Materials Literature
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We have grown epitaxial films of La0.67Sr0.33MnO3 (LSMO) and La0.67Ca0.33MnO3 (LCMO) on single crystalline LaAlO3 substrates by a cost effective polymer-assisted deposition technique. Film crystallinity, microstructure, resistivity, magnetization, and magnetoresistance (MR) were highly dependent on the annealing tempe…
Employing frequency-dependent dielectric susceptibility we characterize the aging in two supercooled liquids, sorbitol and xylitol, below their calorimetric glass transition temperatures. In addition to the alpha relaxation that tracks the structural dynamics, the susceptibility of both liquids possesses a secondary J…
It is shown that traces of 2,4,6-trinitrotoluene (TNT) display strong and distinct structures in differential reflectograms, near 420 and 250nm. These characteristic peaks are not observed from moth balls, nail polish, polyvinyl chloride, starch, soap, paper, epoxy, aspirin, polycarbonate, aspartame, polystyrene, poly…
We report on the enhancement of the mechanical properties of single wall carbon nanotube (SWNT)-polyvinyl alcohol (PVA) composites through functionalization of SWNTs with denatured collagen. In addition to improving compatibility with the matrix, the denatured collagen layer was found to increase the PVA matrix crysta…
Movements of ferroelastic 90° a -domains (twins) of sub-100 nm lateral size contribute greatly to the dielectric, piezoelectric, and elastic properties of ferroelectric materials. However, in thin films the mobility of twins is severely limited due to substrate clamping and pinning of domain walls. Here we demonstrate…
We report the magnetotransport properties of the heterojunction composed of La0.82Ca0.18MnO3 (LCMO) and 0.5wt% Nb-doped SrTiO3 (SNTO). At temperature below 120K, the heterojunction only exhibits a negative magnetoresistance (MR) independent of bias current. At temperatures above 120K, with increasing bias current a cr…
Emittance spectra of the MgAl 2 O 4 spinel have been obtained up to 2500 K. Spectral analysis using a dielectric function model recently developed for amorphous materials allowed us to retrieve the inversion parameter over a very wide temperature range. The results are very close to the most recent published values. B…
It is shown that the magnitude of photostructural changes in chalcogenide glass is a function of the connectivity and fragility of the glass network. Glasses with a floppy network undergo larger photostructural changes, as shown by photorelaxation, photoexpansion and photodarkening measurements. The increasing magnitu…
Recent experiments on polycrystalline Co1−xFexS2 demonstrated composition control over the spin polarization by Fermi level manipulation. We report here the growth and characterization of CoS2 single crystals with fine control over the stoichiometry by chemical vapor transport. At the ideal Co:S atomic ratio we observ…
Li 4 B N 3 H 10 has been synthesized recently from LiNH2∕LiBH4 mixtures and its crystal structure determined. We have calculated the electronic structure of this complex hydride and investigated its thermodynamic stability and decomposition energetics. We find that its enthalpy of formation is −708kJ∕mole with respect…
Simultaneous size and shape control of zinc selenide (ZnSe) nanostructures was achieved using lyotropic liquid crystal templates formed by the self-assembly of an amphiphilic block copolymer in the presence of water and a less polar organic solvent. ZnSe quantum dots, hollow nanospheres, nanotubes, and nanolaminates (…
This letter reports on a simple, easy method for generating suspended nanofibers on a dielectric substrate using various target electrodes. By controlling the electrostatic field between the target electrodes, the nanofibers can be oriented to the electric field direction at the electrodes. The alignment of nanofibers…
A theoretical and experimental study of magnetic metamaterials with unit cells containing two resonant elements is presented. The properties of these structures, consisting of split rings, are governed by strongly anisotropic magnetic coupling between individual elements. This coupling leads to propagation of slow mag…
Ab initio computational studies were performed for CdSe nanocrystals over a wide range of sizes and topologies. Substantial relaxations and coordination of surface atoms were found to play a crucial role in determining the nanocrystal stability and optical properties. While optimally (threefold) coordinated surface at…
We propose to apply plasma in liquid to replace gas-phase plasma because we expect much higher reaction rates for the chemical deposition of plasma in liquid than for chemical vapor deposition. A reactor for producing microwave plasma in a liquid could produce plasma in hydrocarbon liquids and waste oils. Generated ga…
Starting from Newton's equations of motion, we derive a dynamical density functional theory (DDFT) applicable to atomic liquids. The theory has the feature that it requires as input the Helmholtz free energy functional from equilibrium density functional theory. This means that, given a reliable equilibrium free energ…
Dislocation behavior inside the very small grains of nanocrystalline metals has so far eluded high-resolution transmission electron microscopy (TEM) examinations. We have identified full dislocations using high-resolution TEM, and the different ways they reside in the 20–30nm Ni grains. The thermally activated propaga…
Electrical transport properties of thin boron doped nanocrystalline diamond films with thicknesses of 60–500nm have been studied. The Raman spectra measured exhibit Fano resonances, characteristic for B concentrations close to the metal-to-insulator transition. Upon increasing the B concentration, the sp2 carbon relat…
The enzymatic kinetics of glycoside hydrolase family 7 cellobiohydrolase (Cel7A) towards highly crystalline celluloses at the solid-liquid interface was evaluated by applying the novel concept of surface density (rho) of the enzyme, which is defined as the amount of adsorbed enzyme divided by the maximum amount of ads…
Abstract The cohesive element approach is getting increasingly popular for simulations in which a large amount of cracking occurs. Naturally, a robust representation of fragmentation mechanics is contingent to an accurate description of dissipative mechanisms in form of cracking and branching. A number of cohesive law…