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One-pot, single-component synthesis of functional emulsion-templated hybrid inorganic–organic polymer capsules

Rachel L. Harbron、Tom O. McDonald、Steve P. Rannard 等 5 位作者2011-11-01Chemical Communications

Multi-purpose amphiphilic branched copolymer surfactants can be used to simultaneously stabilise and cross-link emulsion droplets to produce encapsulated spheres and hollow capsules.

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Effect of Oxygen Impurities on Thermal Diffusivity of AlN Thin Films Deposited by Reactive RF Magnetron Sputtering

Takashi Yagi、Nobuto Oka、Takashi Okabe 等 6 位作者2011-11-01Japanese Journal of Applied Physics

The thermal diffusivities of AlN thin films with a thickness of about 600 nm deposited by reactive rf magnetron sputtering were measured by the pulsed light heating thermoreflectance technique. The AlN films contain oxygen impurities ranging from 1.1 to 13.6 at. % depending on the sputtering conditions. The measured t…

GaN-based semiconductor devices and materialsAcoustic Wave Resonator TechnologiesThermal properties of materials

Persistent photoinduced magnetization in the coexisting spin-glass and ferromagnetic phases of Pr0.9Ca0.1MnO3thin film

Sayani Majumdar、H. Huhtinen、M Svedberg 等 6 位作者2011-11-01Journal of Physics Condensed Matter

The persistent photoinduced magnetization (PPM) in the low bandwidth material Pr(1-x)Ca(x)MnO₃ at the low hole doping level of x = 0.1 is reported. Upon zero-field cooling under photoexcitation, significant improvement of the ferromagnetic (FM) ordering was observed in the low temperature spin-glass phase. However, up…

Magnetic properties of thin filmsMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Mechanism of self-assembly of rigid-chain macromolecules of cellulose ethers in solutions

С. А. Вшивков、A. G. Galyas2011-11-01Polymer Science Series A

With the aid of the turbidity-spectrum method, the cloud-point method, X-ray analysis, and polarization microscopy and the use of a polarization-photoelectric apparatus, the sizes of supramolecular particles are determined and the liquid-crystalline phase transitions and the structure of cellulose ether solutions are…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsMolecular spectroscopy and chirality

Thermophysical Property Measurements of High Temperature Melts Using an Electrostatic Levitation Method

Takehiko Ishikawa、Junpei Okada、Paul‐François Paradis 等 4 位作者2011-11-01Japanese Journal of Applied Physics

Thermophysical properties of high temperature melts are important to better understand material processes such as casting, welding, and crystal growth. Containerless processing techniques combined with non-contact diagnostic methods play significant roles in thermophysical property measurements of high temperature mel…

Solidification and crystal growth phenomenaMetallurgical Processes and Thermodynamicsnanoparticles nucleation surface interactions

Electrospinning Fabrication of Polyvinyl alcohol)/Waterborne Polyurethane/Silver Composite Nanofibre Mats in Aqueous Solution for Anti-bacterial Exploits

Jae‐Hyeung Park、In Kyo Kim、Jae Young Choi 等 7 位作者2011-11-01Polymers and Polymer Composites

Nanofibre mats of poly(vinyl alcohol) (PVA), waterborne polyurethane (WBPU) and nanometre silver (Ag) colloids have been fabricated by an electrospinning method in aqueous solutions. Since PVA is a water soluble and biocompatible polymer, it is one of the best materials for preparation of electrospun antibacterial nan…

Membrane Separation TechnologiesAdvanced Sensor and Energy Harvesting MaterialsElectrospun Nanofibers in Biomedical Applications

Porphyrin-appended phosphapalladacycle precatalysts: effects of central metals on the catalytic activity in a high-temperature Heck reaction

Yoshihiro Matano、Kazuaki Matsumoto、T. Shibano 等 4 位作者2011-11-01Journal of Porphyrins and Phthalocyanines

The synthesis and the catalytic activity of bis(μ-chloro)-bridged, phosphapalladacycle-fused diporphyrins (M-porphyrin-appended phosphapalladacycles: M = Zn , Ni , free-base), as well as the coordinating ability of their precursors, meso-phosphanylporphyrins are reported. Treatment of meso-phosphanylporphyrinatozinc(I…

