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Photocatalytic oxidation of methanol using silica‐titania composites in a packed‐bed reactor

Jennifer M. Stokke、David W. Mazyck、Chang‐Yu Wu 等 4 位作者2006-10-24Environmental Progress

Abstract The processing of forest products into pulp, paper, paperboard, and other wood products results in the generation of volatile organic compounds (VOCs) and hazardous air pollutants (HAPs). This work focused on the development of a photocatalytic packed‐bed reactor for the oxidation of methanol, which is the pr…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisCatalysis and Oxidation Reactions

Alumina Nanopowder Production from Synthetic Bayer Liquor

Mahyar Mazloumi、Razieh Khalifehzadeh、S.K. Sadrnezhaad 等 4 位作者2006-10-24Journal of the American Ceramic Society

Alkoxides are the most common precursors used for the production of alumina nanopowders. These materials are, however, expensive and corrosive. This paper introduces a new method for the production of alumina nanopowders by rapid cooling of a synthetic caustic sodium aluminate solution (Bayer liquor), followed by calc…

Advanced ceramic materials synthesisMesoporous Materials and CatalysisLayered Double Hydroxides Synthesis and Applications

Fabrication of Symmetric Hierarchical Hollow PbS Microcrystals via a Facile Solvothermal Process

Pingtang Zhao、Jinmin Wang、Guoe Cheng 等 4 位作者2006-10-24The Journal of Physical Chemistry B

Symmetric hierarchical hollow PbS structures consisting of nanowalls were successfully fabricated by a facile solvothermal process in ethylenediamine at 120 degrees C for 12 h, employing lead acetate trihydrate and dithizone as precursors; the thickness of the nanowalls is about 80 nm. No surfactants or other template…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin Films

Synthesis and Study of Arylenevinylene and Aryleneimine-Type Polymers Containing N-Hexyl-3.6-Carbazolyl Groups

D. Conduruta、Nicoleta Cristina Antonoaia、Mircea Grigoraş 等 4 位作者2006-10-24High Performance Polymers

Two monomers with preformed Schiff base and arylenevinylene structure and final bromine substituents were synthesized by coupling of 3-formyl-6-bromo-N-hexyl-carbazole with 1,4-phenylenediamine and tetraethyl-p-xylylene diphosphonate, respectively. These compounds were used to synthesize arylenimine and arylenevinylen…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Characterization of haemocytes of the Indian edible oyster, Crassostrea madrasensis (Preston)

Gijo Ittoop、K C George、N K Sanil 等 6 位作者2006-10-24Aquaculture Research

The haemocytes of the Indian edible oyster Crassostrea madrasensis were characterized using light and electron microscopy. The light microscopic study was conducted by staining a monolayer of the haemocytes with Geimsa. Cells without granules and with a large nucleus occupying much of the cytoplasmic area were grouped…

Aquaculture Nutrition and GrowthAquaculture disease management and microbiotaCalcium Carbonate Crystallization and Inhibition

Narrowband Microwave Dielectric Resonance and Negative Permittivity Behavior in Hydrogen‐Fired Al 2 O 3 –CuO Composites

J.P. Calame、Jacob Battat2006-10-24Journal of the American Ceramic Society

The frequency‐dependent microwave complex permittivity of composites based on an Al 2 O 3 –CuO system is investigated at room temperature. The composites are formed by solution infusion of copper precursors into a porous Al 2 O 3 matrix, followed by thermal decomposition to copper oxides and localized formation of cop…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Lead Chalcogenide Nanotubes Synthesized by Biomolecule‐Assisted Self‐Assembly of Nanocrystals at Room Temperature

Hua Tong、Ying‐Jie Zhu、Lixia Yang 等 5 位作者2006-10-24Angewandte Chemie

Natürlicher Helfer: PbE-Nanoröhren (E=S, Se, Te; siehe Bild) wurden mit einer neuartigen Biomolekül-unterstützten Methode bei Raumtemperatur erhalten. Die als Vorstufen fungierenden Nanodrähte, die sich aus in Gegenwart von Cystein synthetisierten Nanokristallen selbstorganisierten, spielen eine entscheidende Rolle al…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

