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Observation of Hybrid Carbon Nanostructures as Intermediates in the Transformation from Hydrocarbon Nanotubes and Nano-onions to Carbon Nanotubes and Nano-onions via Sonolysis on Silicon Nanowires and Nanodots, Respectively

Boon K. Teo、Xuhui Sun、C. P. Li 等 5 位作者2010-01-11Chemistry of Materials

It was found that hydrocarbon nanotubes (HCNTs) and nano-onions (HCNOs) (hereafter collectively referred to as HCNT(O)s) can be converted to carbon nanotubes (CNTs) and nano-onions (CNOs) (hereafter collectively referred to as CNT(O)s) upon prolonged sonication via hybrid CNT⊂HCNT and CNO⊂HCNO nanostructures as interm…

Carbon Nanotubes in CompositesNanopore and Nanochannel Transport StudiesNanotechnology research and applications

Cost-Effective Single Step Cofiring Process for Manufacturing Solid Oxide Fuel Cells Using HSC™ Anode

Kyung Joong Yoon、Guosheng Ye、Srikanth Gopalan 等 4 位作者2010-01-11Journal of Electrochemical Energy Conversion and Storage

The anode-supported planar solid oxide fuel cell (SOFC) was fabricated by a cost-effective single step cofiring process using high shear compaction (HSC)™ anode substrate. The HSC™ process is a novel ceramic tape fabrication technique, which offers advantages in low-cost and high-volume production of the anode substra…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Vertical absorption edge and temperature dependent resistivity in semihydrogenated graphene

Lei Chen、Zhongshui Ma、C. Zhang2010-01-11Applied Physics Letters

We show that for graphene with any finite asymmetry in the on-site energy between the two sublattices (Δ), the optical absorption edge is determined by the Δ. The universal conductance will be broken and the conductance near the band edge varies with frequency as 1/ω2. The onset conductance is σc=2σ0=πe2/2h, independe…

Graphene research and applications2D Materials and ApplicationsThermal properties of materials

Mechanisms of self-diffusion in stoichiometric and substoichiometric amorphous silicon dioxide

Sergio Orlandini、Simone Meloni、Mariella Ippolito 等 4 位作者2010-01-11Physical Review B

We have investigated the Si and O self-diffusion in stoichiometric and substoichiometric amorphous ${\text{SiO}}_{2}$ by means of molecular-dynamics simulations. The diffusivity and the migration energies at different Si concentrations are reported and the results in qualitative agreement with previous experimental an…

Glass properties and applicationsThin-Film Transistor TechnologiesSilicon Nanostructures and Photoluminescence

X‐ray photoelectron analysis of surface functional groups on diamond‐like carbon films by gas‐phase chemical derivatization method

Susumu Takabayashi、Keishi Okamoto、Hiroaki Motoyama 等 6 位作者2010-01-11Surface and Interface Analysis

Abstract Oxygen‐related surface functional groups on diamond‐like carbon (DLC) films were derivatized with fluorine‐ and nitrogen‐related groups by the gas‐phase chemical derivatization (GCD) method, and the groups were analyzed quantitatively by X‐ray photoelectron spectroscopy (XPS). It is desirable that a derivatiz…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Fully inverted single-digit nanometer domains in ferroelectric films

Noureddine Tayebi、Yoshie Narui、Nathan Franklin 等 7 位作者2010-01-11Applied Physics Letters

Achieving stable single-digit nanometer inverted domains in ferroelectric thin films is a fundamental issue that has remained a bottleneck for the development of ultrahigh density (>1 Tbit/in.2) probe-based memory devices using ferroelectric media. Here, we demonstrate that such domains remain stable only if th…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesFerroelectric and Negative Capacitance Devices

Structural degradation mechanism of multiwalled carbon nanotubes in electrically treated field emission

Chan‐Wook Baik、Jeonghee Lee、Jun Hee Choi 等 7 位作者2010-01-11Applied Physics Letters

Carbon nanotubes in printed field emission arrays are known to be often damaged during field emission. A high-resolution transmission electron microscopy and Raman scattering spectra suggest that the degraded structure is mainly determined by electrical treatment conditions. A nonstationary alternating-current treatme…

