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Crystal Field Analysis of Cr3+Energy Levels in LiGa5O8Spinel

M.G. Brik、N.M. Avram、C.N. Avram2007-11-01Acta Physica Polonica A

Detailed and consistent crystal field analysis of the LiGa 5 O 8 :Cr 3+ absorption spectrum is performed in the present paper by using the exchange charge model of crystal field. We calculate the crystal field parameters from the crystal structure date and diagonalize the crystal field Hamiltonian to obtain the energy…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsMicrowave Dielectric Ceramics Synthesis

Theories and Techniques of Crystal Structure Determination

U. Shmueli2007-11-01Materials Today

1. Symmetry in Crystals: Fundamentals 2. Point Groups and Lattice Types 3. Space-Group Symmetry 4. X-ray Diffraction Techniques 5. The Structure Factor and the Electron Density 6. The Patterson Function 7. Structure-Factor Statistics 8. Direct Methods 9. Atomic Displacement Parameters 10. Refinement of Structural Para…

X-ray Diffraction in Crystallography

Nonisothermal crystallization kinetics of poly(vinylidene fluoride) in a poly(vinylidene fluoride)/dibutyl phthalate/di(2‐ethylhexyl)phthalate system via thermally induced phase separation

Gen‐Liang Ji、Bao‐Ku Zhu、Chunfang Zhang 等 4 位作者2007-11-01Journal of Applied Polymer Science

Abstract The nonisothermal crystallization kinetics of poly(vinylidene fluoride) (PVDF) in PVDF/dibutyl phthalate (DBP)/di(2‐ethylhexyl)phthalate (DEHP) blends via thermally induced phase separation were investigated through differential scanning calorimetry measurements. The Ozawa approach failed to describe the crys…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesPolymer Science and PVC

In situ time‐resolved measurements of carbon nanotube and nanohorn growth

David B. Geohegan、Alexander A. Puretzky、David J. Styers-Barnett 等 12 位作者2007-11-01physica status solidi (b)

Abstract Growth mechanisms of carbon nanotubes are investigated and compared for both high‐ and low‐temperature synthesis methods through experiments utilizing time‐resolved, in situ imaging and spectroscopy. High‐speed videography and pyrometry measured the timeframes for growth for single‐wall carbon nanotubes (SWNT…

Carbon Nanotubes in CompositesDiamond and Carbon-based Materials ResearchFullerene Chemistry and Applications

CHEMICAL INTERACTIONS AT NOBLE METAL NANOPARTICLE SURFACES — CATALYSIS, SENSORS AND DEVICES

Ashalatha S. Nair、Renjis T. Tom、Vishal Kumar 等 5 位作者2007-11-01COSMOS

In this paper, a summary of some of the recent research efforts in our laboratory on chemical interactions at noble metal nanoparticle surfaces is presented. The article is divided into five sections, detailing with (i) interactions of simple halocarbons with gold and silver nanoparticle surfaces at room temperature b…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and ApplicationsGraphene and Nanomaterials Applications

Effect of interlayer cation and relative humidity on the hydration properties of a dioctahedral smectite

Walid Oueslati、M. S. Karmous、H. Ben Rhaïem 等 5 位作者2007-11-01Zeitschrift für Kristallographie Supplements

We’ve built this digital research platform to provide academics everywhere with fast, stable and secure digital access to our library of over 110,000 scholarly books and 800,000 journal articles. We’ve tested the platform in close cooperation with leading academic institutions. If you have any questions or you notice…

Clay minerals and soil interactionsIron oxide chemistry and applicationsLayered Double Hydroxides Synthesis and Applications

In situ photochemical conversion from cinnamoyl‐functionalized liquid‐crystalline monomers to liquid‐crystalline dimers

Hideyuki Kihara、Nobuyuki Tamaoki2007-11-01Liquid Crystals

Liquid‐crystalline (LC) monomers, which were functionalized with a cinnamoyl group on their extremity, were synthesized and irradiated with UV light in their LC phases. In the presence of a triplet sensitizer, most LC monomers were converted into the corresponding dimers, which were produced by the cycloaddition react…

