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Ab Initiothermodynamic and elastic properties of alkaline-earth metals and their hydrides

Louis G. Hector、J. F. Herbst、W. Wolf 等 5 位作者2007-07-27Physical Review B

A systematic investigation of the alkaline earth hydrides $\mathrm{Be}{\mathrm{H}}_{2}$, $\mathrm{Mg}{\mathrm{H}}_{2}$, $\mathrm{Ca}{\mathrm{H}}_{2}$, $\mathrm{Sr}{\mathrm{H}}_{2}$, $\mathrm{Ba}{\mathrm{H}}_{2}$, the corresponding deuterides, and their antecedent metals is reported. We calculate lattice parameters, el…

Advanced Chemical Physics StudiesHydrogen Storage and MaterialsInorganic Fluorides and Related Compounds

Salinity-Dependent Switching of Osmolyte Strategies in a Moderately Halophilic Bacterium: Glutamate Induces Proline Biosynthesis in Halobacillus halophilus

Stephan H. Saum、Volker Müller2007-07-27Journal of Bacteriology

The moderately halophilic bacterium Halobacillus halophilus copes with the salinity in its environment by the production of compatible solutes. At intermediate salinities of around 1 M NaCl, cells produce glutamate and glutamine in a chloride-dependent manner (S. H. Saum, J. F. Sydow, P. Palm, F. Pfeiffer, D. Oesterhe…

Genomics and Phylogenetic StudiesBacterial Genetics and BiotechnologyEnzyme Structure and Function

Effect of dronedarone on renal function in healthy subjects

Yvonne Tschuppert、Thierry Buclin、Laura E. Rothuizen 等 7 位作者2007-07-27British Journal of Clinical Pharmacology

What is already known about this subject • Creatinine clearance (CL) is used to assess glomerular filtration rate (GFR). However, it is known to slightly overestimate the true GFR, due to renal tubular secretion of creatinine. • During phase I‐III clinical trials, a 10–15% increase in serum creatinine has been observe…

Chronic Kidney Disease and DiabetesAcute Kidney Injury ResearchLanthanide and Transition Metal Complexes

Structural Basis of Substrate-binding Specificity of Human Arylamine N-Acetyltransferases

Hong Wu、Ludmila Dombrovsky、W. Tempel 等 8 位作者2007-07-27Journal of Biological Chemistry

The human arylamine N-acetyltransferases NAT1 and NAT2 play an important role in the biotransformation of a plethora of aromatic amine and hydrazine drugs. They are also able to participate in the bioactivation of several known carcinogens. Each of these enzymes is genetically variable in human populations, and polymo…

Protein Structure and DynamicsMicrobial Metabolic Engineering and BioproductionEnzyme Structure and Function

On the Graphitization Nature of Oxides for the Formation of Carbon Nanostructures

M. H. Rümmeli、Christian Kramberger、A. Grüneis 等 7 位作者2007-07-27Chemistry of Materials

The demonstrated graphitization ability of oxides show that the simplistic view of the support playing a catalytically passive role in carbon nanotube synthesis can no longer be taken for granted. The proposed mechanisms suggest a single growth mechanism for both primary soot particles and carbon nanotubes synthesized…

Carbon Nanotubes in CompositesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Osteoblastic Phenotype Expression of MC3T3-E1 Cultured on Electrospun Polycaprolactone Fiber Mats Filled with Hydroxyapatite Nanoparticles

Patcharaporn Wutticharoenmongkol、Prasit Pavasant、Pitt Supaphol2007-07-27Biomacromolecules

Electrospun (e-spun) fiber mats of polycaprolactone (PCL; Mn = 80 000 g mol-1) with or without the presence of hydroxyapatite (HAp) nanoparticles (at 1% w/v based on the volume of the PCL solution) were successfully fabricated. The potential for use of these e-spun fiber mats as bone scaffolds was assessed by mouse ca…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Theory of optical scattering by carbon nanotubes

Said Mikki、Ahmed A. Kishk2007-07-27Microwave and Optical Technology Letters

Abstract Here, a theory of optical scattering by single‐wall carbon nanotube using modal expansion of the scattered and transmitted fields is developed. The effective‐boundary condition, derived previously using accurate quantum‐mechanical one‐electron tight‐biding approach, is employed to obtain the unknown coefficie…

Carbon Nanotubes in CompositesMechanical and Optical ResonatorsThermal Radiation and Cooling Technologies

Synthesis and Characterization of Ag−Hollandite Nanofibers and Its Catalytic Application in Ethanol Oxidation

Junli Chen、Xingfu Tang、Junlong Liu 等 7 位作者2007-07-27Chemistry of Materials

Ag−hollandite nanofibers were synthesized through a simple hydrothermal process by oxidizing Mn(NO 3 ) 2 with AgMnO 4 in aqueous solution. The temperature was found to play an essential role in determining both the crystalline structure and the morphology of the Ag−hollandite materials, whereas the AgMnO 4 /Mn(NO 3 )…

Supercapacitor Materials and FabricationCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Synthesis of Bi2Te3 Nanotubes by Galvanic Displacement

Feng Xiao、Bongyoung Yoo、Kyu Hwan Lee 等 4 位作者2007-07-27Journal of the American Chemical Society

Thermoelectric Bi 2 Te 3 nanotubes were synthesized using galvanic displacement of nickel nanowires. The composition of Bi 2 Te 3 nanotubes was precisely controlled by adjusting the [Bi 3+ ]/[HTeO 2 + ] ratio in the electrolyte. By combining the premagnetically assembled nickel nanowire and galvanic displacement react…

Advanced Thermoelectric Materials and DevicesThermal properties of materialsThermal Radiation and Cooling Technologies

Role of the nanoscale in catalytic CO oxidation by supported Au and Pt nanostructures

