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Low Temperature Processing and Properties of Porous Frit-Bonded SiC Ceramics

Su-Ho Chae、Young‐Wook Kim、In‐Hyuck Song 等 7 位作者2009-09-30Journal of the Korean Ceramic Society

Porous frit-bonded SiC ceramics were successfully prepared at a temperature as low as 800 o C from SiC, frit, and microbeads (glass or polymer). The effects of SiC starting particle size and microbead addition on microstructure, porosity, and flexural strength were investigated. The addition of hollow glass microbead…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Microphase Separation in Sulfonated Block Copolymers Studied by Monte Carlo Simulations

P. Knychała、M. Banaszak、M. J. Park 等 4 位作者2009-09-30Macromolecules

The underpinnings of microphase separation in symmetric poly(styrenesulfonate- block -methylbutylene) (PSS−PMB) copolymer melts were examined by Monte Carlo lattice simulations. The main challenge is understanding the effect of ion pairs in the PSS block on thermodynamics. We assume that experimentally determined Flor…

Polymer crystallization and propertiesFuel Cells and Related MaterialsBlock Copolymer Self-Assembly

Synthesis of HCN Polymer from Thermal Decomposition of Formamide

Franco Cataldo、Giacomo Patanè、Giuseppe Compagnini2009-09-30Journal of Macromolecular Science Part A

Prolonged heating of formamide (HCONH2) at 185°C or 220°C produces a black insoluble product. The FT-IR spectroscopy and the X-ray photoelectron spectroscopy (XPS) suggest that the product has the chemical structure of a polymer of hydrocyanic acid: (HCN)x. The pyrolysis of (HCN)x prepared from formamide produces a la…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchEnergetic Materials and Combustion

Spin-Hamiltonian parameters and tetragonal distortion due to the Jahn–Teller effect for Cu2+centres in trigonal Zn(BrO3)·6H2O crystal

Wen-Lin Feng、He Lv、Weiqing Yang 等 4 位作者2009-09-30Molecular Physics

The spin-Hamiltonian parameters (g factors g//, g⊥ and hyperfine structure constants 65A// and 65A⊥) for the tetragonal Cu2+ centres in trigonal Zn(BrO3)·6H2O crystal are calculated from the complete diagonalization (of energy matrix) method (CDM) based on the cluster approach. In the CDM, the Zeeman and hyperfine int…

Luminescence Properties of Advanced MaterialsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Determination of the Phase Behavior of (LiNH2)c(LiBH4)1−c Quaternary Hydrides through in Situ X-ray Diffraction

Jonathan P. Singer、Martin S. Meyer、Richard M. Speer 等 5 位作者2009-09-30The Journal of Physical Chemistry C

Solid hydride materials combining high gravimetric and volumetric hydrogen capacity, rapid hydrogenation and dehydrogenation kinetics, and low operating temperature are highly desirable for hydrogen storage on fuel cell vehicles. Recently, a material of nominal composition Li 3 BN 2 H 8, formed by combining LiNH 2 and…

Hydrogen Storage and MaterialsHybrid Renewable Energy SystemsAmmonia Synthesis and Nitrogen Reduction

Nephrogenic Systemic Fibrosis in Rats Treated with Erythropoietin and Intravenous Iron

Thomas A. Hope、Whitney A. High、Philip E. LeBoit 等 7 位作者2009-09-30Radiology

PURPOSE: To use a rat model for nephrogenic systemic fibrosis (NSF) that was administered high-dose gadodiamide to determine whether the co-administration of erythropoietin (Epo) and intravenous iron potentiated development of skin lesions that are thought to be a marker for the development of NSF. MATERIALS AND METHO…

Acute Kidney Injury ResearchLanthanide and Transition Metal ComplexesChemotherapy-induced organ toxicity mitigation

Thermally Controllable Reflective Characteristics from Rupture and Self-Assembly of Hydrogen Bonds in Cholesteric Liquid Crystals