Liquid Crystal Research AdvancementsPhotochromic and Fluorescence ChemistryAdvanced Materials and Mechanics

Photoluminescence enhancement in metallic nanocomposite printable polymer

V. Reboud、N. Kehagias、Marinella Striccoli 等 10 位作者2007-11-01Journal of Vacuum Science & Technology B Microelectronics and Nanometer Structures Processing Measurement and Phenomena

A 1.7-fold enhancement in the spontaneous emission intensity of dye chromophore loaded in a printable polymer is achieved by coupling the dye emission to surface plasmons of metallic nanoparticles. The nanocomposite material, embossed into arrays of wires by nanoimprint lithography process, shows good imprint properti…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanomaterials and Printing TechnologiesNanofabrication and Lithography Techniques

Porous Silicon Avalanche LEDs and their Applications in Optoelectronics and Information Displays

P. Jaguiro、P. Katsuba、S. K. Lazarouk 等 4 位作者2007-11-01Acta Physica Polonica A

The use of silicon based light emitting diodes may completely solve the problem of low compatibility of optoelectronics elements and silicon chip. At present time the most suitable kinds of Si-LEDs are monocrystal and porous silicon avalanche LEDs. They have advantages such as long operation lifetime (> 10000 hours),…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

Magnetic and electrical properties of the ZnGeAs2: Mn chalcopyrite

L. I. Koroleva、V. Yu. Pavlov、D. M. Zashchirinskiĭ 等 8 位作者2007-11-01Physics of the Solid State

Doping of the ZnGeAs2 semiconductor with manganese has produced compositions with spontaneous magnetization and high Curie temperatures of up to 367 K for the composition 3.5 wt% Mn. Their magnetic properties are characteristic of spin glasses at temperatures T < T S and magnetic fields H < 11 kOe. In stronger fields,…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Mechanical Properties of Zr-2.5Nb Pressure Tubes Made from Electrolytic Powder

C.E. Coleman、M. Griffiths、V. Grigoriev 等 6 位作者2007-11-01Journal of ASTM International

Abstract Pressure tubes in CANDUCANada Deuterium Uranium (CANDU) is a registered trademark of Atomic Energy of Canada Limited and RBMK reactors are fabricated from Zr-2.5Nb alloy. This paper describes the mechanical properties of tubes used in power reactors made by four routes using electrolytic powder as the base ma…

Fusion materials and technologiesNuclear reactor physics and engineeringNuclear Materials and Properties

Cyclopentadiene: The Impact of Storage Conditions on Thermal Stability

David J. am Ende、David C. Whritenour、Jotham W. Coe2007-11-01Organic Process Research & Development

The potential hazards from cyclopentadiene storage and use on kilogram scale are studied under adiabatic conditions. Cyclopentadiene, a reagent commonly used in organic synthesis, is known to spontaneously dimerize exothermically and thus should be stored cold and used quickly. In the present work we consider the impa…

Thermal and Kinetic AnalysisChemistry and Chemical EngineeringChemical Safety and Risk Management

Nitroxide‐mediated controlled degradation of polypropylene

Alexandros Psarreas、Costas Tzoganakis、Neil T. McManus 等 4 位作者2007-11-01Polymer Engineering and Science

Abstract The purpose of this work is to evaluate a new polypropylene (PP)‐based nitroxyl radical generator (NOR) and offer comparisons with a commonly used peroxide in the production of controlled‐rheology polypropylene (CRPP) resins. CRPP resins are produced by reactive processing in a batch mixer by using different…

Corrosion Behavior and InhibitionPolymer crystallization and propertiesFuel Cells and Related Materials

Functionalization of Biodegradable Polyester for Tissue Engineering Applications

Rossana Mara da Silva Moreira Thiré、Taíla O. Meiga、Sabrina Dick 等 4 位作者2007-11-01Macromolecular Symposia