Sergey N. Rashkeev、Andrew R. Lupini、Steven H. Overbury 等 5 位作者2007-07-27Physical Review B

Experiments have found that the catalytic activity of Au increases sharply for supported nanoparticles smaller than $5\phantom{\rule{0.3em}{0ex}}\mathrm{nm}$, while Pt exhibits the opposite behavior. Several authors, seeking to explain the nanoscale Au activity, reached conflicting conclusions, attributing it to diffe…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceElectronic and Structural Properties of Oxides

Evidence for out-of-equilibrium crystal nucleation in suspensions of oppositely charged colloids

Eduardo Sanz、Chantal Valeriani、Daan Frenkel 等 4 位作者2007-07-27arXiv

We report a numerical study of the rate of crystal nucleation in a binary suspension of oppositely charged colloids. Two different crystal structures compete in the thermodynamic conditions under study. We find that the crystal phase that nucleates is metastable and, more surprisingly, its nucleation free energy barri…

Materials ScienceSoft Condensed Matter

Controllable Synthesis of CuS Nanostructures from Self-Assembled Precursors with Biomolecule Assistance

Benxia Li、Yi Xie、Yi Xue2007-07-27The Journal of Physical Chemistry C

In this work, taking the preparation of CuS nanomaterials as an example, the multiple roles of l -cysteine in the formation of metal sulfide nanostructures were elucidated. First, the precursors captured from the initial reaction solutions were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, Four…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsCopper-based nanomaterials and applications

Impurity conduction and magnetic polarons in antiferromagnetic oxides

Corneliu Chiorescu、J. L. Cohn、J. J. Neumeier2007-07-27Physical Review B

Low-temperature transport and magnetization measurements, reported for the antiferromagnets $\mathrm{Sr}\mathrm{Mn}{\mathrm{O}}_{3}$ and $\mathrm{Ca}\mathrm{Mn}{\mathrm{O}}_{3}$, provide a means for distinguishing self-trapped from bound magnetic polaron (MPs) and reveal new insight into the role of impurity states on…

ZnO doping and propertiesMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Guided modes of elliptical metamaterial waveguides

Klaus Halterman、Simin Feng、P. L. Overfelt2007-07-27Physical Review A

The propagation of guided electromagnetic waves in open elliptical metamaterial waveguide structures is investigated. The waveguide contains a negative-index media core, where the permittivity $\ensuremath{\epsilon}$ and permeability $\ensuremath{\mu}$ are negative over a given bandwidth. The allowed mode spectrum for…

Metamaterials and Metasurfaces ApplicationsMicrowave Engineering and WaveguidesAdvanced Antenna and Metasurface Technologies

High-pressure study of X-ray diffuse scattering in ferroelectric perovskites

Sylvain Ravy、Jean-Paul Itie、Alain Polian 等 4 位作者2007-07-27arXiv

We present a high-pressure x-ray diffuse scattering study of the ABO$_3$ ferroelectric perovskites BaTiO_3 and KNbO_3. The well-known diffuse lines are observed in all the phases studied. In KNbO_3, we show that the lines are present up to 21.8 GPa, with constant width and a slightly decreasing intensity. At variance,…

Materials Science

Is Small Perfect? Size Limit to Defect Formation in Pyramidal Pt Nanocontacts

Varlei Rodrigues、Fernando Sato、Douglas S. Galvao 等 4 位作者2007-07-27arXiv

We report high resolution transmission electron microscopy and ab initio calculation results for the defect formation in Pt nanocontacts (NCs). Our results show that there is a size limit to the existence of twins (extended structural defects). Defects are always present but blocked away from the tip axes. The twins m…

Materials Science

Room temperature spin filtering in epitaxial cobalt-ferrite tunnel barriers

A. V. Ramos、M. -J. Guittet、J. -B. Moussy 等 7 位作者2007-07-27arXiv

We report direct experimental evidence of room temperature spin filtering in magnetic tunnel junctions (MTJs) containing CoFe2O4 tunnel barriers via tunneling magnetoresistance (TMR) measurements. Pt(111)/CoFe2O4(111)/gamma-Al2O3(111)/Co(0001) fully epitaxial MTJs were grown in order to obtain a high quality system, c…

Materials Science

Excitation of spin dynamics by spin-polarized current in vortex state disks

B. A. Ivanov、C. E. Zaspel2007-07-27arXiv

A spin-polarized current with the polarization perpendicular to the plane of a vortex-state disk results in renormalization of the effective damping for a given magnetization mode, and the effective damping becomes zero if the current exceeds a threshold value. The lowest threshold current corresponds to the lowest fr…

Materials Science

Carbon Nanostructures as an Electromechanical Bicontinuum

Cristiano Nisoli、Paul E. Lammert、Eric Mockensturm 等 4 位作者2007-07-27Physical Review Letters

A two-field model provides a unifying framework for elasticity, lattice dynamics and electromechanical coupling in graphene and carbon nanotubes, describes optical phonons, nontrivial acoustic branches, strain-induced gap opening, gap-induced phonon softening, doping-induced deformations, and even the hexagonal graphe…

Carbon Nanotubes in CompositesGraphene research and applicationsThermal properties of materials

Mechanisms of superhydrophobicity on hydrophilic substrates

Jianlin Liu、Xi‐Qiao Feng、Gang-Feng Wang 等 4 位作者2007-07-27Journal of Physics Condensed Matter

Surface microstructures of solids play a significant role in producing superhydrophobic surfaces. In the present paper, the Cassie?Baxter and Wenzel models on a rough substrate are examined from the viewpoints of geometry and energy. The result shows that if the air beneath a droplet on a sinusoidal substrate is open…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferAdhesion, Friction, and Surface Interactions