Hu Wang、Hui Cao、Song Li 等 7 位作者2009-09-30The Journal of Physical Chemistry B

A cholesteric liquid crystal (Ch-LC) composite, made of a series of cholesteryl esters, a nematic LC, and a hydrogen bond (H-bond) chiral dopant (HCD), was prepared and filled into a planar treated cell. When the cell was heated, the selective reflection of the cell exhibited an unusual blue shift. One of the reasonab…

Liquid Crystal Research AdvancementsPhotonic Crystals and ApplicationsPhotochromic and Fluorescence Chemistry

Atomic scale high-angle annular dark field STEM analysis of the N configuration in dilute nitrides of GaAs

M. Herrera、Quentin M. Ramasse、Dwayne Morgan 等 12 位作者2009-09-30Physical Review B

While high-angle annular dark field scanning transmission electron microscopy (HAADF-STEM) has been successfully used for the analysis of heavy atoms in a lighter matrix, the detection of light atoms in a heavy matrix remains challenging. In this paper, we show that the combination of first-principles total-energy cal…

Semiconductor materials and devicesAdvanced Electron Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy Techniques

Uniform energy and density distribution: diblock copolymers’ functional

Emanuele Spadaro2009-09-30Interfaces and Free Boundaries Mathematical Analysis Computation and Applications

We study a nonlocal variational problem arising in diblock copolymers models, whose energy is given by the Cahn–Hilliard functional plus a long-range interaction term. We prove that minimizers develop uniform energy and density distributions, thus justifying partially the highly regular microphase separation observed…

Rheology and Fluid Dynamics StudiesBlock Copolymer Self-AssemblyComposite Material Mechanics

Symmetry-induced nonequilibrium distributions of bright and dark exciton states in single carbon nanotubes

Ryusuke Matsunaga、Yuhei Miyauchi、Kazunari Matsuda 等 4 位作者2009-09-30Physical Review B

We investigated the magnetic and temperature dependence of the bright and dark exciton luminescence spectra in single carbon nanotubes. We found that the phonon-induced exciton scattering rate from the bright to the dark state is only one order of magnitude larger than the dark exciton recombination rate below 10 K at…

Carbon Nanotubes in CompositesQuantum and electron transport phenomenaMechanical and Optical Resonators

Synthesis and Self-Assembly of Fluorescent Micelles from Poly(ferrocenyldimethylsilane-b-2-vinylpyridine-b-2,5-di(2′-ethylhexyloxy)-1,4-phenylvinylene) Triblock Copolymer

Feng He、Torben Gädt、Marcus Jones 等 6 位作者2009-09-30Macromolecules

A fluorescent ABC triblock copolymer containing poly(ferrocenyldimethylsilane) (PFS) and poly(2-vinylpyridine) (P2VP) moieties in the segments was synthesized via living anionic polymerization followed by quenching the living chains using a π-conjugated poly(2,5-di(2′-ethylhexyloxy)-1,4-phenylvinylene aldehyde (PDEHPV…

Advanced Polymer Synthesis and CharacterizationLuminescence and Fluorescent MaterialsDendrimers and Hyperbranched Polymers

Interfaces within graphene nanoribbons

J Wurm、Michael Wimmer、İnanç Adagideli 等 5 位作者2009-09-30New Journal of Physics

We study the conductance through two types of graphene nanostructures: nanoribbon junctions in which the width changes from wide to narrow, and curved nanoribbons. In the wide–narrow structures, substantial reflection occurs from the wide–narrow interface, in contrast to the behavior of the much studied electron gas w…

Graphene research and applicationsQuantum and electron transport phenomenaMolecular Junctions and Nanostructures

Fabrication and Characterization of (1-x)BiFeO3-xBaTiO3Ceramics Prepared by a Solid State Reaction Method

S. Chandarak、Muangjai Unruan、Thanapong Sareein 等 8 位作者2009-09-30Journal of Magnetics

In this study, BiFe<TEX>$O_3$</TEX>-BaTi<TEX>$O_3$</TEX> ceramics have been fabricated by a solid-state reaction method. The effects of BaTi<TEX>$O_3$</TEX> content in the (1-x)BiFe<TEX>$O_3$</TEX>-xBaTi<TEX>$O_3$</TEX> (x = 0.1, 0.2, 0.25, 0.3, 0.4, 0.5) system on crystal structure and magnetic, dielectric, and ferro…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