Carbon Nanotubes in CompositesGraphene research and applicationsIon-surface interactions and analysis

Degradation of Solid Oxide Fuel Cell Cathodes Accelerated at a High Water Vapor Concentration

Seung Hwan Kim、Kwang Bo Shim、C. S. Kim 等 8 位作者2010-01-11Journal of Electrochemical Energy Conversion and Storage

The influence of water vapor in air on power generation characteristic of solid oxide fuel cells was analyzed by measuring cell voltage at a constant current density, as a function of water vapor concentration at 800°C and 1000°C. Cell voltage change was negligible at 1000°C, while considerable voltage drop was observ…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsElectronic and Structural Properties of Oxides

Effect of Filler and Urethane Rubber on NR/BR with Nanosilica: Morphology and Wear

Kaushik Pal、R. Rajasekar、Dong Jin Kang 等 7 位作者2010-01-11Journal of Thermoplastic Composite Materials

The blends of butadiene rubber (BR), urethane rubber (EU) and natural rubber (NR) was prepared using a blending technique in presence of different types of carbon black. The effect of filler on morphological and wear characteristics was studied. ISAF type of carbon black showed a significant effect on optimum cure tim…

Polymer Nanocomposites and PropertiesTribology and Wear AnalysisPolymer Nanocomposite Synthesis and Irradiation

Self‐Assembly of Discrete Homochiral, Helical, Hydrogen‐Bonded Nanocages: From Vesicles to Microspheres and Tubules Capable of Gelating Solvents

Liwei Yan、Ying Xue、Ge Gao 等 7 位作者2010-01-11Chemistry - A European Journal

The chiral tris-monodentate imidazolinyl ligands 1 a-c exhibit a strong tendency to form the discrete, helical [2+3] nanocages 3 ([1(2).2(3)]) with tartaric acids 2. Circular dichroism (CD) spectra and theoretical calculations reveal that supramolecular handedness of capsulelike architectures is determined only by the…

Metal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in Materials

Interconnected Networks of Zn(NO3)2·6(H2O) Nanotubes and Its Solid-Phase Transformation into Porous Zinc Oxide Architectures

Ji Hong Wu、Binni Varghese、Xue Dong Zhou 等 7 位作者2010-01-11Chemistry of Materials

Highly oriented Zn(NO 3 ) 2 ·6H 2 O nanotubes were grown on mica substrates based on an epitaxy mechanism. The Zn(NO 3 ) 2 ·6H 2 O nanotubes with rectangular cross-section were self-assembled on mica surfaces into large-area, interconnected hexagonal networks. Fast evaporation of the solvent was found to be crucial fo…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Theory of quantum paraelectrics and the metaelectric transition

G. J. Conduit、Benjamin D. Simons2010-01-11Physical Review B

We present a microscopic model of the quantum paraelectric-ferroelectric phase transition with a focus on the influence of coupled fluctuating phonon modes. These may drive the continuous phase-transition first order through a metaelectric transition and furthermore stimulate the emergence of a textured phase that pre…

Ferroelectric and Piezoelectric MaterialsMaterial Dynamics and PropertiesAcoustic Wave Resonator Technologies

Increase in specific heat and possible hindered rotation of interstitialC2molecules in neutron-irradiated graphite

Tadao Iwata、Mitsuo Watanabe2010-01-11Physical Review B

Irradiation-induced increase in the low-temperature specific heat has been measured in the temperature range of 1.9--43 K in graphite neutron-irradiated to $1.4\ifmmode\times\else\texttimes\fi{}{10}^{20}\text{ }\text{n}/{\text{cm}}^{2}$ $(E>1\text{ }\text{MeV})$ around 333 K. The increase of the lattice specific he…

Fusion materials and technologiesIon-surface interactions and analysisGraphite, nuclear technology, radiation studies

Enhanced multiferroicity in Mg-doped Ca3Co2−xMnxO6

L. Li、Wei Luo、Y. J. Guo 等 7 位作者2010-01-11Applied Physics Letters

Polycrystalline Ca3−xMgxCo2−yMnyO6 (y∼1.0) samples are prepared in order to investigate the A-site doping effect of Ca3Co2−yMnyO6 (y∼1.0). Compared with Ca3Co2−yMnyO6 (y∼1.0), the ferroelectric polarization and Curie point of Ca3−xMgxCo2−yMnyO6 (y∼1.0) at the maximal doping x∼0.3 are significantly enhanced. The magnet…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Monte Carlo Study of the Self-Assembly of Achiral Bolaform Amphiphiles into Helical Nanofibers