Abstract Summary: Chemical modification of polymer surface may potentially be used to create smart materials that can guide cellular adhesion, proliferation and maintenance of specific expression of molecules. The microbial polyester poly (3‐hydroxybutyrate) (PHB) has been attracted attention as promising material for…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical Applications

Grating Couplers Fabricated by Electron-Beam Lithography for Coupling Free-Space Light Into Nanophotonic Devices

Scott Masturzo、J.M. Yarrison-Rice、Howard E. Jackson 等 4 位作者2007-11-01IEEE Transactions on Nanotechnology

Grating couplers with nanoscale periodicity have been fabricated on silicon-on-insulator (SOI) substrates by electron beam lithography and reactive ion etching. A versatile experimental apparatus has been implemented to measure the efficiency of these gratings in coupling free-space radiation into planar waveguides. T…

Photonic and Optical DevicesOrbital Angular Momentum in OpticsOptical Coatings and Gratings

Modification of Polylactic Acid Fiber with Enzymatic Treatment

Kazuya Sawada、Hiroshi Urakawa、Mitsuo Ueda2007-11-01Textile Research Journal

Enzymatic modification of polylactic acid fibers is investigated using various kinds of protease and lipase. The effects of enzymes on the hydrolysis of polylactic acid fibers is evaluated by means of fiber weight loss, fiber strength and fiber surface observation. It is found that proteases derived from Bacillus subt…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsMicroplastics and Plastic Pollution

Photoinduced enhancement of luminescence from (dibenzoylmethanato)boron difluoride in polymethyl methacrylate

А. Г. Мирочник、Е. В. Федоренко、D. Kh. Gizzatulina 等 4 位作者2007-11-01Russian Journal of Physical Chemistry A

The photochemical behavior of (dibenzoylmethanato)boron difluoride in the polymethyl methacrylate matrix was studied. Photoinduced luminescence enhancement was observed, and a mechanism of the process related to the aggregation of high-polarity luminophore molecules under irradiation was suggested.

Molecular Sensors and Ion DetectionLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

Cellular Toxicity of Inorganic Hydroxide Nanoparticles

Soo-Jin Choi、Jae‐Min Oh、Taeun Park 等 4 位作者2007-11-01Journal of Nanoscience and Nanotechnology

Layered double hydroxides (LDHs), anionic clays, have attracted increasing interest as nanovehicles for delivering genes, drugs, and bio-active molecules into cells. However, no attempts have been made to evaluate the potential undesirable effects of LDH nanoparticles. The cytotoxicity of LDHs with different chemical…

biodegradable polymer synthesis and propertiesLayered Double Hydroxides Synthesis and Applications

Observation of Clear Images of Dislocations in Protein Crystals by Synchrotron Monochromatic-Beam X-ray Topography

Mayumi Koishi、Naoki Ohya、Yu Mukobayashi 等 6 位作者2007-11-01Crystal Growth & Design

Crystal defects, especially dislocations, in hen egg-white lysozyme crystals that have multiple polymorphisms, for example, tetragonal, orthorhombic, monoclinic forms, etc., were investigated by means of synchrotron monochromatic-beam X-ray topography. The observed topographic images of dislocations were much clearer…

Enzyme Structure and FunctionX-ray Spectroscopy and Fluorescence AnalysisCrystallization and Solubility Studies

Increased expression of erythropoietin receptor in human pterygial tissues

Hisao Ito、Shigeaki Ohno、Katsuya Nakanishi 等 10 位作者2007-11-01International Journal of Molecular Medicine

Erythropoietin (Epo) induces physiological activities such as cell proliferation, migration, and angiogenesis in Epo receptor (EpoR)-expressing vascular endothelial and tumor cells. Recently, it has been demonstrated that growth factor-independent proliferation is frequently observed during the cell transformation pro…

Hemoglobinopathies and Related DisordersPlatelet Disorders and TreatmentsDendrimers and Hyperbranched Polymers