Mechanochemical Activation‐Assisted Low‐Temperature Synthesis of CaZrO 3

Guotian Ye、Tom Troczynski2006-10-24Journal of the American Ceramic Society

Calcium zirconate (CaZrO 3 , CZ) was prepared using a solid‐state reaction with mechanochemical activation through vibro‐milling, aiming at completing the reaction CaO+ZrO 2 =CaZrO 3 at relatively low calcination temperatures. Changes in the crystallite size and homogeneity of the mixed components CaO and ZrO 2 in the…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisNuclear materials and radiation effects

Experimental Evidence for the Development of Bimodal Grain Size Distributions by the Nucleation‐Limited Coarsening Mechanism

Tomoko Sano、Gregory S. Rohrer2006-10-24Journal of the American Ceramic Society

It has recently been hypothesized that transient bimodal grain size distributions can arise from unimodal distributions during coarsening if the continued growth of a majority fraction of the crystals is arrested by the energy barrier to nucleate new layers. To test this hypothesis experimentally, SrTiO 3 has been coa…

Solidification and crystal growth phenomenananoparticles nucleation surface interactionsElectronic and Structural Properties of Oxides

Photoluminescence of multiwalled carbon nanotubes excited at different wavelengths

Yuan Yan-hong、Miao Run-Cai、Bai Jin-tao 等 4 位作者2006-10-24Chinese Physics

In this paper the multiwalled carbon nanotubes (MWNTs) were synthesized by a chemical vapour deposition and the SEM graph shows that the sample has good construction. The micro-Raman spectrum shows the characteristic line of the MWNTs and an additional line produced by the defects on the outer surface of MWNTs. The ph…

Carbon Nanotubes in CompositesGraphene research and applicationsNanotechnology research and applications

Structure of a carbohydrate esterase from Bacillus anthracis

Leoni Oberbarnscheidt、Edward J. Taylor、G.J. Davies 等 4 位作者2006-10-24Proteins Structure Function and Bioinformatics

Family 4 carbohydrate esterases (CEs) catalyse the N- or O-deacetylation of substrates such as acetylated xylan, chitin, and peptidoglycan. CEs are classified into 14 families by sequence homology (see http://afmb.cnrs-mrs.fr/CAZY4). Family 4 is by far the largest of the CE families, with over 1000 open reading frames…

Bacterial Genetics and BiotechnologyEnzyme Structure and FunctionPolyamine Metabolism and Applications

Enhanced localization of Dyakonov-like surface waves in left-handed materials

L.-C. Crasovan、Osamu Takayama、D. Artigas 等 6 位作者2006-10-24Physical Review B

We address the existence and properties of hybrid surface waves forming at interfaces between left-handed materials and dielectric birefringent media. The existence conditions of such waves are found to be highly relaxed in comparison to Dyakonov waves existing in right-handed media. We show that left-handed materials…

Metamaterials and Metasurfaces ApplicationsPlasmonic and Surface Plasmon ResearchOrbital Angular Momentum in Optics

Habit Modification of Asparagine Monohydrate Crystals by Growth in Hydrogel Media

Rositza I. Petrova、Rakesh Patel、Jennifer A. Swift2006-10-24Crystal Growth & Design

Crystal growth of a model molecular crystal system, asparagine monohydrate (Asn·H 2 O), was explored in a variety of hydrogel media. Morphologies of crystals grown in agarose, carrageenan, and gelatin gels were compared with those of crystals grown from pure aqueous solutions, as well as those grown from solutions con…

Enzyme Structure and FunctionCalcium Carbonate Crystallization and InhibitionCrystallization and Solubility Studies

A New Strategy for the Preparation of Polyamide-6 Microspheres with Designed Morphology

Aihua Pei、Andong Liu、Tingxiu Xie 等 4 位作者2006-10-24Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVCommunication to the...Communication to the EditorNEXTA New Strategy for the Preparation of Polyamide-6 Microspheres with Designed MorphologyAihua Pei, Andong Liu, Tingxiu Xie, and Guisheng YangView Author Information Beijing National Laboratory for Molecular Sciences, Key Laboratory o…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesSynthesis and properties of polymers