M. Wahab、P. Schiller、Robin Schmidt 等 4 位作者2010-01-11Langmuir

It is shown by coarse-grained off-lattice Monte Carlo simulations that a geometrically induced frustration of the parallel arrangement of rigid achiral bolaform amphiphiles can cause chirality in self-assembled nanostructures. The amphiphilic molecules are represented as rigid linear chains of 8 equally sized hydropho…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

Phase stabilization of δ-Bi2O3 nanostructures by epitaxial growth onto single crystal SrTiO3 or DyScO3 substrates

Danielle L. Proffit、G. R. Bai、Dillon D. Fong 等 10 位作者2010-01-11Applied Physics Letters

We observe that the high-temperature δ-phase of Bi2O3 is stabilized to room temperature by the epitaxial growth of nanostructures onto either (001)-oriented SrTiO3 or (001)p-oriented DyScO3 single crystal substrates. In addition, the morphology can be controlled by the miscut of the substrate. Synchrotron x-ray scatte…

Advancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsElectronic and Structural Properties of Oxides

Synthesis of Organoclays with Controlled Particle Size and Whiteness from Chemically Treated Indian Bentonite

Hasmukh A. Patel、Rajesh S. Somani、Hari C. Bajaj 等 4 位作者2010-01-11Industrial & Engineering Chemistry Research

Organoclays or nanoclays have gained increased attention from industry as well as academia during the past 1 1 / 2 decades. These clays are prepared from natural clays which invariably have other minerals as impurities. It is of prime significance to remove impurities from organoclays which find applications in polyme…

Hydrogels: synthesis, properties, applicationsPolymer Nanocomposites and PropertiesClay minerals and soil interactions

Amine-Templated Aluminoborates Exhibiting Graphite and Diamond Nets

Avijit Kumar Paul、Srinivasan Natarajan2010-01-11Crystal Growth & Design

A solvothermal reaction of Al 2 O 3, H 3 BO 3, pyridine, and H 2 O at 180 °C/7 days in the presence of organic amine molecules gave rise to four new aluminoborates, [(C 6 H 18 N 2 )(AlB 6 O 13 H 3 )], I; [(C 5 H 16 N 2 )(AlB 5 O 10 )]·2H 2 O, II; [(C 5 H 16 N 2 )(AlB 5 O 10 )], III; and [(C 5 H 17 N 3 )(AlB 5 O 10 )]·…

Crystal Structures and PropertiesChemical Synthesis and CharacterizationX-ray Diffraction in Crystallography

Spin waves inJ1a−J1b−J2orthorhombic square-lattice Heisenberg models: Application to iron pnictide materials

Ryan Applegate、J. Oitmaa、Rajiv R. P. Singh2010-01-11Physical Review B

Motivated by the observation of spatially anisotropic exchange constants in the iron pnictide materials, we study the spin-wave spectra of the ${J}_{1a}\text{\ensuremath{-}}{J}_{1b}\text{\ensuremath{-}}{J}_{2}$ Heisenberg models on a square lattice with nearest-neighbor exchange ${J}_{1a}$ along $x$ and ${J}_{1b}$ alo…

Physics of Superconductivity and MagnetismRare-earth and actinide compoundsIron-based superconductors research

Surface plasmon enhanced photoconductance and single electron effects in mesoporous titania nanofibers loaded with gold nanoparticles

Min-Soo Son、Ji-Eun Im、Kang‐Kyun Wang 等 6 位作者2010-01-11Applied Physics Letters

We have synthesized mesoporous TiO2 nanofibers loaded with Au nanoparticles (MTNF-Au) and fabricated single nanofiber-based devices. MTNF-Au devices exhibited surface plasmon enhanced photoconductance under visible light, whereas MTNF devices without Au nanoparticles did not. Moreover, Coulomb oscillations were observ…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications