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Comparison of mechanical and dielectric relaxation processes in laser-deposited poly(methyl methacrylate) films

Peter Rösner、Jörg Hachenberg、K. Samwer 等 9 位作者2006-06-09New Journal of Physics

Dynamic loss spectra for laser-deposited poly(methyl methacrylate) (PMMA) films are investigated at a frequency of 5.4 kHz with dielectric spectroscopy and mechanical torsional spectroscopy using a double-paddle oscillator as a substrate in a temperature range from room temperature up to 530 K. By comparing both metho…

Phase Equilibria and ThermodynamicsMaterial Dynamics and PropertiesCultural Heritage Materials Analysis

Magnetic anisotropy in the ferromagnetic insulating state ofLa1−xCaxMnO3

V. Likodimos、M. Pissas2006-06-09Physical Review B

Ferromagnetic resonance (FMR) has been applied to study the variation of magnetic anisotropy and phase separation tendencies in the ferromagnetic insulating state of stoichiometric hole-doped ${\mathrm{La}}_{1\ensuremath{-}x}{\mathrm{Ca}}_{x}\mathrm{Mn}{\mathrm{O}}_{3}\phantom{\rule{0.3em}{0ex}}(0.125\ensuremath{\leqs…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Gd(III) Polyaminocarboxylate Chelate: Realistic Many-Body Molecular Dynamics Simulations for Molecular Imaging Applications

Carine Clavaguéra、Emmanuelle Sansot、F. Calvo 等 4 位作者2006-06-09The Journal of Physical Chemistry B

Realistic molecular dynamics simulations of polyaminocarboxylate complexes of gadolinium (III) ion in water are performed, providing coordination numbers and average residence times in quantitative agreement with available experimental data. A theoretical analysis, based on fitting a fluctuating charges model on ab in…

Radioactive element chemistry and processingSpectroscopy and Quantum Chemical StudiesLanthanide and Transition Metal Complexes

Quantitative Rietveld texture analysis of CaSiO3perovskite deformed in a diamond anvil cell

Lowell Miyagi、Sébastien Merkel、Takehiko Yagi 等 6 位作者2006-06-09Journal of Physics Condensed Matter

The Rietveld method is used to extract quantitative texture information from a single synchrotron diffraction image of a CaSiO(3) perovskite sample deformed in axial compression in a diamond anvil cell. The image used for analysis was taken in radial geometry at 49 GPa and room temperature. We obtain a preferred orien…

High-pressure geophysics and materialsNuclear materials and radiation effectsX-ray Diffraction in Crystallography

Control of Crystal Size and Orientation in Polymer Films by Host−Guest Interactions

Christophe Daniel、Antonio Avallone、Paola Rizzo 等 4 位作者2006-06-09Macromolecules

The unprecedented occurrence of two different kinds of uniplanar orientation by solution casting, observed for syndiotactic polystyrene (s-PS) films, has been rationalized in terms of host−guest interactions into molecular complex phases. Correlation lengths along different crystallographic directions ( D hkl ), of mo…

Polymer crystallization and propertiesPolymer Nanocomposites and PropertiesPolymer composites and self-healing

Kinetic study of the thermoluminescence of KMgF3:LaF3 compounds employing the general one trap model

E. Caselli、C. Furetta、P. Molina 等 6 位作者2006-06-09Radiation Protection Dosimetry

The parameters characterising the trap centres involved in the thermoluminescence of KMgF3:LaF3 compounds have been found by deconvolving the glow curve with the General One Trap model (GOT). For the fitting procedure the Levenberg-Marquardt method has been employed. Tm-T(stop) measurements along with initial rise mea…

Luminescence Properties of Advanced Materialsnanoparticles nucleation surface interactionsInorganic Fluorides and Related Compounds

Advances in data reduction of high-pressure x-ray powder diffraction data from two-dimensional detectors: a case study of schafarzikite (FeSb2O4)

Bernd Hinrichsen、Robert E. Dinnebier、P. Rajiv 等 6 位作者2006-06-09Journal of Physics Condensed Matter

Methods have been developed to facilitate the data analysis of multiple two-dimensional powder diffraction images. These include, among others, automatic detection and calibration of Debye-Scherrer ellipses using pattern recognition techniques, and signal filtering employing established statistical procedures like fra…

High-pressure geophysics and materialsCrystal Structures and PropertiesX-ray Diffraction in Crystallography

Improving the elasticity and cytophilicity of biodegradable polyurethane by changing chain extender

Changhong Zhang、Ning Zhang、Xuejun Wen2006-06-09Journal of Biomedical Materials Research Part B Applied Biomaterials

Two types of biodegradable polyurethanes (PUs) were synthesized from methylene di-p-phenyl-diisocyanate (MDI), polycaprolactone diol (PCL-diol), and chain extenders of either butanediol (BD) or 2,2'-(methylimino)diethanol (MIDE). The effects of two types of chain extenders on the degradation, mechanical properties, hy…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsPolymer composites and self-healing

Selective Growth of Calcium Molybdate Whiskers by Rapid Cooling of a Sodium Chloride Flux

Katsuya Teshima、Kunio Yubuta、Shiori Sugiura 等 8 位作者2006-06-09Crystal Growth & Design

Long whiskers of calcium molybdate (CaMoO 4 ) were selectively grown by rapid cooling of a NaCl flux. The crystal growth of CaMoO 4 was conducted by heating a mixture of solute and flux at 900 °C for 10 h and then cooling to 500 °C at a rate of 270 °C·h -1 or quenching in a furnace with the electric power turned off.…

Graphene research and applicationsLuminescence Properties of Advanced MaterialsTransition Metal Oxide Nanomaterials

Effect of Ti and metal vacancies on the electronic structure, stability, and dehydrogenation ofNa3AlH6: Supercell band-structure formalism and gradient-corrected density-functional theory

Shaohan Li、Puru Jena、Rajeev Ahuja2006-06-09Physical Review B

Electronic and structural properties of sodium-aluminum hexahydride $({\mathrm{Na}}_{3}\mathrm{Al}{\mathrm{H}}_{6})$ formed during the decomposition reaction of sodium alanate $(\mathrm{Na}\mathrm{Al}{\mathrm{H}}_{4})$ and the effects of Ti catalyst are studied using supercell approach and density-functional theory. T…

Hydrogen Storage and MaterialsAmmonia Synthesis and Nitrogen ReductionSuperconductivity in MgB2 and Alloys

Effect of sterilization on the physicochemical properties of molded poly(L‐lactic acid)

Shawn J. Peniston、Sun Ju Choi2006-06-09Journal of Biomedical Materials Research Part B Applied Biomaterials

In this study, the process of manufacturing and sterilizing an orthopedic implant constructed from poly(L-lactic acid) (PLLA) was closely simulated. The hydrogen peroxide gas plasma (HPGP) sterilization process was comparatively investigated against ethylene oxide (EtO). Characterization of the physical, thermal, mech…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesGraphene and Nanomaterials Applications

Synthesis of silk fibroin‐insulin bioconjugates and their characterization and activities in vivo

Yu‐Qing Zhang、Yan Ma、Yun‐Yue Xia 等 8 位作者2006-06-09Journal of Biomedical Materials Research Part B Applied Biomaterials

The regenerated liquid silk fibroin with an average molecular mass of about 60 kDa consists of 18 kinds of amino acids containing approximately 10% of polar amino acids with hydroxyl and amino groups such as serine and lysine. The liquid silk fibroin is coupled covalently with insulin molecules through these strongly…

RNA Interference and Gene DeliveryAntimicrobial Peptides and ActivitiesSilk-based biomaterials and applications

Equilibrium Distribution of Permeants in Polyelectrolyte Microcapsules Filled with Negatively Charged Polyelectrolyte: The Influence of Ionic Strength and Solvent Polarity

Weijun Tong、Haiqing Song、Changyou Gao 等 4 位作者2006-06-09The Journal of Physical Chemistry B

The effects of ionic strength and solvent polarity on the equilibrium distribution of fluorescein (FL) and FITC-dextran between the interior of polyelectrolyte multilayer microcapsules filled with negatively charged strong polyelectrolyte and the bulk solution were systematically investigated. A negatively charged str…

Membrane Separation TechnologiesSurface Modification and SuperhydrophobicityPolymer Surface Interaction Studies