Catalytic C–H Functionalization MethodsPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation Mechanisms

Synthesis, deblocking and cure reaction studies of secondary alcohol-blocked isocyanates

Issam Ahmed Mohammed、Sankar Govindarajan2011-11-01High Performance Polymers

A series of 1,3-dichloro-2-propanol-blocked diisocyanates, based on diisocyanates including 4,4′-methylene di(phenyl isocyanate), toluene-2,4-diisocyanate, isophorone diisocyanate and 1,6-diisocyanatohexane, were prepared and characterized thoroughly by Fourier transform infrared, 1 H-NMR, 13 C-NMR spectroscopic metho…

Polymer composites and self-healingEpoxy Resin Curing ProcessesSynthesis and properties of polymers

Effect of defect structure of lanthanum manganite on oxygen exchange kinetics and diffusion

Н. М. Поротникова、М. В. Ананьев、Э. Х. Курумчин2011-11-01Russian Journal of Electrochemistry

The method of oxygen isotopic exchange was used to study the oxygen exchange kinetics and diffusion in the LaMnO 3 + δ oxide at the temperatures of 600–850°C and in the range of oxygen pressures of 133.3–9332.4 Pa. The rate of interface exchange and diffusion coefficient of oxygen are much lower in the case of LaMnO 3…

Catalytic Processes in Materials ScienceAdvancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materials

Structural transformations during heat treatment of W-Mo cast high-speed steel modified using titanium diboride

А. С. Чаус、M. Bogachik、Peter Úradník2011-11-01The Physics of Metals and Metallography

The effect of the austenitizing temperature on the transformation of the primary structure of a tungsten-molybdenum high-speed steel of the R6M5 type modified by an addition of a titanium boride powder has been studied. The results of metallographic, X-ray diffraction, and electron-microprobe analysis of the steel hav…

Microstructure and Mechanical Properties of SteelsAdvanced materials and compositesMetal Alloys Wear and Properties

Synthesis of the Fe3O4@SiO2@SiO2–Tb(PABA)3 Luminomagnetic Microspheres

Dehui Sun、Ping Lü、Ji-Lin Zhang 等 5 位作者2011-11-01Journal of Nanoscience and Nanotechnology

In this paper, we describe the synthesis and characterization of a luminomagnetic microspheres with core-shell structures (denoted as Fe3O4@ SiO2 @SiO2-Tb(PABA)3). The luminomagnetic microspheres were characterized by field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), Fourier…

Luminescence Properties of Advanced MaterialsLanthanide and Transition Metal ComplexesNanocluster Synthesis and Applications

Pharmaceutical and Biomedical Applications of Interpenetrating Polymer Network

Neelam Jain、Pramod Kumar Sharma、Arunabha Banik 等 5 位作者2011-11-01Current Drug Therapy

Interpenetrating polymer network (IPN) based drug delivery system is basically designed to deliver drugs at a predetermined rate for a desired period of time with minimum fluctuation. Due to its physical and biological characteristics such as enhanced solubility of hydrophobic drugs, excellent swelling capacity, impar…

Hydrogels: synthesis, properties, applicationsAdvanced Polymer Synthesis and CharacterizationCollagen: Extraction and Characterization

Anthraquinone Liquid crystal dichroic dyes – a new form of chromonic dye?

Stephen J. Cowling、Colin Ellis、John W. Goodby2011-11-01Liquid Crystals

Dichroic dyes, based on anthraquinone chromophores, for incorporation into various liquid-crystalline host mixtures have been prepared. For each dye, which has been designed to absorb at different regions of the visible spectrum, we investigate liquid crystalline behaviour and prepare mixtures of dyes that also promot…

Liquid Crystal Research AdvancementsDyeing and Modifying Textile FibersPhotochromic and Fluorescence Chemistry

Thermal transport in individual thermoelectric nanowires: a review

W Kim2011-11-01Materials Research Innovations

Extensive research efforts have been devoted to nanowires because of their novel electronic, optical and thermoelectric properties due to spatial confinement in two dimensions. Among various fields, nanowires have been of interest in the thermoelectric community not only for their novel thermoelectric properties but a…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

The pH sensitivity of –NH exchange in LnDOTA–tetraamide complexes varies with amide substituent

Ana Christina L. Opina、Yunkou Wu、Piyu Zhao 等 5 位作者2011-11-01Contrast Media & Molecular Imaging

The amide proton exchange rates in various lanthanide(III) DOTA-tetraamide complexes were investigated by CEST as a function of variable chemical structures and charges on the amide substituents. Comparisons were made between YbDOTA-(gly)(4)(-) (Yb-1), YbDOTA-(NHCH(2)PO(3))(4 (5-) (Yb-2) and YbDOTA-(NHCH(2)PO(3)Et(2))…

Advanced MRI Techniques and ApplicationsRadioactive element chemistry and processingLanthanide and Transition Metal Complexes

Corrosion Inhibition and Adsorption Properties of N-Phenylhydrazine-1,2-Dicarbothioamide on Mild Steel in Hydrochloric Acid

Sudhish Kumar Shukla、Ashish Kumar Singh、M.A. Quraishi2011-11-01International Journal of Electrochemical Science

Corrosion Inhibition of the mild steel in 1M HCl N-phenylhydrazine-12-dithiocarboamide (PDA) has been investigated using weight-loss, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques. Inhibition efficiency increases with increase in inhibitor concentration, and solution temperat…

Corrosion Behavior and InhibitionHydrogen embrittlement and corrosion behaviors in metalsConcrete Corrosion and Durability

Growth of One-Dimensional Polyindole Nanostructures

Shubhra Goel、Nasreen Mazumdar、Alka Gupta2011-11-01Journal of Nanoscience and Nanotechnology

One-dimensional (1D) nanostructured polyindole (Nano-Pind) was synthesized with 10 minutes (Pind-10 m) and 24 hours (Pind-24 h) of polymerization time using a facile chemical oxidative polymerization method. The obtained Nano-Pinds were explored to study the differences in their structural, optical, spectral and condu…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsSynthesis and properties of polymers

Comparison of tensile properties and impact damage tolerance of hemp and glass fiber composites

Asim Shahzad2011-11-01Journal of Reinforced Plastics and Composites

Tensile properties and impact damage tolerance of hemp fiber and chopped strand mat (CSM) glass fiber composites have been evaluated and compared. The absolute and specific tensile properties of CSM glass fiber composites were found to be much superior to hemp fiber composites. Impact damage tolerance of hemp fiber co…

Natural Fiber Reinforced CompositesCellular and Composite StructuresAluminum Alloys Composites Properties

Foaming of amorphous polymers and blends in supercritical CO 2 : Solubility versus block copolymers addition

José Antonio Reglero Ruiz、Philippe Viot、Michel Dumon2011-11-01Journal of Cellular Plastics

Supercritical CO 2 (scCO 2 ) is used as a medium for foaming amorphous polymers. Astudy of the solubility of supercritical CO 2 in several amorphous polymers (PS andPMMA) and blends is performed, followed by an investigation of the foaming behavior of the polymer–gas systems. Nano-structuring triblock copolymers (styr…

Phase Equilibria and ThermodynamicsCarbon dioxide utilization in catalysisPolymer Foaming and Composites

Effects of Carbon Black on the Properties of HNBR Reinforced by in-situ Prepared ZDMA

Xingbo Zhao、Qiuyu Zhang、Junwei Gu 等 5 位作者2011-11-01Polymer-Plastics Technology and Engineering

Hydrogenated nitrile rubber (HNBR) filled with carbon black (CB) and in-situ prepared zinc dimethacrylate (ZDMA) was prepared by mechanical mixing method. The effects of carbon black on the vulcanization characteristics, physical and dynamic mechanical properties, thermal stability and the fracture surface morphologie…

Polymer Nanocomposites and PropertiesPolymer Nanocomposite Synthesis and IrradiationSilicone and Siloxane Chemistry