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Novel crown-containing porphyrin and its complexes with transition metals

Ya. F. Al Ansari、В. Е. Баулин、Е. В. Савинкина 等 4 位作者2008-11-27Russian Journal of Coordination Chemistry

The novel crown-containing porphyrin 5-{4-[(4-hydroxybenzo-15-crown-5)-5-yldiazo]phenyl}-10,15,20-triphenylporphyrin (H 3 L) and its transition metal complexes MHL (M = Co(II), Ni(II), Cu(II), and Zn(II)) and AgH 2 L were obtained. The compositions and structures of all the compounds were studied by MALDI-TOF mass spe…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine Chemistry

Improvement of the Long‐Term Performance of Impact‐Modified Polycarbonate by Selected Heat Treatments

Tom A. P. Engels、Bernard A. G. Schrauwen、Leon E. Govaert 等 4 位作者2008-11-27Macromolecular Materials and Engineering

Abstract Next to the intended increase of the impact toughness, impact modification of polycarbonate generally results in an unwanted decrease in yield stress and time‐to‐failure under constant stress. It is demonstrated that this loss in strength can be fully compensated for by an annealing treatment, or by increasin…

Polymer crystallization and propertiesEpoxy Resin Curing ProcessesInjection Molding Process and Properties

Influence of electrosynthesis potential on corrosion performance of polypyrrole coated stainless steel and its mechanism research

Ruqiang Zhu、G. X. Li、J. H. Zheng 等 5 位作者2008-11-27Surface Engineering

The electrosynthesis process of conducting polymer on stainless steel was investigated and a two-step process was adopted to obtain polypyrrole (PPy) films at low potentials. The effects of applied potentials on the electrochemical, structural and protective properties of PPy films have been explored using scanning el…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Critical micelle concentrations of cetyltrimethylammonium chloride and their influence on the periodic structure of mesoporous silica

Daqing Li、Hao Li、Yan Fu 等 7 位作者2008-11-27Colloid Journal

The influence of micelle morphology transformation on the structure of mesoporous materials is fundamental in designing optimal, well-ordered, mesoporous materials. Firstly, the steady-state fluorescence technique was adopted to determine the first and second critical micelle concentrations of cetyltrimethylammonium c…

Surfactants and Colloidal SystemsMesoporous Materials and CatalysisAnalytical Chemistry and Chromatography

Performance Evaluation of Treated—Untreated Jute—Carbon and Glass—Carbon Hybrid Composites of Bisphenol-C based Mixed Epoxy—Phenolic Resins

V. A. Patel、B. D. Bhuva、P. H. Parsania2008-11-27Journal of Reinforced Plastics and Composites

Jute—carbon and glass—carbon hybrid composites of mixed matrix material [epoxy resin of bisphenol-C (EBC) and bisphenol-C-formaldehyde (BCF) of 50 wt% of the fibers] have been prepared by hand lay-up technique at 150°C under 7.6MPa pressure for 2h. Alkali-treated jute fibers have been acrylated to improve their physic…

Mechanical Behavior of CompositesNatural Fiber Reinforced CompositesFiber-reinforced polymer composites

Transformation optics for the full dielectric electromagnetic cloak and metal–dielectric planar hyperlens

Davy P. Gaillot、Charles Croënne、F Zhang 等 4 位作者2008-11-27New Journal of Physics

Full dielectric electromagnetic cloaks are studied in this paper for considering the possibility of achieving effective permeability gradients by taking advantage of a magnetic Mie resonance in high-κ ceramics. Extreme performance sensitivity to the dispersion of the complex effective parameters, which could be proble…

Metamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Finite wavelength cloaking by plasmonic resonance

N-A P Nicorovici、R C McPhedran、S Enoch 等 4 位作者2008-11-27New Journal of Physics

We consider cloaking by a coated cylindrical system using plasmonic resonance, and extend previous quasistatic treatments to include the effect of finite wavelength. We show that a probe cylinder can still be cloaked at finite wavelengths, but the cloaking cylinder develops a nonzero scattering cross section. We show…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

Study on the Crystallization Kinetic and Characterization of Poly(lactic acid) and Poly(vinyl alcohol) Blends

Jen‐Taut Yeh、Ming‐Chien Yang、Ching-Ju Wu 等 7 位作者2008-11-27Polymer-Plastics Technology and Engineering

In this study, poly(lactic acid) (PLA) and poly(vinyl alcohol) (PVA) blends, with PLA/PVA mass ratios of 100/0, 90/10, 80/20, 70/30, 60/40, 50/50, and 40/60, were prepared by means of the melt blending method. The result of torque measurements and thermal gravimtric analysis tests showed that the addition of PLA can d…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesCarbon dioxide utilization in catalysis

Synthesis of large-scale periodic ZnO nanorod arrays and its blue-shift of UV luminescence

Xiaoxian Zhang、Dongfang Liu、Lihuan Zhang 等 11 位作者2008-11-27Journal of Materials Chemistry

We demonstrate a promising route to fabricate large scale hexagonally patterned, vertically aligned ZnO nanorod arrays with small diameter. By adding 3-mercaptopropyltriethoxysilane (MPTES) molecules as a connection between catalyst and substrate the large size dispersion resulting from the removal of catalyst pattern…

ZnO doping and propertiesAdvanced Sensor and Energy Harvesting MaterialsNanomaterials and Printing Technologies

Generalized field-transforming metamaterials

Sergei Tretyakov、Igor S. Nefedov、Pekka Alitalo2008-11-27New Journal of Physics

In this paper, we introduce a generalized concept of field-transforming metamaterials, which perform field transformations defined as linear relations between the original and transformed fields. These artificial media change the fields in a prescribed fashion in the volume occupied by the medium. We show what electro…

Metamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface TechnologiesRadio Wave Propagation Studies

The Properties of Woven Kenaf and Betel Palm (Areca catechu) Reinforced Unsaturated Polyester Composites

Wen‐Chi Lai、M. Mariatti、Mohamad Jani S.2008-11-27Polymer-Plastics Technology and Engineering

The use of woven betel palm and kenaf lignocellulosic fibers as a reinforcing phase in unsaturated polyester was reported. The morphology, physical properties, and mechanical properties of the natural fibers and resulting woven composites were evaluated. Kenaf fibers exhibit higher tensile properties than betel palm f…

Natural Fiber Reinforced CompositesCellular and Composite StructuresMechanical Engineering and Vibrations Research

Neutral and reduced Roussin's red salt ester [Fe 2 (μ-RS) 2 (NO) 4 ] (R = n-Pr, t-Bu, 6-methyl-2-pyridyl and 4,6-dimethyl-2-pyrimidyl): synthesis, X-ray crystal structures, spectroscopic, electrochemical and density functional theoretical investigations

Rongming Wang、Miguel A. Camacho-Fernandez、Wei Xu 等 5 位作者2008-11-27Dalton Transactions

A series of Roussin's red salt esters [Fe(2)(micro-RS)(2)(NO)(4)] (R = n-Pr (), t-Bu (), 6-methyl-2-pyridyl () and 4,6-dimethyl-2-pyrimidyl ()) were synthesized by the reaction of Fe(NO)(2)(CO)(2) with thiols or thiolates. Complexes were characterized by IR, UV-vis, (1)H-NMR, electrochemistry, and single-crystal X-ray…

Metal complexes synthesis and propertiesMagnetism in coordination complexesMetal-Catalyzed Oxygenation Mechanisms

Magnetocaloric effect in La1−xPrxFe10.7Co0.8Si1.5compounds near room temperature

Jun Shen、Bo Gao、Q. Y. Dong 等 7 位作者2008-11-27Journal of Physics D Applied Physics

The magnetic properties and magnetocaloric effects in NaZn 13 -type La 1− x Pr x Fe 10.7 Co 0.8 Si 1.5 compounds have been investigated. Partially replacing La with Pr leads to a small reduction in the Curie temperature T C due to the lattice contraction, but the values of T C for La 1− x Pr x Fe 10.7 Co 0.8 Si 1.5 ar…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsMagnetic Properties of Alloys

Electromagnetic cloaking devices for TE and TM polarizations

Filiberto Bilotti、S Tricarico、Lucio Vegni2008-11-27New Journal of Physics

In this paper, we present the design of an electromagnetic cloaking device working for both transverse electric (TE) and transverse magnetic (TM) polarizations. The theoretical approach to cloaking used here is inspired by the one presented by Alù and Engheta (2005 Phys. Rev. E 72 016623) for TM polarization. The case…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Large reversible magnetocaloric effect in RNi compounds

Pramod Kumar、К. Г. Суреш、A. K. Nigam 等 4 位作者2008-11-27Journal of Physics D Applied Physics

In an attempt to identify novel magnetic refrigerant materials, we have studied the magnetic and magnetocaloric properties in RNi compounds with R = Gd, Ho and Er. GdNi is a simple ferromagnet with a collinear structure in contrast to HoNi and ErNi, in which the moments of rare earth sublattice are arranged non-collin…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsThermal Expansion and Ionic Conductivity

Characterization of Incipient Spall Damage in Shocked Copper Multicrystals

Pedro Peralta、Stephen Digiacomo、Seyed Majid Hashemian 等 10 位作者2008-11-27International Journal of Damage Mechanics

Correlations between spall damage and local microstructure were investigated in multicrystalline copper samples via impact tests conducted with laser-driven plates at low pressures (2—6 GPa). The copper samples had a large grain size as compared to the thickness, which was either 200 or 1000 μm, to isolate the effects…

High-Velocity Impact and Material BehaviorSurface Treatment and Residual StressIon-surface interactions and analysis

An aberration-free lens with zero F-number

David Schurig2008-11-27New Journal of Physics

Starting from the Luneberg lens index profile, we apply the transformation design method to the problem of far-field imaging of (infinitely) distant objects. This analysis yields a single element lens with a planar image surface, zero aberrations of all orders, zero F-number and (in some cases) constant aperture for a…

Metamaterials and Metasurfaces ApplicationsAdvanced optical system designOptical Coatings and Gratings

Solutions in folded geometries, and associated cloaking due to anomalous resonance

Graeme W Milton、Nicolae-Alexandru P Nicorovici、Ross C McPhedran 等 5 位作者2008-11-27New Journal of Physics

Solutions for the fields in a coated cylinder where the core radius is bigger than the shell radius are seemingly unphysical, but can be given a physical meaning if one transforms to an equivalent problem by unfolding the geometry. In particular, the unfolded material can act as an impedance matched hyperlens, and as…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisQuasicrystal Structures and Properties

Isotropic transformation optics: approximate acoustic and quantum cloaking

Allan Greenleaf、Yaroslav Kurylev、Matti Lassas 等 4 位作者2008-11-27New Journal of Physics

Transformation optics constructions have allowed the design of electromagnetic, acoustic and quantum parameters that steer waves around a region without penetrating it, so that the region is hidden from external observations. The material parameters are anisotropic, and singular at the interface between the cloaked an…

Metamaterials and Metasurfaces ApplicationsOrbital Angular Momentum in OpticsTopological Materials and Phenomena

Solutions in folded geometries, and associated cloaking due to anomalous resonance

Graeme W. Milton、Nicolae-Alexandru P. Nicorovici、Ross C. McPhedran 等 5 位作者2008-11-27Purdue e-Pubs (Purdue University System)

Solutions for the fields in a coated cylinder where the core radius is bigger than the shell radius are seemingly unphysical, but can be given a physical meaning if one transforms to an equivalent problem by unfolding the geometry. In particular, the unfolded material can act as an impedance matched hyperlens, and as…

Metamaterials and Metasurfaces ApplicationsElectromagnetic Scattering and AnalysisAdvanced Antenna and Metasurface Technologies