Magnetic Field Control of Photoinduced Silver Nanoparticle Formation

J. C. Scaiano、Carolina Aliaga、Steven Maguire 等 4 位作者2006-06-09The Journal of Physical Chemistry B

The micellar photoreduction of benzophenone in the presence of Ag+ leads to very rapid and efficient formation of silver nanoperticles. External magnetic fields can be used to control the rate of formation and properties of silver nanoparticles generated by reaction of ketyl radicals formed in the photoreduction of be…

Nanoparticles: synthesis and applicationsGold and Silver Nanoparticles Synthesis and Applicationsnanoparticles nucleation surface interactions

Chitosan scaffolds for in vitro buffalo embryonic stem‐like cell culture: An approach to tissue engineering

Wah Wah Thein‐Han、Yindee Kitiyanant2006-06-09Journal of Biomedical Materials Research Part B Applied Biomaterials

Three-dimensional (3D) porous chitosan scaffolds are attractive candidates for tissue engineering applications. Chitosan scaffolds of 70, 88, and 95% degree of deacetylation (% DD) with the same molecular weight were developed and their properties with buffalo embryonic stem-like (ES-like) cells were investigated in v…

Nanocomposite Films for Food PackagingElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Molecular Dynamics Simulation Study of the Structure of Poly(ethylene oxide) Brushes on Nonpolar Surfaces in Aqueous Solution

Dmitry Bedrov、Grant D. Smith2006-06-09Langmuir

The structure of poly(ethylene oxide) (PEO, M(w) = 526) brushes of various grafting density (sigma) on nonpolar graphite and hydrophobic (oily) surfaces in aqueous solution has been studied using atomistic molecular dynamics simulations. Additionally, the influence of PEO-surface interactions on the brush structure wa…

Surfactants and Colloidal SystemsPolymer Surface Interaction StudiesElectrostatics and Colloid Interactions

Aqueous Solution Route to High-Aspect-Ratio Zinc Oxide Nanostructures on Indium Tin Oxide Substrates

Chen-Hao Ku、Jih‐Jen Wu2006-06-09The Journal of Physical Chemistry B

High-aspect-ratio ZnO nanowires and nanotubes are formed on indium tin oxide (ITO) substrates using a three-step route at low temperatures. The three steps, including successive ionic layer absorption and reaction (SILAR) deposition of the ZnO seed layer, hydrothermal annealing of the seed layer, and chemical bath dep…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsGa2O3 and related materials

Universality of one-dimensional heat conductivity

Trieu Mai、Onuttom Narayan2006-06-09Physical Review E

We show analytically that the heat conductivity of oscillator chains diverges with system size N as N(1/3), which is the same as for one-dimensional fluids. For long cylinders, we use the hydrodynamic equations for a crystal in one dimension. This is appropriate for stiff systems such as nanotubes, where the eventual…

Thermal properties of materialsAdvanced Thermodynamics and Statistical MechanicsThermal Radiation and Cooling Technologies

Microstructural and magnetotransport properties ofLa0.7Ca0.3MnO3∕BaTiO3andLa0.7Sr0.3MnO3∕BaTiO3bilayered films

Y. P. Lee、S. Y. Park、Y. H. Hyun 等 7 位作者2006-06-09Physical Review B

The microstructural and the magnetotransport properties of ${\mathrm{La}}_{0.7}{\mathrm{Ca}}_{0.3}\mathrm{Mn}{\mathrm{O}}_{3}$ and ${\mathrm{La}}_{0.7}{\mathrm{Sr}}_{0.3}\mathrm{Mn}{\mathrm{O}}_{3}$ films, deposited on a $\mathrm{Ba}\mathrm{Ti}{\mathrm{O}}_{3}$ layer (LCMO/BTO and LSMO/BTO, respectively), and on $\mat…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

WO3/CeO2 Nanocomposite Powders: Synthesis, Characterization, and Reactivity

Marta Maria Natile、Francesco Tomaello、Antonella Glisenti2006-06-09Chemistry of Materials

WO 3 /CeO 2 nanocomposite powders, characterized by increasing W/Ce atomic ratio, were prepared by depositing, by wet impregnation, different amounts of WO 3 on the CeO 2 surface. The powders were characterized by means of X-ray photoelectron and diffuse reflectance infrared Fourier transform spectroscopic techniques…

Catalytic Processes in Materials ScienceTransition Metal Oxide NanomaterialsCatalysis and Oxidation Reactions