Ein bisher einmaliger Einblick in die Diffusion durch die Beobachtung der Konzentration von Gastmolekülen in nanoporösen Wirtmaterialien

Jörg Kärger、Pavel Kortunov、Sergey Vasenkov 等 8 位作者2006-10-24Angewandte Chemie

Mit Interferenzmikroskopie wurde die Konzentration von Gastmolekülen in Ferrierit-Zeolithen ermittelt. Die Mikroporen-Diffusionskoeffizienten wurden durch die mikroskopische Anwendung des zweiten Fickschen Gesetzes als eine Funktion der Beladung bestimmt. Mit Interferenzmikroskopie lassen sich isotrope und anisotrope…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisClay minerals and soil interactions

Nanostructure formation in polymer thin films influenced by humidity

Hartmut Gliemann、Arlete Tavares Almeida、Denise Freitas Siqueira Petri 等 4 位作者2006-10-24Surface and Interface Analysis

Abstract The influence of relative humidity (RH) during the film preparation on the surface morphology and on the material distribution of the resulting technical polymer blend films consisting of poly (methyl methacrylate) (PMMA) and poly (vinyl butyral) (PVB) is investigated by atomic force microscopy. Both pure pol…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsBlock Copolymer Self-Assembly

Raman resonance window of single-wall carbon nanotubes

J. S. Park、Y. Oyama、Riichiro Saito 等 10 位作者2006-10-24Physical Review B

The spectral width, or $\ensuremath{\gamma}$ value, of the Raman excitation profile for single-wall carbon nanotubes is calculated by evaluating the lifetime of the carriers. The calculated results for the $\ensuremath{\gamma}$ values are compared with the experimental spectral width of the Raman excitation profile. T…

Carbon Nanotubes in CompositesGraphene research and applicationsNanopore and Nanochannel Transport Studies

TD-DFT Description of Photoabsorption and Electron Transfer in a Covalently Bonded Porphyrin−Fullerene Dyad

Oana Cramariuc、Terttu I. Hukka、Tapio T. Rantala 等 4 位作者2006-10-24The Journal of Physical Chemistry A

Structure, photoabsorption, and excited states of a covalently bonded porphyrin-fullerene dyad H(2)P-O34-C(60) are studied using DFT and TD-DFT approaches. Charge transfer from the donor (porphyrin) to the acceptor (fullerene) and the excited-state geometrical relaxation are of special interest. An analysis of differe…

Porphyrin and Phthalocyanine ChemistryFullerene Chemistry and ApplicationsPhotochemistry and Electron Transfer Studies

R ‐Curve and Stress–Strain Behavior of Ferroelastic Ceramics

Jacob L. Jones、Mark Hoffman2006-10-24Journal of the American Ceramic Society

The R ‐curve and stress–strain behaviors in a variety of ferroelastic polycrystalline ceramic compositions are investigated and compared. These include soft and hard compositions of Pb(Zr,Ti)O 3 , Na 0.5 Bi 4.5 Ti 4 O 15 , PbNb 2 O 6 , PbTiO 3 , and Pb(Mg 1/3 Nb 2/3 )O 3 –Pb(Zr,Ti)O 3 . The fracture toughness enhancem…

Ferroelectric and Piezoelectric MaterialsAdvanced ceramic materials synthesisAdvanced materials and composites

Variable Temperature and EPR Frequency Study of Two Aqueous Gd(III) Complexes with Unprecedented Sharp Lines

Alain Borel、Hoon Kang、Christelle Gateau 等 6 位作者2006-10-24The Journal of Physical Chemistry A

We present an EPR study of two Gd(III) complexes in aqueous solution at multiple temperatures and EPR frequencies. These two complexes, [Gd(TPATCN)] and [Gd(DOTAM)(H(2)O)](3+), display remarkably sharp lines (i.e. slow transverse electron spin relaxation) in comparison with all complexes studied in the past, especiall…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies