Materials Literature
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Abstract A new family of lanthanide carboxylate complexes with benzoic acid and its derivatives was synthesised and characterised. The structures of the complexes were established by X‐ray crystallography, which revealed that various chelating modes of the carboxylate ligands are present on the metal ion, resulting in…
The quasi-unit cell picture describes the atomic structure of quasicrystals in terms of a single, repeating cluster which overlaps neighbors according to specific overlap rules. In this paper, we discuss the precise relationship between a general atomic decoration in the quasi-unit cell picture atomic decorations in t…
Surface Patterson Functions have been derived by direct inversion of experimental Low-Energy Electron Diffraction I-V spectra measured at multiple incident angles. The direct inversion is computationally simple and can be used to discriminate between different structural models. 1x1 YSi_2 epitaxial layers grown on Si(…
Alternating current susceptibility and direct current magnetization have been studied for polycrystalline Ca$_{1-x}$Mn$_x$O. On increasing the Mn content, magnetic ordering changes from spin-glass behavior for $0.25 \leqslant x \leqslant 0.4$ to antiferromagnetic order. The paramagnetic/antiferromagnetic transition is…
We present chronocoulometry experiments and equilibrium Monte Carlo simulations for the electrosorption of Br and Cl on Ag(100) single-crystal electrode surfaces. Two different methods are used to calculate the long-range part of the adsorbate-adsorbate interactions. The first method is a truncated-sum approach, while…
The plasma–copper reaction that is based on the hydrogen chloride (HCl) feed gas has been studied. Copper line can be etched at a high rate with this process. The wall profile can also be controlled by the process condition. Influences of process parameters such as plasma exposure time, pressure, plasma power, and sub…
Dept. of Crystalline Materials Science, Nagoya University, Nagoya 464-8603 Dept. of Applied Physics, Nagoya University, Nagoya 464-8603 SPring-8/JASRI, 1-1-1 Koto, Mikazuki-cho, Sayo-gun, Hyogo 679-5198 Faculty of Science and Technology, Science University of Tokyo, Chiba 278-8510 ISSP, University of Tokyo, Kashiwa 27…
Second-order optical nonlinearities, d 33 , of LaBGeO 5 , LiBGeO 4 and Ba 2 TiGe 2 O 8 crystals in transparent crystallized glasses were estimated by means of the Maker fringe technique. Transparent surface crystallized glasses were fabricated by crystallization of a glass with the exact or close stoichiometric compos…
Cation-driven and anion-driven electrochemomechanical deformations (ECMD) in electrodeposited polypyrrole (PPy) films have been investigated by means of cyclic voltammetry and cyclic step-voltammetry (CSV). The film deposited from hydrochloric acid (PPyCl) expanded upon anodic reaction (anodic expansion) while that de…
This study investigated the potassium (K) status of sugarcane growing soils in Fiji, using samples taken from fields under cultivation and also from sites that had not been cultivated for at least 30 years. Five sites were on highly weathered oxyhydroxide soils where the total K contents and K retention capacities wer…
GaN-based metal-oxide-semiconductor (MOS) capacitors were fabricated by using Ga oxide. The oxide was formed by photoelectrochemical (PEC) oxidation of GaN and was dominated by the β-Ga 2 O 3 phase. The electrical properties were characterized by capacitance–voltage and current–voltage measurements. The MOS structures…
ZnO nanowires were synthesized at 1380°C from ball-milled ZnO powders by a thermal evaporation procedure with argon carrier gas without any catalysts. Scanning electron microscopy revealed that the typical diameter and length of the ZnO nanowires are in the uniform ranges of 15 to 40 nm and 10 to 70 µm, respectively.…
New metal-ordered manganites RBaMn_{2}O_{6} have been synthesized and investigated in the structures and electromagnetic properties. RBaMn_{2}O_{6} can be classified into three groups from the structural and electromagnetic properties. The first group (R = La, Pr and Nd) has a metallic ferromagnetic transition, follow…
Cu electropolishing has recently been introduced to replace Cu-chemical mechanical polishing (CMP). In this work, we found that when the space width is fixed, the planarization efficiency (PE) decreases with increasing line width. When line width is fixed, the PE value decreases as space width increases. Furthermore,…
General equations for photon-correlation functions measured by dynamic-light-scattering on inhomogeneous, non-ergodic systems are presented. In contrast to previous studies on the same subject, our derivation includes the most general case that is free from any assumption on the nature of dynamic fluctuations. The pre…
In materials confined within nanometer channels in single-walled carbon nanotube (SWNT) bundles, interesting properties which are not observed in bulk materials are expected. In the present paper, we report an X-ray diffraction (XRD) study on water adsorption in SWNT bundles. It was found that a substantial amount of…
New dendrons and dendrimers with dendritic arms composed of alternate phenyleneethynylene and phenylenevinylene moieties have been efficiently synthesized using orthogonal and convergent syntheses that combine Sonogashira and Horner-Wadsworth-Emmons reactions. Two different iterative routes have been developed that al…
The local injection and lateral propagation of charge in ultrathin polyaniline (PAN) layers have been studied with the scanning electrochemical microscope (SECM). Monolayers of PAN were deposited on a glass substrate using the LB method and were chemically reduced using sodium dithionite. A microelectrode held close t…
We have measured the equilibrium swelling of polystyrene networks by linear deuterated polystyrene using the ion beam technique of helium-3 nuclear reaction analysis. These measurements enable an analysis of the swelling of networks at low degrees of swelling, and our results showed more swelling than predicted by usi…
The sound field generated from a cylindrical sonochemical cell is discussed in depth. This sound field is considered with a variable operating frequency. An acoustic model is developed to predict the spatial distribution of acoustic pressure, which is compared with experimental measurements of the spatial characterist…