their potential use in many applications, especially for smart materials. The unique effects of the SME and SE originate from…
A fast-response and scattering-free polymer network liquid crystal (PNLC) light modulator is demonstrated at λ = 1.06 μm wavelength. A decay time of 117 μs for 2π phase modulation is obtained at 70 °C, which is ∼ 650 × faster than that of the host nematic LCs. The major tradeoff is the increased operating voltage. Pot…
We propose the use of high strength, metal-coated Kevlar yarns to weave flexible, conformal, and load-bearing antennas for an emerging class of applications emphasizing multiple functionality. In particular, here we present a unified, quantitative analysis of multiple properties of conductors as load-bearing materials…
Abstract Natural fiber‐reinforced nanocomposites based on polypropylene/nanoclay/banana fibers were fabricated by melt mixing in a twin‐screw extruder followed by compression molding in this current study. Maleic anhydride polypropylene copolymer (MA‐g‐PP) was used as a compatibilizer to increase the compatibility bet…