Materials Literature
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Nanodonuts! A hydrogen-bonded cyclic assembly (rosette, left) of a melamine featuring π-conjugated oligo(p-phenyleneethynylene) hierarchically self-organizes with a cyanurate in decane under dilute conditions to form toroidal nanostructures (right) with a diameter of 40 nm.
A non-linear conjugate gradient optimization scheme is used to obtain excitation energies within the Random Phase Approximation (RPA). The solutions to the RPA eigenvalue equation are located through a variational characterization using a modified Thouless functional, which is based upon an asymmetric Rayleigh quotien…
Innovative research and diagnostic techniques for biological testing have advanced during recent years because of the development of semiconductor nanocrystals. Although these commercially available, fluorescent nanocrystals have a protective organic coating, the inner core contains cadmium and selenium. Because these…
The electronic structure of the anomalous $δ$-phase of Pu is analyzed by a general and exact reformulation of the exchange energy of the $f$-shell. It is found that the dominating contribution to the exchange energy is a polarization of orbital spin-currents that preserves the time reversal symmetry, hence a non-magne…
We study the bias-dependent spin-transfer torque in magnetic tunnel junctions in the Stoner model by scattering theory. We show that the in-plane (Slonczewski type) torque vanishes and subsequently reverses its direction when the bias voltage becomes larger or the barrier wider than material and device-dependent criti…
The phase locking behavior of spin transfer nano-oscillators (STNOs) to an external microwave signal is experimentally studied as a function of the STNO intrinsic parameters. We extract the coupling strength from our data using the derived phase dynamics of a forced STNO. The predicted trends on the coupling strength…
Exponential band edges have been observed in a variety of materials, both crystalline and amorphous. In this Letter, we infer the structural origins of these tails in amorphous and defective crystalline Si by direct calculation with current ab initio methods. We find that exponential tails appear in relaxed models of…
We study theoretically the charge transport pumped by magnetization dynamics through epitaxial FIF and FNIF magnetic tunnel junctions (F: Ferromagnet, I: Insulator, N: Normal metal). We predict a small but measurable DC pumping voltage under ferromagnetic resonance conditions for collinear magnetization configurations…
The spectrally- and polarization-resolved absorption cross-sections of a single gold nanorod have been investigated using the spatial modulation spectroscopy technique. The ensemble of its optical features, that is, longitudinal and transverse surface plasmon resonances and interband absorption, has been quantitativel…
Phase-change materials are successfully employed in optical data storage and are becoming a promising candidate for future electronic storage applications. Despite the increasing technological interest, many fundamental properties of these materials remain poorly understood. However, in the last few years the understa…
The dynamics of a "peeling front" or an elastic line is studied under creep (constant load) conditions. Our experiments show an exponential dependence of the creep velocity on the inverse force (mass) applied. In particular, the dynamical correlations of the avalanche activity are discussed here. We compare various av…
The electronic structure of the magnetic semiconductor Ga$_{1-x}$Cr$_{x}$N and the effect of Si doping on it have been investigated by photoemission and soft x-ray absorption spectroscopy. We have confirmed that Cr in GaN is predominantly trivalent substituting for Ga, and that Cr 3$d$ states appear within the band ga…
The dynamics of magnetization in the presence of spin-transfer torque was studied. We derived the equation for the motion of magnetization in the presence of a spin current by using the local equilibrium assumption in non-equilibrium thermodynamics. We show that, in the resultant equation, the ratio of the Gilbert dam…
This work describes an innovative concept for the development of organized molecular systems thanks to the template effect of the pre-structured semi-conductive SmSi(111) interface. This substrate was selected because Sm deposition in the submonolayer range leads to a 8x2-reconstruction, which is a well-defined one-di…
A method that is used by space-confining NaAlH 4 into the as-synthesized ordered mesoporous silica (OMS) is presented in the present work. NaAlH 4 in the pores of OMS is obtained by impregnation and drying techniques. It has been found that the space-confined NaAlH 4 in the pores of OMS shows the lower temperature and…
Hierarchical, three-fold symmetrical, single-crystalline gold dendrites were synthesized by the reaction between a zinc plate and a solution of HAuCl 4 in the ionic liquid [BMIM][PF 6 ]. The unique dendritic gold nanostructures show a three-order hierarchy (i.e., a three-fold symmetrical <111>-oriented trunk, three gr…
Novel fluorescent, conformationally restricted dipyrromethene boron difluoride (BODIPY) dyes have been prepared by introducing a naphthalenyl group at the meso position of the BODIPY core. These BODIPY dyes exhibit increased fluorescence quantum yields compared with dyes that have a meso-position phenyl group with int…
This paper discusses the formation of nanosized hexagonal tungsten oxide (h-WO 3 ) during the annealing of hexagonal ammonium tungsten bronze (HATB), (NH 4 ) 0.33− x WO 3− y . This process was investigated by TG/DTA-MS, XRD, SEM, Raman, XPS, and 1 H-MAS NMR analyses. Through adjusting the temperature and atmosphere of…
Colloidal Ag nanoparticles coated with L-glutathione attached to bimane chromophores were studied by absorption, circular dichroism (CD), and fluorescence spectroscopies. The absorption and CD spectra were resonantly enhanced by Ag surface plasmons. The wavelength and particle-size dependence of the enhancement indica…
Triggered biodegradable composites made entirely from renewable resources are urgently sought after to improve material recyclability or be able to divert materials from waste streams. Many biobased polymers and natural fibers usually display poor interfacial adhesion when combined in a composite material. Here we pro…