Optical properties of fibres with aluminophosphosilicate glass cores

Mikhail M. Bubnov、A N Gur'yanov、K. V. Zotov 等 11 位作者2009-09-30Quantum Electronics

The optical properties of fibres with aluminophosphosilicate (APS) glass cores have been studied at Al 2 O 3 and P 2 O 5 concentrations varied independently from 0 to 20%, and the ranges of dopant concentrations that ensure an optical loss level acceptable for the fabrication of active fibres have been established. Th…

Advanced Fiber Optic SensorsGlass properties and applicationsPhotonic Crystal and Fiber Optics

Effect of abrasive particle size on abrasive wear of hardfacing alloys

R. Chotěborský、P. Hrabě、Miroslav Müller 等 6 位作者2009-09-30Research in Agricultural Engineering

Hardfacing is one of the most useful and economical ways to improve the performance of components submitted to severe wear conditions. This study has been made for the comparison of microstructure and abrasion resistance of hardfacing alloys reinforced with chromium carbides or complex carbides. The hardfacing alloys…

High-Temperature Coating BehaviorsAdvanced materials and compositesMetal Alloys Wear and Properties

Development of Catalyst Free Carbon Nanotubes from Coal and Waste Plastics

Abhishek Dosodia、C. Lal、Bhanu Pratap Singh 等 5 位作者2009-09-30Fullerenes Nanotubes and Carbon Nanostructures

DC‐Arc technique has been used to synthesize carbon nanotubes from super clean coal, chemically cleaned coal, original coal and waste plastics instead of using high purity graphite in the presence of metal catalysts. The results obtained are compared in terms of yield, purity and type of carbon nanotubes produced from…

Carbon Nanotubes in CompositesGraphene research and applicationsNanotechnology research and applications

Phenyl@Rh(I)-Bridged Periodic Mesoporous Organometalsilica with High Catalytic Efficiency in Water-Medium Organic Reactions

Xushi Yang、Fengxia Zhu、Jianlin Huang 等 5 位作者2009-09-30Chemistry of Materials

A facile approach to prepare phenyl and Rh(I) organometal bridged periodic mesoporous organometalsilica was developed based on surfactant-directed co-condensation of RhCl[PPh 2 (CH 2 ) 2 Si(OEt 3 ) 3 ] 3 and (OEt) 3 SiPhSi(OEt) 3 . The as-prepared Rh(I)-PPh 2 -PMO(Ph) exhibited matchable catalytic efficiency with the…

Mesoporous Materials and CatalysisPolyoxometalates: Synthesis and ApplicationsLayered Double Hydroxides Synthesis and Applications

Immobilization of a Photoswitchable Piperidine Base

Ragnar S. Stoll、Stefan Hecht2009-09-30Organic Letters

The synthesis of a photoswitchable piperidine base, carrying a monochlorosilane anchoring group, and its immobilization on silica gel, mimicking an oxide surface, is reported. Efficient photoswitching between the E and Z isomers of the azobenzene photochrome was demonstrated for the immobilization precursor in solutio…

Molecular Sensors and Ion DetectionPorphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence Chemistry

Synthesis and Physical Properties of Two Chiral Terpyridyl Europium(III) Complexes with Distinct Crystal Polarity

Dongping Li、Cheng‐Hui Li、Jun Wang 等 7 位作者2009-09-30European Journal of Inorganic Chemistry

Abstract By utilizing the chiral terpyridyl‐type ligand L(–) [L =“dipineno”‐(4,5:4″,5″)‐fused 2,2′:6′,2″‐terpyridine or 2,6‐bis(7,7‐dimethyl‐5,6,7,8‐tetrahydro‐6,8‐methanoisoquinolin‐3‐yl)pyridine], two novel Eu III complexes with the formula [Eu(tta) 3 L](C 3 H 6 O) · 0.5(H 2 O) ( 1 ) and [Eu(bta) 3 (L)](C 3 H 6 O)(…

Molecular Sensors and Ion DetectionMagnetism in coordination complexesLanthanide and Transition Metal Complexes